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56 条记录 (耗时 0.036 秒)

    Fluorescent whitening agents
    31.
    发明授权
    Fluorescent whitening agents 失效
    荧光增白剂

    公开(公告)号：US06458169B2

    公开(公告)日：2002-10-01

    申请号：US09767112

    申请日：2001-01-22

    申请人： Peter Rohringer ,  Georges Metzger ,  Dieter Reinehr

    发明人： Peter Rohringer ,  Georges Metzger ,  Dieter Reinehr

    IPC分类号： C07D25100

    CPC分类号： C09B23/148 ,  C07D251/68 ,  C11D3/42 ,  D06L4/621 ,  D06L4/657 ,  D06L4/75 ,  D06M13/07 ,  D06M13/358 ,  D06P1/6426 ,  D21H21/30 ,  Y10S8/919

    摘要： The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine, L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.

    摘要翻译： 本发明提供了新的具有下式的化合物：其中X为O或优选为NH; M是氢，碱金属原子，铵或由胺形成的阳离子; 每个R 1独立地是氨基酸被除去的氨基酸残基; n为1或2; 并且每个R 2独立地是氢，C 1 -C 3烷基，卤素，氰基，其中R是氢或C 1 -C 3烷基的COOR，其中R具有其先前含义的CONH-R，其中R具有其先前含义的SO 2 NH- 其中R具有其先前意义的NH-COR，其中M具有其先前含义的SO 3 M，或当n为1时，R 2也可以是其中R 3为C 1 -C 3烷基或苯基的CO-R 3;条件是将这些化合物排除在 哪一个）X是NH，n是1，R2是SO3M，其中M具有其先前的意义; 环）X是NH，n是2，一个R2是SO3M，其中M具有其先前的意义，另一个R 2是氢，甲基或卤素; orc）X是NH，n是1，R1是甘氨酸，R2是H或CO2H; ord）X是NH，n是2，每个R2是SO3M，其中M具有其先前的意义，SO3M基团在苯环中是2,5位，R1是D，L-丙氨酸，L-缬氨酸，L L-亮氨酸，L-异亮氨酸，L-苏氨酸，L-天冬氨酸，L-谷氨酸，L-苯丙氨酸，L-脯氨酸，D，L-甲硫氨酸或甘氨酸。新的4,4'-二氨基芪 - 2,2'-二磺酸化合物可用作荧光增白剂，特别是用于纸。

    Process for flameproofing polyurethanes
    35.
    发明授权
    Process for flameproofing polyurethanes 失效
    隔热聚氨酯的工艺

    公开(公告)号：US4010124A

    公开(公告)日：1977-03-01

    申请号：US564410

    申请日：1975-04-02

    申请人： Peter Hofmann ,  Peter Rohringer

    发明人： Peter Hofmann ,  Peter Rohringer

    IPC分类号： C07F9/40 ,  C08G18/38 ,  C08K5/5333 ,  C08K5/53

    CPC分类号： C07F9/4075 ,  C07F9/40 ,  C08G18/388 ,  C08K5/5333

    摘要： A process for flameproofing polyurethanes, particularly polyurethane foams, is provided. It consists in adding a reaction product from dimethyl methanephosphonate, an aliphatic diol or triol and a lower epoxide to the polyurethane components. These reaction products are non-uniform mixtures of different esters of methane phosphonic acid.

    摘要翻译： 提供了一种用于隔热聚氨酯，特别是聚氨酯泡沫塑料的方法。 它包括将甲基膦酸二甲酯，脂族二醇或三醇和较低环氧化物的反应产物加入到聚氨酯组分中。 这些反应产物是不同的甲烷膦酸酯的不均匀混合物。

    Compositions of fluorescent whitening agents
    36.
    发明授权
    Compositions of fluorescent whitening agents 失效
    荧光增白剂组合物

    公开(公告)号：US07731820B2

    公开(公告)日：2010-06-08

    申请号：US11665886

    申请日：2005-10-17

    申请人： Robert Cockcroft ,  Ted Deisenroth ,  Peter Rohringer ,  Winfried Steffen

    发明人： Robert Cockcroft ,  Ted Deisenroth ,  Peter Rohringer ,  Winfried Steffen

    IPC分类号： D21H21/30 ,  D21H17/37 ,  D21H17/53

    CPC分类号： D21H21/30 ,  D21H17/37 ,  D21H17/53

    摘要： The invention relates to a composition comprising a) at least one water-soluble fluorescent whitening agent, b) a polymer formed from an ethylenically unsaturated monomer or monomer blend, characterized in that at least one monomer is acrylamide and the water-soluble polymer has an average (weight average) molecular weight of between 500 and 49,000, optionally, c) polyethylene glycol with a weight average molecular weight of between 500 and 6000 and d) water and the use of the composition for the fluorescent whitening of paper in coating and size press or film press applications.

