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31.发明授权公开(公告)号：US10300472B2
公开(公告)日：2019-05-28
申请号：US15535659
申请日：2016-10-04
Applicant: LG CHEM, LTD.
Inventor： Min Ji Choi , Mi Young Kim , Sung Shik Eom , Dong Hyun Ko , Da Won Jung , Tae Yun Kim
Abstract: The present invention relates to a catalyst composition including a phosphorous-based ligand, and a hydroformylation method using the catalyst composition. More particularly, the present invention relates to a catalyst composition, which includes two different kinds of monocoordinated phosphine ligands and a transition metal catalyst, and a hydroformylation method using the catalyst composition. In accordance with the present invention, a catalyst composition lowering a selection ratio of normal aldehyde to iso aldehyde (n/i ratio), which are generated during hydroformylation of an olefinic compound, and exhibiting superior catalytic activity and stability, and a method of hydroformylating an olefinic compound using the catalyst composition are provided.
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32.发明申请公开(公告)号：US20180272326A1
公开(公告)日：2018-09-27
申请号：US15535659
申请日：2016-10-04
Applicant: LG CHEM, LTD.
Inventor： Min Ji CHOI , Mi Young Kim , Sung Shik Eom , Dong Hyun Ko , Da Won Jung , Tae Yun Kim
CPC classification number: B01J31/2404 , B01J31/24 , B01J31/28 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/50
Abstract: The present invention relates to a catalyst composition including a phosphorous-based ligand, and a hydroformylation method using the catalyst composition. More particularly, the present invention relates to a catalyst composition, which includes two different kinds of monocoordinated phosphine ligands and a transition metal catalyst, and a hydroformylation method using the catalyst composition. In accordance with the present invention, a catalyst composition lowering a selection ratio of normal aldehyde to iso aldehyde (n/i ratio), which are generated during hydroformylation of an olefinic compound, and exhibiting superior catalytic activity and stability, and a method of hydroformylating an olefinic compound using the catalyst composition are provided.
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公开(公告)号：US09884315B2
公开(公告)日：2018-02-06
申请号：US14906426
申请日：2015-08-24
Applicant: LG CHEM, LTD.
Inventor： Myung Ji Suh , Kyong Yong Cha , Dae Heung Choi , Ye Seul Hwang , Dong Hyun Ko
IPC: B01J27/192 , B01J37/00 , B01J37/04 , B01J37/08 , C07C5/48
CPC classification number: B01J27/192 , B01J23/002 , B01J23/8876 , B01J35/002 , B01J37/0009 , B01J37/0036 , B01J37/031 , B01J37/04 , B01J37/08 , B01J37/088 , B01J2523/00 , C07C5/48 , C07C2523/04 , C07C2523/28 , C07C2523/31 , C07C2523/745 , C07C2523/75 , C07C2527/192 , C07C2529/83 , C07C11/167 , B01J2523/15 , B01J2523/31 , B01J2523/51 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845
Abstract: Disclosed are a composite oxide catalyst for preparing butadiene and a method of preparing the same. More particularly, a composite oxide catalyst, for preparing butadiene, including a metal composite oxide and AlPO4, and a method of preparing the same are disclosed.According to the present disclosure, a composite oxide catalyst for preparing butadiene, which includes a specific binder material, prevents generation of ingredients with a high boiling point, has superior catalyst strength, catalytic activity and butadiene yield, and a method of preparing the same are provided.
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34.发明授权公开(公告)号：US09707552B1
公开(公告)日：2017-07-18
申请号：US15107361
申请日：2015-10-19
Applicant: LG CHEM, LTD.
