公开(公告)号：US5057620A

公开(公告)日：1991-10-15

申请号：US563330

申请日：1990-08-07

申请人： Yoshio Inoue ,  Naoki Omura

发明人： Yoshio Inoue ,  Naoki Omura

IPC分类号： C07F7/08 ,  C08G77/38

CPC分类号： C07F7/0885 ,  C07F7/0858

摘要： A process for producing a linear organotetrasiloxane comprises the step of hydrolyzing a dihalotetrasiloxane in the presence of an organic compound having at least one epoxy radical. The process prevents effectively the by-production of high molecular weight or cyclic condensates, and yields a linear organotetrasiloxane having a high OH number and high activity.

摘要翻译： 线性有机四硅氧烷的制备方法包括在具有至少一个环氧基的有机化合物的存在下水解二卤代四硅氧烷的步骤。 该方法有效地防止高分子量或环状缩合物的副产物，并产生具有高OH值和高活性的直链有机基四硅氧烷。

公开(公告)号：US5013800A

公开(公告)日：1991-05-07

申请号：US425267

申请日：1989-10-23

申请人： Yoshio Inoue

发明人： Yoshio Inoue

IPC分类号： C08L83/04 ,  C08L83/08 ,  C08L83/10 ,  C08L83/12

CPC分类号： C08L83/10 ,  C08L83/04 ,  C08L83/08 ,  C08L83/12 ,  C08G77/24 ,  C08G77/46 ,  C08G77/70 ,  Y10S528/901

摘要： A novel room temperature-curable organopolysiloxane-based composition is proposed which is capable of giving a surface coating highly insusceptible to surface stain even by exposure over years. The composition comprises: (A) a block copolymer composed of dimethylsiloxane units and trifunctional siloxane units of which the organic group is a phenyl group or a fluorine containing aliphatic group, in a specified molar proportion; (B) an organosilane compound having hydrolyzable groups; and (C) a polyoxyalkylene-modified organosiloxane compound of the formula (Me.sub.3 SiO--).sub.2 SiR.sup.4 --C.sub.3 H.sub.6 --(--O--R.sup.5 --).sub.b --O--SiR.sup.6.sub.a X.sub.3-a, in which Me is a methyl group, R.sup.4 is a methyl group or trimethylsiloxy group, R.sup.5 is an ethylene group or propylene group, R.sup.6 is a monovalent hydrocarbon group, X is a hydrolyzable group, the subscript a is zero or 1 and the subscript b is a positive integer not exceeding 50, with optional addition of a condensation catalyst.

摘要翻译： 提出了一种新型的室温可固化的有机基聚硅氧烷基组合物，其能够使表面涂层甚至在多年时间内暴露于表面污渍也是不易感染的。 该组合物包括：（A）由特定摩尔比例的由二甲基硅氧烷单元和有机基团为苯基或含氟脂族基团的三官能硅氧烷单元组成的嵌段共聚物; （B）具有可水解基团的有机硅烷化合物; 和（C）式（Me3SiO - ）2SiR4-C3H6 - （ - O-R5-）bO-SiR6aX3-a的聚氧化烯改性的有机硅氧烷化合物，其中Me是甲基，R4是甲基或三甲基甲硅烷氧基 R5是亚乙基或亚丙基，R6是一价烃基，X是可水解基团，下标a是0或1，下标b是不超过50的正整数，任选地加入缩合催化剂。

公开(公告)号：US4987155A

公开(公告)日：1991-01-22

申请号：US557824

申请日：1990-07-26

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Tsuneo Kimura

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Tsuneo Kimura

IPC分类号： C08J9/02 ,  C08L83/04

CPC分类号： C08J9/02 ,  C08L83/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/16 ,  C08G77/62 ,  C08J2383/04

摘要： The invention provides a foamable organopolysiloxane composition capable of giving, by foaming and curing at room temperature, a silicone rubber foam of high foaming expansion having very uniform and dense cellular structure. The composition is prepared by a process comprising the steps of: (A) compounding an .alpha.,.omega.-dihydroxy dimethylpolysiloxane with a reinforcing silica filler, hexamethyl disilazane and water as the hydrolysis agent of the silazane to give a compound; (B) removing ammonia in the compound formed by the hydrolysis of the silazane compound as completely as possible; and (C) compounding the compound with a polyhydroxy methylpolysiloxane, an organohydrogenpolysiloxane and a platinum compound as a catalyst for the dehydrogenation reaction between the silanolic hydroxy groups and the silicon-bonded hydrogen atoms to produce hydrogen as the foaming gas.

