Acrylic-halogenated polyolefin copolymer adhesion promoters
    32.
    发明授权
    Acrylic-halogenated polyolefin copolymer adhesion promoters 有权
    丙烯酸卤化聚烯烃共聚物粘合促进剂

    公开(公告)号:US06965000B2

    公开(公告)日:2005-11-15

    申请号:US10864978

    申请日:2004-06-10

    IPC分类号: C08F4/00 C08F293/00

    摘要: The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.

    摘要翻译: 本发明涉及一种制备该方法的共聚物和共聚物的方法。 共聚物通过受控自由基聚合方法制备,通常是原子转移自由基聚合方法,其中可聚合烯烃单体在卤代聚烯烃大分子引发剂存在下聚合。 该方法的共聚物产物可用于强烈粘附到聚烯烃基材上并且非聚烯烃成膜组合物强烈粘附的成膜组合物。 共聚物可以施加到粘合促进层中的基材上,或者可以加入到含有另外的树脂化合物的成膜组合物如引物中。

    Acrylic-halogenated polyolefin copolymer adhesion promoters

    公开(公告)号:US06576722B2

    公开(公告)日:2003-06-10

    申请号:US09736507

    申请日:2000-12-13

    IPC分类号: C08J444

    摘要: The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.

    Pigment dispersions containing dispersants having pendent hydrophilic polymeric segments prepared by controlled radical polymerization
    38.
    发明授权
    Pigment dispersions containing dispersants having pendent hydrophilic polymeric segments prepared by controlled radical polymerization 失效
    含有分散剂的颜料分散体,其具有通过受控自由基聚合制备的具有亲水性亲水性聚合物链段

    公开(公告)号:US06376597B1

    公开(公告)日:2002-04-23

    申请号:US09464915

    申请日:1999-12-16

    IPC分类号: C08L5100

    摘要: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant in hydrophobic, while at least a portion of each pendent polymeric segment is hydrophilic.

    摘要翻译: 描述了包含颜料,选自水和水与至少一种有机溶剂的混合物的水性载体和颜料分散剂的颜料分散体。 通过聚合(i)至少一种具有自由基聚合性基团的预聚物和(ii)至少一种第二单体来制备颜料分散剂。 预聚物通过至少一种可自由基聚合的第一单体的受控自由基聚合,例如原子转移自由基聚合制备。 第二单体形成颜料分散剂的聚合物主链段,并且预聚物形成与主链相邻的聚合物链段。 疏水性的颜料分散剂的骨架部分,而每个侧链聚合物链段的至少一部分是亲水的。

    Block copolymers
    40.
    发明授权
    Block copolymers 失效
    嵌段共聚物

    公开(公告)号:US06288173B1

    公开(公告)日:2001-09-11

    申请号:US09325227

    申请日:1999-06-03

    IPC分类号: C08F29700

    摘要: Block copolymers containing at least two blocks are provided and comprise: (a) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., 2-ethylhexyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer, e.g., hydroxypropyl methacrylate; and (b) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., iso-butyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer. The calculated Tg of the second monomer of the block copolymer is at least 20° C. greater than the calculated Tg of the first monomer.

    摘要翻译: 提供含有至少两个嵌段的嵌段共聚物,其包含:(a)含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基可聚合单体的残基的第一嵌段,例如甲基丙烯酸2-乙基己基酯和少量的 至少一种羟基官能的烯属不饱和自由基聚合单体,例如甲基丙烯酸羟丙酯; 和(b)含有至少一种不含羟基官能团的第二烯属不饱和自由基可聚合单体残基的第二嵌段,例如甲基丙烯酸异丁酯和少量至少一种羟基官能烯属不饱和自由基聚合单体。 嵌段共聚物的第二单体的计算的Tg比第一单体的计算的Tg大至少20℃。