Inventor： Mi Young Kim , Min Ji Choi , Sung Shik Eom , Dong Hyun Ko , Da Won Jung , Tae Yun Kim
CPC classification number: B01J31/2404 , B01J31/185 , B01J31/20 , B01J31/2234 , B01J31/24 , B01J2231/321 , B01J2531/82 , B01J2531/822 , B01J2531/84 , C07C45/50 , C07C45/505 , C07C47/20
Abstract: Disclosed are a catalyst composition containing a phosphorous-based ligand and a hydroformylation process using the same. More specifically, disclosed are a catalyst composition containing a monodentate phosphite ligand, a monodentate phosphine ligand and a transition metal catalyst, wherein the total content of the entire ligand including the monodentate phosphite ligand and the monodentate phosphine ligand is 1 to 33 moles, based on 1 mole of the transition metal catalyst, and a hydroformylation method using the same.The present invention has an effect of providing a catalyst composition which reduces an N/I (ratio of normal to iso) selectivity of aldehydes produced by hydroformylation of an olefin-based compound and exhibits superior catalytic activity and stability, and a hydroformylation method of an olefin-based compound using the catalyst composition.
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公开(公告)号：US09234086B2
公开(公告)日：2016-01-12
申请号：US14510934
申请日：2014-10-09
Applicant: LG CHEM, LTD.
Inventor： Hyun Kyu Kim , Sung Shik Eom , Mi Yeon Lee , Dong Hyun Ko , Da Won Jung
CPC classification number: C08K5/12 , C08K5/0016 , C08K5/04 , C08K5/06 , C08K5/10 , C08K13/00 , C08K2201/014 , C08L101/00
Abstract: Disclosed is a plasticizer composition which comprises an ester-based plasticizer and an ether compound and exhibits improved workability and heat loss in proportion to content of the ether compound.
Abstract translation: 公开了一种增塑剂组合物，其包含酯类增塑剂和醚化合物，并且与醚化合物的含量成比例地显示出改进的可加工性和热损失。
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Patent Agency Ranking
公开(公告)号：US20150291496A1
公开(公告)日：2015-10-15
申请号：US14441765
申请日：2014-07-21
Applicant: LG Chem, Ltd.
Inventor： Sung Shik Eom , Min Soo Kim , Tae Yun Kim , Dong Hyun Ko
IPC: C07C45/75
CPC classification number: C07C45/75 , C07C45/86 , C07C47/263
Abstract: Disclosed is a method of preparing methylol alkanal. According to the present invention, a yield of methylol alkanal may be improved without using formaldehyde in an excess amount of a theoretical minimum molar ratio or more, formaldehyde wastewater may be reduced, and the amount of formaldehyde remainder, which may act as a hydrogenation catalyst poison, comprised in the methylol alkanal is decreased when the prepared methylol alkanal is hydrogenated resulting in improvement in efficiency of the hydrogenation.
Abstract translation: 公开了制备羟甲基链烷醛的方法。 根据本发明，可以在不使用超过理论最小摩尔比或更多的甲醛的情况下改善羟甲基链烷酸的收率，甲醛废水可能降低，甲醛剩余量可作为氢化催化剂 当制备的羟甲基链烷醛被氢化时，包含在羟甲基链烷醛中的毒素降低，从而提高氢化效率。
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37.发明授权公开(公告)号：US09127141B2
公开(公告)日：2015-09-08
申请号：US14340881
申请日：2014-07-25
Applicant: LG CHEM, LTD.
Inventor： Mi Yeon Lee , Hyun Kyu Kim , Da Won Jung , Dong Hyun Ko
IPC: C07C67/293 , C08K5/12 , C07C67/03
Abstract: Provided is a method of preparing an ester plasticizer, more particularly, a method of preparing an ester plasticizer including conducting a transesterification reaction of a compound of Chemical Formula 1 with a first alcohol of Chemical Formula 2.According to the preparation method according to an embodiment of the present invention, an ester plasticizer having high purity, yield, and process efficiency as well as excellent plasticizer properties such as processability and absorption rate may be easily prepared even under no catalyst.
