摘要:
The present invention relates to aqueous isocyanate emulsions and their use as binders in the production of shaped articles. These emulsions contain(A) from 80 to 20% by weight, based on the total emulsion, of water;(B) from 18 to 79% by weight, based on the total emulsion, of an organic polyisocyanate;(C) from 0.5 to 15% by weight, based on the total emulsion of a sulfonic acid corresponding to the formula:R.sub.1 --SO.sub.3 H).sub.nwhereinn represents the integers 1 or 2, andR.sub.1 represents an aromatic hydrocarbon radical containing from 6 to 14 carbon atoms, an aliphatic hydrocarbon radical containing from 10 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical containing from 6 to 15 carbon atoms, an araliphatic hydrocarbon radical containing from 7 to 15 carbon atoms or an alkaromatic hydrocarbon radical containing from 7 to 24 carbon atoms; and(D) from 0 to 10% by weight, based on the polyisocyanate, of a nonionic, surface-active agent as an emulsifier.
摘要:
The novel AOX-free process for imparting wet strength to paper with water-dispersible polyisocyanates is distinguished by a good wet-strength effect, even under mild drying conditions, and does not affect the activity of optical brighteners used at the same time.
摘要:
The present invention relates to a process for preparing an isocyanate group-containing allophanate corresponding to formula (I) ##STR1## wherein R represents the residue obtained by removing the isocyanate groups from a (cyclo)aliphatic or araliphatic diisocyanate,Y represents the represents an m-valent residue obtained by removing the hydroxyl groups from a (poly)hydroxyl compound having m OH groups andn and m are the same or different and have a value of 1 to 5, by reacting an isocyanate group-containing oxadiazinetrione with a primary alcohol in the presence of a basic catalyst having a pKa value of >6.
摘要:
The present invention relates to tanning agents containing carbamoyl sulfonate groups that are prepared by the reaction of(A) organic polyisocyanates,(B) 0.01 to 0.4 equivalents, relative to the isocyanate groups of polyisocyanate (A), of polyether alcohols having incorporated polyalkylene oxide units (the equivalents of the polyether alcohol being based on the hydroxyl groups), wherein 40 to 100 mole-% of the polyalkylene oxide units consist of polyethylene oxide units having a sequence length of 5 to 70,(C) optionally, NCO-reactive components other than polyether polyol (B), and(D) ammonium or alkali bisulfites or disulfites.
摘要:
Textiles can be finished in a wash- and cleaning-resistant manner by impregnation if aqueous dispersions are employed for this purpose which contain reactive copolymers and/or cocondensates having perfluoroalkyl groups and water-dispersible polyisocyanate mixtures whose NCO groups are not blocked.
摘要:
The present invention relates to a process for the production of aqueous dispersions of polyurethanes containing chemically incorporated carboxylate groups wherein the counterions to the carboxylate groups are predominantly ammonium ions corresponding to the formula ##STR1## by mixing a starting aqueous dispersion of polyurethanes containing chemically incorporated carboxylate groups wherein the counterions to the carboxylate groups are ammonium ions corresponding to the formula ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and represent C.sub.1-4 alkyl groups, provided that the total number of carbon atoms in these substituents is 3 to 6,with at least an equivalent quantity of ammonia, based on the trialkyl ammonium ions, and subsequently removing under vacuum at least a portion of the displaced trialkyl amines and the excess ammonia, if present.
摘要:
This invention relates to new emulsifiers for aqueous isocyanate emulsions and to their use as binders in the production of molded articles, in particular plates, e.g., from materials containing lignocellulose.
摘要:
The invention relates to aqueous adhesives which are based on water-dispersible polymers and which contain water-dispersible polyisocyanate preparations having an average NCO-functionality of at least 2.2, which, in addition to an aromatic polyisocyanate or a mixture of aromatic polyisocyanates, contain a quantity of emulsifier sufficient to guarantee the dispersibility of the polyisocyanates, as additives capable of improving the bonding properties of these adhesives.
摘要:
Dispersions of hydrophobic substances in water are prepared by dissolving the hydrophobic substance together with an ionomeric polyaddition or condensation product in an organic, water-miscible solvent or a mixture of such a solvent with water, diluting the solution with water and removing the organic solvent. The dispersions are excellently suitable for the preparation of photographic recording materials.
摘要:
This invention relates to a new process for the production of polyisocyanates having a biuret structure by reacting aliphatic or cycloaliphatic diisocyanates with sub-stoichiometric quantities of specified aldoximes. When aldoximes are used as the biuretizing agents insoluble ureas are not formed during the reaction and nitriles which are easy to handle and distill are formed as secondary products.