公开(公告)号：US4320068A

公开(公告)日：1982-03-16

申请号：US233736

申请日：1981-02-12

申请人： Jurgen Schwindt ,  Holger Meyborg ,  Helmut Reiff ,  Klaus Konig

发明人： Jurgen Schwindt ,  Holger Meyborg ,  Helmut Reiff ,  Klaus Konig

IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C273/18 ,  C07C275/62 ,  C08G18/78 ,  C08J9/02 ,  C09D175/00 ,  C07C127/24

CPC分类号： C08G18/7831 ,  C07C273/1809

摘要： This invention relates to a new process for the production of polyisocyanates having a biuret structure by reacting aliphatic or cycloaliphatic diisocyanates with sub-stoichiometric quantities of specified aldoximes. When aldoximes are used as the biuretizing agents insoluble ureas are not formed during the reaction and nitriles which are easy to handle and distill are formed as secondary products.

摘要翻译： 本发明涉及通过使脂族或脂环族二异氰酸酯与亚化学计量的规定的醛肟反应生产具有缩二脲结构的多异氰酸酯的新方法。 当使用醛基作为缩合反应剂时，在反应期间不形成不溶性的脲，并且易于处理和蒸馏的腈形成为次要产物。

公开(公告)号：US4263423A

公开(公告)日：1981-04-21

申请号：US057936

申请日：1979-07-16

申请人： Jurgen Schwindt ,  Holger Meyborg ,  Gerhard Grogler ,  Klaus Recker

发明人： Jurgen Schwindt ,  Holger Meyborg ,  Gerhard Grogler ,  Klaus Recker

IPC分类号： C08G18/00 ,  C08G18/22 ,  C08G18/72 ,  C08G18/73 ,  C08G18/16 ,  C08G18/24 ,  C08G18/26

CPC分类号： C08G18/72 ,  C08G18/22

摘要： The instant invention is directed to a process for the production of a light fast, transparent polyurethane elastomer comprising reacting:(A) from 90 to 50% by weight, based on the polyurethane solids content, of a compound having a molecular weight of from 400 to 10,000 which has at least two Zerewitinoff active hydrogen atoms;(B) from 50 to 10% by weight, based on the polyurethane solids content, of an aliphatic and/or alicyclic polyisocyanate; and(C) from 0 to 20% by weight, based on the polyurethane solids content, of a chain-lengthening agent having a molecular weight of from 60 to 400; in the presence of:(D) catalysts for the isocyanate polyaddition reaction, the improvement wherein said catalysts, component (D), is a catalyst combination of:(a) an alkali metal hydroxide and/or alkaline earth metal hydroxide; and(b) an organometallic compound selected from the group consisting of the acetyl acetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetyl acetonates of metals of the 4th main group or sulfur-containing compounds of metals of the 4th main group, in which compounds the sulfur is directly attached to the metal atom.

摘要翻译： 本发明涉及一种生产轻质，透明的聚氨酯弹性体的方法，包括使（A）基于聚氨酯固体含量的90至50重量％的分子量为400的化合物 至10,000具有至少两个Zerewitinoff活性氢原子; （B）基于聚氨酯固体含量为50至10重量％的脂族和/或脂环族多异氰酸酯; 和（C）基于聚氨酯固体含量为0至20重量％的分子量为60至400的链延长剂; 在（D）用于异氰酸酯加聚反应的催化剂的存在下，其中所述催化剂组分（D）是以下的催化剂组合：（a）碱金属氢氧化物和/或碱土金属氢氧化物; 和（b）选自第四主要金属的第四主要金属的第四主要金属的乙酰丙酮酸铁，C 1 -C 8醇盐，酚盐，烯醇化物和/或乙酰丙酮化物的有机金属化合物或第四主要金属的含硫化合物 基团，其中化合物硫直接连接到金属原子上。