摘要翻译： 本发明提供一种可发泡的有机聚硅氧烷组合物，其能够通过在室温下发泡和固化得到具有非常均匀且致密的细胞结构的高发泡膨胀的硅橡胶泡沫。 通过包括以下步骤的方法制备组合物：（A）将α，ω-二羟基二甲基聚硅氧烷与增强二氧化硅填料，六甲基二硅氮烷和水混合，作为硅氮烷的水解试剂，得到化合物; （B）通过尽可能完全地水解硅氮烷化合物形成的化合物中除去氨; 和（C）将化合物与多羟基甲基聚硅氧烷，有机氢聚硅氧烷和铂化合物混合，作为硅烷醇羟基与硅键合的氢原子之间的脱氢反应的催化剂，以产生氢作为发泡气体。

公开(公告)号：US4983451A

公开(公告)日：1991-01-08

申请号：US177082

申请日：1988-04-04

申请人： Morihiko Sugino ,  Yoshio Inoue

发明人： Morihiko Sugino ,  Yoshio Inoue

IPC分类号： C04B35/83

CPC分类号： C04B35/83 ,  Y10T428/2918 ,  Y10T428/292 ,  Y10T428/2982 ,  Y10T428/30 ,  Y10T442/2738 ,  Y10T442/655 ,  Y10T442/658 ,  Y10T442/667 ,  Y10T442/673

摘要： Disclosed herein are a carbon fiber-reinforced carbon composite material composed of carbon as a matrix and carbon fiber as a reinforcement, and also a process for producing the same. The composite material is produced by coating nonwoven fabrics of carbon fiber or a blend of carbon fiber and organic fiber with a filler-containing liquid, laminating the nonwoven fabrics one over another, and subjecting the laminated nonwoven fabrics to needle punching repeatedly with a plurality of needles, thereby yielding a prepreg of three-dimensional structure, and carbonizing and calcining the thus obtained prepreg.

摘要翻译： 本发明公开了一种由作为基质的碳和碳纤维作为增强体构成的碳纤维增强碳复合材料，以及其制造方法。 该复合材料通过将碳纤维或碳纤维与有机纤维的混合物的无纺织物与含有填料的液体一起涂布，将无纺织物层压而成，并将多层无纺布反复进行针刺， 针，由此得到三维结构的预浸料坯，并将由此得到的预浸料坯进行碳化和煅烧。

公开(公告)号：US4734479A

公开(公告)日：1988-03-29

申请号：US27263

申请日：1987-03-18

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

IPC分类号： C08K5/00 ,  C08K3/00 ,  C08K5/05 ,  C08K5/5425 ,  C08K5/5465 ,  C08K5/57 ,  C08L1/00 ,  C08L23/00 ,  C08L27/00 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07 ,  C08L101/00 ,  C08G77/06

CPC分类号： C08K5/5465 ,  C08L83/04 ,  C08G77/16 ,  C08G77/18 ,  C08G77/26 ,  Y10S528/901

摘要： The essential components in the inventive room temperature-curable organopolysiloxane composition are: (A-1) a diorganopolysiloxane of which each terminal silicon atom has a silanolic hydroxy group or two alkoxy groups; (A-2) a filler; (A-3) an alkenyloxy silane, e.g. methyl tri)isopropenyloxy)silane; (A-4) a guanidino-containing organosilicon compound, e.g. 3-(tetramethylguanidino)propyl trimethoxy silane; (A-5) an alcohol, e.g. methyl or ethyl alcohol; (B) an organosilicon compound having a silicon-bonded hydrogen atom; and (C) an organic tin compound as a catalyst. By virtue of the unique formulation above, the composition is very stable in storage in a moisture-free condition for a long period of time without losing the high curability when exposed to a moisture-containing atmosphere.