    摘要翻译： 本发明涉及包含a）至少一种水溶性荧光增白剂的组合物，b）由烯属不饱和单体或单体共混物形成的聚合物，其特征在于至少一种单体是丙烯酰胺，并且水溶性聚合物具有 平均（重均分子量）在500和49,000之间，任选地，c）重均分子量在500和6000之间的聚乙二醇和d）水，并且使用组合物用于涂布和尺寸的纸的荧光增白 印刷机或胶卷机应用。

    Formulations of fluorescent whitening agents
    39.
    发明授权
    Formulations of fluorescent whitening agents 失效
    荧光增白剂的配方

    公开(公告)号：US06620294B1

    公开(公告)日：2003-09-16

    申请号：US10049030

    申请日：2002-02-08

    申请人： Olli Juhani Jokinen ,  Rainer Hans Traber ,  Peter Rohringer

    发明人： Olli Juhani Jokinen ,  Rainer Hans Traber ,  Peter Rohringer

    IPC分类号： D21H1100

    CPC分类号： D21H21/30 ,  C08K5/0041 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1007 ,  C08L29/04

    摘要： Stable formulations of fluorescent whitening agents are described. These contain a) 2 to 20% by weight of a fluorescent whitening agent of formula (1) in which R1 is hydrogen, C1-C5-alkyl, C1-C5-alkoxy or halogen and M is hydrogen, an alkali metal, ammonium or magnesium, b) 4 to 30% by weight of an unmodified or modified polyvinyl alcohol, c) 55 to 94% by weight of water and d) 0 to 20% weight of further additives, polyethylene glycol being excluded. A process for the preparation of the formulations and their use for whitening paper materials is also described.

    摘要翻译： 描述荧光增白剂的稳定配方。 这些包含a）2至20重量％的式（1）荧光增白剂，其中R 1是氢，C 1 -C 5 - 烷基，C 1 -C 5 - 烷氧基或卤素，M是氢，碱金属，铵或 镁，b）4至30重量％的未改性或改性的聚乙烯醇，c）55至94重量％的水和d）0-20重量％的其它添加剂，不包括聚乙二醇。 还描述了制备制剂的方法及其用于增白纸材料的用途。

    Fluorescent whitening agents
    40.
    发明授权
    Fluorescent whitening agents 失效
    荧光增白剂

    公开(公告)号：US06210449B1

    公开(公告)日：2001-04-03

    申请号：US09381468

    申请日：1999-09-20

    申请人： Peter Rohringer ,  Georges Metzger ,  Dieter Reinehr

    发明人： Peter Rohringer ,  Georges Metzger ,  Dieter Reinehr

    IPC分类号： C07D25100

    CPC分类号： C09B23/148 ,  C07D251/68 ,  C11D3/42 ,  D06L4/621 ,  D06L4/657 ,  D06L4/75 ,  D06M13/07 ,  D06M13/358 ,  D06P1/6426 ,  D21H21/30 ,  Y10S8/919

    摘要： The present invention provides new compounds having formula (1), in which X is 0 or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine; L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.

    摘要翻译： 本发明提供具有式（1）的新化合物，其中X为0或优选为NH; M是氢，碱金属原子，铵或由胺形成的阳离子; 每个R 1独立地是氨基酸被除去的氨基酸残基; n为1或2; 并且每个R 2独立地是氢，C 1 -C 3烷基，卤素，氰基，其中R是氢或C 1 -C 3烷基的COOR，其中R具有其先前含义的CONH-R，其中R具有其先前含义的SO 2 NH- 其中R具有其先前含义的NH-COR，其中M具有其先前含义的SO 3 M，或当n为1时，R 2也可以是其中R 3为C 1 -C 3烷基或苯基的CO-R 3; 条件是排除这些化合物，其中a）X是NH，n是1，R2是其中M具有其先前意义的SO 3 M; 或b）X是NH，n是2，一个R2是SO3M，其中M具有其先前的含义，另一个R 2是氢，甲基或卤素; 或c）X是NH，n是1，R1是甘氨酸，R2是H或CO2H; 或d）X是NH，n是2，每个R2是SO3M，其中M具有其先前的意义，SO 3 M基团在苯环中是2.5位，R 1是D，L-丙氨酸，L-缬氨酸， L-亮氨酸 L-异亮氨酸，L-苏氨酸，L-天冬氨酸，L-谷氨酸，L-苯丙氨酸，L-脯氨酸，D，L-甲硫氨酸或甘氨酸。 大多数新类的4,4'-二氨基芪-2,2'-二磺酸化合物可用作荧光增白剂，特别是用于纸。