公开(公告)号：US4587275A

公开(公告)日：1986-05-06

申请号：US429707

申请日：1982-09-30

申请人： Richard Kopp ,  Holger Meyborg ,  Gerhard Grogler ,  Jurgen Schwindt

发明人： Richard Kopp ,  Holger Meyborg ,  Gerhard Grogler ,  Jurgen Schwindt

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/32 ,  C08G18/38 ,  C08G18/65 ,  C08G18/14

CPC分类号： C08G18/3861 ,  C08G18/10

摘要： Polyurethane urea elastomers are produced by reacting polyisocyanates with compounds containing at least two isocyanate reactive hydrogen atoms having a molecular weight of 400 to 10,000 and mononuclear or dinuclear aromatic diamines. The aromatic diamines must have at least one sulfonamide group as a substituent on at least one of their aromatic rings. Known chain lengthening agents, activators, blowing agents, auxiliary agents and additives may also be included in the reaction mixture.Polyurethane elastomers produced by this process have excellent mechanical properties. In particular, such elastomers are soft yet have high tear propagation resistance.

摘要翻译： 聚氨酯脲弹性体是通过使多异氰酸酯与分子量为400至10,000的至少两个异氰酸酯反应性氢原子和单核或双核芳族二胺的化合物反应来制备的。 芳族二胺必须在至少一个它们的芳环上具有至少一个磺酰胺基作为取代基。 已知的增链剂，活化剂，发泡剂，辅助剂和添加剂也可以包括在反应混合物中。 通过该方法生产的聚氨酯弹性体具有优异的机械性能。 特别地，这种弹性体是柔软的但具有高的抗撕裂传播性。

公开(公告)号：US4303773A

公开(公告)日：1981-12-01

申请号：US148109

申请日：1980-05-09

申请人： Otto Ganster ,  Hans J. Meiners ,  Willi Eifler ,  Holger Meyborg ,  Jurgen Schwindt

发明人： Otto Ganster ,  Hans J. Meiners ,  Willi Eifler ,  Holger Meyborg ,  Jurgen Schwindt

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/28 ,  C08G18/32 ,  C08G18/54 ,  C08G18/65 ,  C08G18/16 ,  C08G18/24

CPC分类号： C08G18/6529 ,  C08G18/10 ,  C08G18/2805 ,  C08G18/3243 ,  C08G2120/00 ,  Y10S528/906

摘要： This invention relates to a process for the production of non-cellular polyurethane ureas elastomers using a chain-extender mixture produced from asymmetrically alkyl-substituted anilines by condensation with formaldehyde. The chain-extending agents used in the instant invention show medium reactivity to compounds containing isocyanate groups. These chain-extending agents may be processed both in high-pressure and in low-pressure metering and mixing units because they are either liquid at room temperature or can be melted at relatively low temperatures (below 55.degree. C.). The homogeneous, i.e. non-cellular, polyurethane urea elastomers obtained in the instant invention are distinguished by having excellent mechanical properties.

摘要翻译： 本发明涉及使用由不对称烷基取代的苯胺与甲醛缩合制备的扩链剂混合物生产非细胞聚氨酯脲醛弹性体的方法。 用于本发明的增链剂显示出对含有异氰酸酯基团的化合物的介质反应性。 这些增链剂可以在高压和低压计量和混合单元中进行加工，因为它们在室温下是液体的，或者可以在相对低的温度（低于55℃）下熔化。 通过具有优异的机械性能来区分在本发明中获得的均匀的，即非细胞的聚氨酯脲弹性体。

公开(公告)号：US4352896A

公开(公告)日：1982-10-05

申请号：US309636

申请日：1981-10-08

申请人： Richard Kopp ,  Holger Meyborg ,  Jurgen Schwindt

发明人： Richard Kopp ,  Holger Meyborg ,  Jurgen Schwindt

IPC分类号： C08G18/38 ,  C08J9/02 ,  C08G18/14 ,  C08G18/32

CPC分类号： C08J9/02 ,  C08G18/3819 ,  C08J2375/04

摘要： This invention relates to mixtures of polyols which are liquid at room temperature with functional aldoximes as blowing agents, wherein the aldoxime groups react with polyisocyanates to liberate carbon dioxide and are simultaneously incorporated by means of the functional group thereof into the polyurethane formed. The present invention also relates to a process for the production of polyurethane foams using these incorporated reactive blowing agents as the primary blowing agent in combination with blowing agents known in polyurethane chemistry. The process according to the invention described herein is suitable for the production of various polyurethane foams or cellular polyurethane elastomers, particularly including the production of semi-rigid and rigid polyurethane integral skin foams which are obtained by foaming the reaction mixture in closed molds.

