公开(公告)号：US08329964B2

公开(公告)日：2012-12-11

申请号：US12665140

申请日：2009-03-27

Applicant: Michel Devic ,  Dominique Guillet ,  Emmanuel Guiraud ,  Laurent Wendlinger

Inventor： Michel Devic ,  Dominique Guillet ,  Emmanuel Guiraud ,  Laurent Wendlinger

IPC: C07C17/23

CPC classification number: C07C21/18 ,  B01J21/04 ,  B01J23/866 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/26 ,  C07C17/25 ,  C07C17/354 ,  C07C19/08

Abstract: The invention relates to a gas-phase continuous method for preparing 2,3,3,3-tetrafluoro-1-propene, said method comprising the following steps: (i) hydrogenation of hexafluoropropylene to form 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the previous step to 1,2,3,3,3-pentafluoropropene-1; (iii) hydrogenation of the 1,2,3,3,3-pentafluoropropene-1 obtained in the previous step to form 1,1,1,2,3-pentafluoropropane; and (iv) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the previous step to form 2,3,3,3-tetrafluoro-1-propene.

Abstract translation: 本发明涉及一种制备2,3,3,3-四氟-1-丙烯的气相连续方法，所述方法包括以下步骤：（i）六氟丙烯的氢化形成1,1,1,2,3 ，3-六氟丙烷; （ii）将上一步获得的1,1,1,2,3,3-六氟丙烷的脱氟化氢化为1,2,3,3,3-五氟丙烯-1; （iii）在前一步骤中获得的1,2,3,3,3-五氟丙烯-1的氢化形成1,1,1,2,3-五氟丙烷; 和（iv）前一步骤中获得的1,1,1,2,3-五氟丙烷的脱氟化氢，形成2,3,3,3-四氟-1-丙烯。

公开(公告)号：US08252964B2

公开(公告)日：2012-08-28

申请号：US13001663

申请日：2009-06-08

Applicant: Michel Devic ,  Anne Pigamo ,  Laurent Wendlinger

Inventor： Michel Devic ,  Anne Pigamo ,  Laurent Wendlinger

IPC: C07C17/38

CPC classification number: C07C17/389 ,  C07C21/18

Abstract: The subject of the invention is a process for the purification of 2,3,3,3-tetrafluoro-1-propene (HFO-1234yf). More particularly, it relates to a purification process in which 2,3,3,3-tetrafluoro-1-propene, comprising impurities based on halogen compounds, is brought into contact with an adsorbent, preferably molecular sieves and advantageously molecular sieves having a pore opening with an average diameter between 5 and 11 Å, preferably between 5 and 9 Å.

Abstract translation: 本发明的主题是用于纯化2,3,3,3-四氟-1-丙烯（HFO-1234yf）的方法。 更具体地说，本发明涉及一种纯化方法，其中将包含基于卤素化合物的杂质的2,3,3,3-四氟-1-丙烯与吸附剂，优选分子筛和有利的分子筛接触，所述分子筛具有孔 平均直径在5和11埃之间，优选在5和9之间。

公开(公告)号：US20110105809A1

公开(公告)日：2011-05-05

申请号：US13001663

申请日：2009-06-08

Applicant: Michel Devic ,  Anne Pigamo ,  Laurent Wendlinger

Inventor： Michel Devic ,  Anne Pigamo ,  Laurent Wendlinger

IPC: C07C17/389

CPC classification number: C07C17/389 ,  C07C21/18

Abstract: The subject of the invention is a process for the purification of 2,3,3,3-tetrafluoro-1-propene (HFO-1234yf). More particularly, it relates to a purification process in which 2,3,3,3-tetrafluoro-1-propene, comprising impurities based on halogen compounds, is brought into contact with an adsorbent, preferably molecular sieves and advantageously molecular sieves having a pore opening with an average diameter between 5 and 11 Å, preferably between 5 and 9 Å.