摘要翻译： 本发明的室温可固化的有机基聚硅氧烷组合物中的主要成分是：（A-1）每个末端硅原子具有硅烷醇羟基或两个烷氧基的二有机聚硅氧烷; （A-2）填料; （A-3）烯氧基硅烷，例如 甲基三）异丙烯氧基）硅烷; （A-4）含胍基的有机硅化合物，例如 3-（四甲基胍基）丙基三甲氧基硅烷; （A-5）醇，例如 甲基或乙醇; （B）具有硅键合氢原子的有机硅化合物; 和（C）有机锡化合物作为催化剂。 由于上述独特的配方，组合物在无水条件下长期储存时非常稳定，而在暴露于含湿气氛时不会损失高固化性。

公开(公告)号：US4721765A

公开(公告)日：1988-01-26

申请号：US30693

申请日：1987-03-25

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Koji Yokoo

IPC分类号： C08K5/00 ,  C08K5/05 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/544 ,  C08K5/5465 ,  C08K5/57 ,  C08L1/00 ,  C08L23/00 ,  C08L27/00 ,  C08L83/04 ,  C08L83/06 ,  C08L101/00 ,  C08G77/06

CPC分类号： C08K5/5465 ,  C08L83/04 ,  C08G77/16 ,  C08G77/18 ,  C08G77/26

摘要： The invention provides a room temperature-curable organopolysiloxane composition curable into a rubbery elastomer, which has excellent storage stability under a moisture-free condition without losing high curability. The composition comprises, in addition to the conventional essential ingredients of a hydroxy- or alkoxy-terminated diorganopolysiloxane, filler, triisopropenyloxy silane compound as a crosslinking agent and a guanidino-containing organosilicon compound as a curing aid, an amino-containing silane compound such as MeSi[NH--C.sub.3 H.sub.6 --Si(OEt).sub.3 ].sub.3 and MeSi[NH--C.sub.2 H.sub.4 NHC.sub.3 H.sub.6 --Si(OMe).sub.3 ].sub.3.

摘要翻译： 本发明提供可固化到橡胶弹性体中的室温可固化的有机基聚硅氧烷组合物，其在无湿度条件下具有优异的储存稳定性，而不损失高固化性。 除了作为交联剂的填充剂，作为交联剂的三异丙烯基氧基硅烷化合物和作为固化助剂的含胍基的有机硅化合物的常规必需成分之外，还包含含氨基的硅烷化合物，例如 MeSi [NH-C3H6-Si（OEt）3] 3和MeSi [NH-C2H4NHC3H6-Si（OMe）3] 3。

公开(公告)号：US4695617A

公开(公告)日：1987-09-22

申请号：US837588

申请日：1986-03-07

申请人： Yoshio Inoue ,  Masatoshi Arai ,  Shinichi Sato ,  Koji Yokoo

发明人： Yoshio Inoue ,  Masatoshi Arai ,  Shinichi Sato ,  Koji Yokoo

IPC分类号： C08L83/00 ,  C08K5/5425 ,  C08K5/5465 ,  C08L83/04 ,  C08L83/06 ,  H01B3/46 ,  C08G77/20

CPC分类号： C08K5/5465 ,  C08K5/54 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08G77/26 ,  Y10S528/901

摘要： The room temperature-curable organopolysiloxane composition of the invention capable of giving a cured rubber can be used advantageously as an insulating material in electric and electronic instruments without causing troubles in contact points which is unavoidable with conventional compositions. The inventive composition is formulated with (a) a diorganopolysiloxane terminated at the molecule molecular chain ends each with a silanolic hydroxy group, (b) an alkenyloxy, e.g. isopropenyloxy, containing silane and (c) a guanidino-substituted organosilicon compound and these components are specified either by the upper limit of the content of low molecular constituents having a specified vapor pressure or higher or the upper limit of the vapor pressure of the compound per se so that the electric contact points near the insulation with the composition are free from exposure to the vapor of organosilicon compounds which may be deposited as an oxide of silicon by sparks.

摘要翻译： 能够提供固化橡胶的本发明的室温可固化的有机基聚硅氧烷组合物可以有利地用作电气和电子仪器中的绝缘材料，而不会在常规组合物中不可避免地引起接触点的麻烦。 本发明的组合物配制成（a）在分子分子链处终止的二有机聚硅氧烷，每个末端具有硅烷醇羟基，（b）链烯氧基，例如， 含有硅烷的异丙烯氧基和（c）胍基取代的有机硅化合物，并且这些组分由具有特定蒸气压或更高的低分子量成分的含量的上限或化合物的蒸气压的上限规定 使得与组合物绝缘附近的电接触点不会暴露于有机硅化合物的蒸气中，有机硅化合物可以通过火花作为硅的氧化物沉积。