Abstract translation: 提供一种制备酯增塑剂的方法，更具体地，涉及一种制备包括进行化学式1的化合物与化学式2的第一醇的酯交换反应的酯增塑剂的方法。根据实施方案的制备方法 本发明中，即使没有催化剂，也可以容易地制备纯度高，产率高，工艺效率高的增塑剂，加工性和吸收倍率等优异的增塑剂性能。
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公开(公告)号：US20140350307A1
公开(公告)日：2014-11-27
申请号：US14364559
申请日：2013-09-26
Applicant: LG CHEM, LTD.
Inventor： Sung Shik Eom , Dong Hyun Ko , Dae Chul Kim
IPC: C07C29/132 , B01J19/24
CPC classification number: C07C29/132 , B01D3/002 , B01D3/141 , B01J19/2455 , C07C29/141 , C07C29/175 , C07C29/80 , C07C45/50 , C07C45/74 , C07C45/82 , C07C47/02 , C07C31/12 , C07C47/21 , C07C31/125
Abstract: Disclosed are an apparatus and method for preparing alcohol from olefin. A reactor for hydroformylating olefin comprises a loop reactor for reducing high-boiling point components, a post-treatment device for separating aldehyde comprises a catalyst/aldehyde separator and a divided wall column (DWC) for removing remaining high-boiling point components, and a post-treatment device for separating alcohol comprises a divided wall column (DWC) for removing remaining high-boiling point components. The apparatus and method for preparing alcohol reduce production of high-boiling point components in the preparation of alcohols and efficiently remove remaining high-boiling point components, thus obtaining alcohol containing no high-boiling point components.
Abstract translation: 公开了一种从烯烃制备醇的装置和方法。 用于加氢甲酰化烯烃的反应器包括用于还原高沸点组分的环管反应器，用于分离醛的后处理装置包括用于除去剩余的高沸点组分的催化剂/醛分离器和分隔壁塔（DWC），以及 用于分离醇的后处理装置包括用于除去剩余的高沸点组分的分隔壁塔（DWC）。 制备醇的装置和方法减少了醇的制备中的高沸点成分的产生，有效地除去剩余的高沸点成分，得到不含高沸点成分的醇。
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39.发明授权Catalyst compositions for hydroformylation reaction and hydroformylation process using the same 有权用于加氢甲酰化反应的催化剂组合物和使用其的加氢甲酰化方法公开(公告)号：US08710276B2
公开(公告)日：2014-04-29
申请号：US13949800
申请日：2013-07-24
Applicant: LG Chem, Ltd.
Inventor： Dong Hyun Ko , Sung Shik Eom , O Hak Kwon , Hye Won Yang , Jae Hui Choi
CPC classification number: B01J31/2404 , B01J31/0267 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C45/50 , C07C45/505 , C07C47/02
Abstract: Disclosed are a catalyst composition for hydroformylation of olefin compounds, comprising a specific phosphine ligand and a transition metal catalyst, and a hydroformylation process using the same. Through a hydroformylation process using the catalyst composition according to the present invention, a suitable selectivity of iso-aldehyde can be maintained, catalyst stability can be improved, the amount of used ligand can be reduced and superior catalyst activity can be obtained.
Abstract translation: 公开了包含特定膦配体和过渡金属催化剂的烯烃化合物的加氢甲酰基化的催化剂组合物和使用其的加氢甲酰化方法。 通过使用根据本发明的催化剂组合物的加氢甲酰化方法，可以保持适当的异醛选择性，可以提高催化剂的稳定性，可以降低使用的配位体的量并获得优异的催化剂活性。
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公开(公告)号：US11918988B2
公开(公告)日：2024-03-05
申请号：US17613486
申请日：2020-12-24
Applicant: LG CHEM, LTD.
Inventor： Sunhwan Hwang , Jun Kyu Han , San Jin Han , Dong Hyun Ko , Kyoung Yong Cha
CPC classification number: B01J37/038 , B01J23/80 , B01J37/06 , C07C5/48 , C07C2523/80
Abstract: A method for manufacturing a catalyst for oxidative dehydrogenation reaction, a catalyst for oxidative dehydrogenation reaction, and a method for manufacturing butadiene using the same.
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