Abstract translation: 本发明的主题是用于纯化2,3,3,3-四氟-1-丙烯（HFO-1234yf）的方法。 更具体地说，本发明涉及一种纯化方法，其中将包含基于卤素化合物的杂质的2,3,3,3-四氟-1-丙烯与吸附剂，优选分子筛和有利的分子筛接触，所述分子筛具有孔 平均直径在5和11埃之间，优选在5和9之间。

公开(公告)号：US20090270659A1

公开(公告)日：2009-10-29

申请号：US12302659

申请日：2007-05-09

Applicant: Bertrand Collier ,  Stephanie Amerio ,  Michel Devic

Inventor： Bertrand Collier ,  Stephanie Amerio ,  Michel Devic

IPC: C07C21/18 ,  C07C19/08 ,  B01J12/00

CPC classification number: B01J8/0446 ,  B01J2208/00274 ,  B01J2219/00006 ,  C07C17/206 ,  C07C17/21 ,  C07C17/383 ,  C07C19/08

Abstract: The invention relates to a method for producing hydrofluorocarbons. The method comprises a step of reacting at least one hydro(fluoro)chlorocarbon or chlorocarbon with hydrofluoric acid in a gaseous phase in the presence of a catalyst, and a step of separating fluorination reaction products from the mixture. The method is characterized in that the gaseous flow from the reaction is compressed by means of a compressor before being subjected to the separation step. The invention also relates to a device for implementing the method.

Abstract translation: 本发明涉及一种生产氢氟烃的方法。 该方法包括在催化剂存在下使气态中至少一种氢（氟）氯化碳或氯代烃与氢氟酸反应的步骤和从混合物中分离氟化反应产物的步骤。 该方法的特征在于，在进行分离步骤之前，来自反应的气流通过压缩机被压缩。 本发明还涉及一种用于实现该方法的装置。

公开(公告)号：US20060198771A1

公开(公告)日：2006-09-07

申请号：US11403655

申请日：2006-04-13

Applicant: Michel Devic

Inventor： Michel Devic

IPC: B01J19/00 ,  B01J19/18

CPC classification number: B01J23/38 ,  B01F3/04539 ,  B01F3/04836 ,  B01F7/00241 ,  B01F7/00633 ,  B01F2003/04638 ,  B01F2003/04673 ,  B01J8/006 ,  B01J8/222 ,  B01J8/228 ,  B01J19/1881 ,  B01J23/10 ,  B01J23/40 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J2208/00176 ,  B01J2208/00212 ,  B01J2219/185 ,  C01B15/029

Abstract: This invention concerns a device comprising a cylindrical vertical stirred reactor (v), provided with centrifugal turbines (a) arranged along a single vertical agitated shaft, and its uses for implementing any process whereby several gas constituents are made to react in the presence of a solid suspended in a liquid phase. The device is particularly suited for directly making hydrogen peroxide.

Abstract translation: 本发明涉及一种装置，该装置包括一个圆柱形立式搅拌反应器（v），该反应器设有沿着单个垂直搅拌轴设置的离心式涡轮机（a）及其用于实施任何方法的用途，其中若干气体成分在 固体悬浮在液相中。 该装置特别适用于直接制造过氧化氢。

公开(公告)号：US06509486B2

公开(公告)日：2003-01-21

申请号：US09987045

申请日：2001-11-13

Applicant: Michel Devic

Inventor： Michel Devic

IPC: C07C5018

CPC classification number: C07C66/02

Abstract: The present invention relates to a process for the synthesis of 2-carboxyanthraquinone from 2-ethylanthraquinone by oxidation of the said ethyl group by means of a nitric acid solution. Anthra-quinones are used in the manufacture of oxygen-absorbing films which make possible the preparation of packagings suited to the preservation of oxygen-sensitive products, such as foodstuffs.

公开(公告)号：US6019870A

公开(公告)日：2000-02-01

申请号：US737684

申请日：1997-01-17

Applicant: Michel Devic ,  Jean-Pierre Schirmann

Inventor： Michel Devic ,  Jean-Pierre Schirmann

IPC: D21C9/10 ,  D21C9/16 ,  D21C9/147

CPC classification number: D21C9/1026 ,  D21C9/1042 ,  D21C9/163

Abstract: A process of dignifying lignocellulosic pulp with oxygen followed by treatment of the delignified pulp with a chelating agent, followed by washing, followed by treatment with hydrogen peroxide at an alkaline pH in the presence of an alkali metal silicate at a temperature greater than 100.degree. C. and a pressure greater than 1.5 times the saturated vapor pressure.