公开(公告)号：US4579636A

公开(公告)日：1986-04-01

申请号：US728566

申请日：1985-04-29

申请人： Yoshio Inoue ,  Takehide Okami

发明人： Yoshio Inoue ,  Takehide Okami

IPC分类号： C09K3/10 ,  C08K5/5425 ,  C08K5/548 ,  C08L83/00 ,  C08L83/04 ,  C08L83/06 ,  C09J183/00 ,  C08F2/46

CPC分类号： C08K5/54 ,  C08K5/07 ,  C08G77/16 ,  C08G77/28

摘要： The silicone rubber composition of the invention essentially comprises (a) a silanolic hydroxy-terminated diorganopolysiloxane, (b) a hydrolyzable vinyl silane compound such as a vinyl trialkoxysilane and (c) an organopolysiloxane having at least two mercapto groups in the form of, for example, 3-mercaptopropyl groups, in a molecule. The composition can be cured by two different mechanisms of crosslink formation one by the condensation reaction between the silanol groups in (a) and the hydrolyzable groups in (b) in the presence of atmospheric moisture and the other between the vinyl groups in (b) and mercapto groups in (c) under irradiation with ultraviolet light. The two-way cruability of the composition greatly expands the application fields of the silicone rubber composition.

摘要翻译： 本发明的硅橡胶组合物基本上包含（a）硅烷醇羟基封端的二有机聚硅氧烷，（b）可水解的乙烯基硅烷化合物如乙烯基三烷氧基硅烷和（c）具有至少两个巯基的有机聚硅氧烷， 例如，分子中的3-巯基丙基。 通过两种不同的交联形成机理可以通过（a）中的硅烷醇基团与（b）中的水解基团在大气水分存在下的水解性基团和（b）中的乙烯基基团之间的缩合反应， （c）中的巯基。 组合物的双向可靠性大大扩展了硅橡胶组合物的应用领域。

公开(公告)号：US4117751A

公开(公告)日：1978-10-03

申请号：US745118

申请日：1976-11-26

申请人： Yoshio Inoue

发明人： Yoshio Inoue

IPC分类号： B23Q35/128 ,  G03F1/00 ,  G03F1/90 ,  B26D3/08

CPC分类号： G03F1/68 ,  B23Q35/128 ,  Y10T83/0252 ,  Y10T83/0333 ,  Y10T83/875

摘要： The invention relates to an apparatus for incising on a film to be processed the precise contour of a required photographic image so as to obtain a process block for prints in which such photographic image is to be inserted. The apparatus comprises a data input unit capable of detecting the precise contour by causing a light pen to trace the general contour of a required image on a photocopy; an output unit capable of incising the contour on a film to be processed by receiving signals of the positions of the precise contour detected by the input unit; and a control unit capable of performing a control operation, such as relay, comparison, etc. of the signals between the input unit and the output unit.

摘要翻译： 本发明涉及一种用于切割要处理所需摄影图像的精确轮廓的胶片的装置，以便获得其中要插入这种照相图像的打印件的处理块。 该装置包括能够通过使光笔在复印件上追踪所需图像的一般轮廓来检测精确轮廓的数据输入单元; 输出单元，其能够通过接收由所述输入单元检测到的所述精确轮廓的位置的信号来切割要处理的胶片上的轮廓; 以及控制单元，其能够执行诸如输入单元和输出单元之间的信号的继电器，比较等的控制操作。

公开(公告)号：US4115329A

公开(公告)日：1978-09-19

申请号：US740056

申请日：1976-11-08

申请人： Atsumi Noshiro ,  Yoshio Inoue

发明人： Atsumi Noshiro ,  Yoshio Inoue

IPC分类号： C08L61/00 ,  C08L61/04 ,  C09D11/00 ,  C09D11/02 ,  C09D11/033 ,  C09D11/10 ,  C09D11/103 ,  C08L93/00

CPC分类号： C09D11/103

摘要： Printing ink compositions which are suitable for use in the method of dry-planographic printing on a high-speed web offset press are provided wherein an ink vehicle comprises from 1 to 70% by weight of a silicone-modified phenolic resin prepared by reacting an oil-soluble solid phenolic resin with an amino group-containing organopolysiloxane. Said ink compositions are capable of producing copy sheets without the occurrence of scumming and the piling of ink throughout a long continuous operation by the said printing method.

摘要翻译： 提供了适用于高速卷筒纸胶版印刷机上的干 - 平版印刷方法的印刷油墨组合物，其中油墨载体包含1-70重量％的硅氧烷改性酚醛树脂，其通过使油 可溶性固体酚醛树脂与含氨基的有机聚硅氧烷。 所述油墨组合物能够通过所述印刷方法在长时间的连续操作中产生复印纸，而不会发生浮渣和油墨堆积。