Abstract translation: PCT No.PCT / FR95 / 00494 Sec。 371日期1997年1月17日 102（e）日期1997年1月17日PCT提交1995年4月14日PCT公布。 出版物WO95 / 31599 日期1995年11月23日一种使木质纤维素纸浆氧化的方法，然后用螯合剂处理脱木素纸浆，然后洗涤，随后在碱性pH下在碱金属硅酸盐存在下用过氧化氢处理温度 大于100℃，压力大于饱和蒸汽压力的1.5倍。

公开(公告)号：US5219601A

公开(公告)日：1993-06-15

申请号：US850127

申请日：1992-03-12

Applicant: Michel Devic

Inventor： Michel Devic

IPC: A23L1/277 ,  A23L1/308

CPC classification number: A23L5/49

Abstract: A variety of plant materials adopted for processing into, e.g., low-calorie vegetable fibers and dietary flours, are bleached by (1) prebleaching such plant material in a first aqueous solution containing an alkaline agent and hydrogen peroxide, the alkaline agent being present in solution in such amount that the final pH of the resulting suspension is no greater than 9, (2) filtering and washing the suspension produced in step (1) with water, to an effectiveness of at least 50%, (3) bleaching the material obtained after step (2) in a second aqueous solution containing an alkaline agent and hydrogen peroxide, the alkaline agent being present in solution in such amount that the final pH of the resulting suspension is no greater than 8.5, and, characteristically, (4) filtering and washing the suspension produced in step (3) with water.

Abstract translation: 用于加工成例如低卡路里植物纤维和膳食面粉的各种植物材料通过（1）将这种植物材料预漂白在含有碱性试剂和过氧化氢的第一水溶液中而漂白，碱性试剂存在于 溶液的量使所得悬浮液的最终pH不大于9，（2）用水过滤和洗涤步骤（1）中产生的悬浮液，有效性至少为50％，（3）漂白材料 在步骤（2）之后在含有碱性试剂和过氧化氢的第二水溶液中获得的碱性试剂以使所得悬浮液的最终pH不大于8.5的量存在于溶液中，特征在于（4） 用水过滤和洗涤步骤（3）中产生的悬浮液。

公开(公告)号：US4496760A

公开(公告)日：1985-01-29

申请号：US523945

申请日：1983-08-17

Applicant: Michel Devic

Inventor： Michel Devic

IPC: C07C51/00 ,  C01B7/19 ,  C01B35/06 ,  C07C51/44 ,  C07C51/487 ,  C07C65/32 ,  C07C65/34 ,  C07C67/00 ,  C07C59/76

CPC classification number: C07C51/44 ,  C07C51/487

Abstract: A process for the decomposition of complexes of ortho-benzoyl benzoic acids, hydrogen fluoride, and boron trifluoride, whether or not the ortho-benzoyl benzoic acid is substituted, is disclosed wherein the ortho-benzoyl benzoic acid is obtained separately from the hydrogen fluoride and boron trifluoride. This process is characterized in that the complex is treated with an inert solvent at a temperature of at least 20.degree. C., in a distillation column having at least about 8 theoretical plates whereby the solvent reflux is operated at a rate equal to about 5 to about 40 times the weight of the feed delivery rate of the column.The process of the present invention also makes it possible to recover hydrogen fluoride and boron trifluoride for reuse as catalysts in the synthesis of ortho-benzoyl benzoic acid without causing decomposition of the acid.

Abstract translation: 公开了分离邻苯甲酰苯甲酸，氟化氢和三氟化硼的络合物的方法，无论邻苯甲酰苯甲酸是否被取代，其中邻苯甲酰苯甲酸分别从氟化氢和 三氟化硼。 该方法的特征在于，在至少20℃的温度下，在具有至少约8理论塔板的蒸馏塔中用惰性溶剂处理络合物，由此溶剂回流以等于约5至 是柱的饲料输送速率的约40倍。 本发明的方法还可以在不引起酸分解的情况下回收氟化氢和三氟化硼作为合成邻苯甲酰苯甲酸的催化剂。

公开(公告)号：US4379092A

公开(公告)日：1983-04-05

申请号：US324520

申请日：1981-11-24

Applicant: Michel Devic

Inventor： Michel Devic

IPC: C07C50/16 ,  B01J27/00 ,  B01J27/12 ,  C07B61/00 ,  C07C45/00 ,  C07C46/00 ,  C07C50/24 ,  C07C65/34 ,  C07C67/00 ,  C07C50/18 ,  C09B1/00

CPC classification number: C07C65/34 ,  C07C46/00

Abstract: A process for the preparation of anthraquinone compounds by condensation of phthalic anhydride with a benzene derivative wherein a mixture of hydrofluoric acid and boron trifluoride is utilized as catalyst.

Abstract translation: 用邻苯二甲酸酐与苯衍生物缩合制备蒽醌化合物的方法，其中使用氢氟酸和三氟化硼的混合物作为催化剂。