摘要翻译： 本发明涉及在室温下为功能性醛肟作为发泡剂的多元醇混合物，其中醛肟基与多异氰酸酯反应以释放二氧化碳，并通过其功能基团同时引入所形成的聚氨酯中。 本发明还涉及使用这些掺入的反应性发泡剂作为主要发泡剂与聚氨酯化学中已知的发泡剂组合来生产聚氨酯泡沫体的方法。 根据本文所述的本发明的方法适用于生产各种聚氨酯泡沫或多孔聚氨酯弹性体，特别是包括通过在闭合模具中使反应混合物发泡获得的半刚性和硬质聚氨酯整体表皮泡沫的生产。

公开(公告)号：US4263408A

公开(公告)日：1981-04-21

申请号：US57935

申请日：1979-07-16

申请人： Holger Meyborg ,  Werner Mormann ,  Gerhard Grogler ,  Jurgen Schwindt

发明人： Holger Meyborg ,  Werner Mormann ,  Gerhard Grogler ,  Jurgen Schwindt

IPC分类号： C08G18/00 ,  C08G18/22 ,  C08G18/72 ,  C08G18/14

CPC分类号： C08G18/22 ,  C08G18/72 ,  C08G2101/0033 ,  C08G2410/00 ,  Y10T428/249989

摘要： The instant invention is directed to a process for the production of molded foams having a compact surface and cellular core and an integral density distribution over the cross-section of the body, comprising reacting(A) polyisocyanates, and(B) relatively high molecular and/or low molecular compounds having an average of at least two isocyanate-reactive hydrogen atoms in the presence of:(C) catalysts for the isocyanate polyaddition reaction and(D) blowing agents and optionally other known additives, in a closed mold under the conditions of foaming inside molds, the improvement wherein said polyisocyanates are aliphatic and/or alicyclic polyisocyanates and said catalysts are catalyst combinations of:(i) an alkali metal and/or alkaline earth metal hydroxide and(ii) a metal compound, the metal compound being the acetylacetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetylacetonates of metals of the 4th Main Group or sulfur compounds of metals of the 4th Main Group of the Periodic System of Elements in which the sulfur is directly attached to the metal atom.

摘要翻译： 本发明涉及一种生产具有紧凑的表面和多孔芯的模制泡沫的方法以及在主体的横截面上的整体密度分布，包括使（A）多异氰酸酯与（B）相对高分子和 /或在以下情况下平均具有至少两个异氰酸酯反应性氢原子的低分子化合物：（C）用于异氰酸酯加聚反应的催化剂和（D）发泡剂和任选的其它已知添加剂，在封闭模具中在条件 在模具中发泡的改进，其中所述多异氰酸酯是脂族和/或脂环族多异氰酸酯，所述催化剂是以下催化剂组合：（i）碱金属和/或碱土金属氢氧化物和（ii）金属化合物，金属化合物为 第四主要金属的金属的乙酰丙酮化物，C1-C8醇盐，酚盐，烯醇化物和/或乙酰丙酮化物或第四主族金属的硫化合物 的元素周期系统，其中硫直接连接到金属原子上。

公开(公告)号：US5459197A

公开(公告)日：1995-10-17

申请号：US251876

申请日：1994-06-01

申请人： Jurgen Schwindt ,  Helmut Reiff ,  Werner Kubitza

发明人： Jurgen Schwindt ,  Helmut Reiff ,  Werner Kubitza

IPC分类号： C08G18/08 ,  C08G18/28 ,  C08G18/62 ,  C08G18/66 ,  C08G18/70 ,  C08G18/75 ,  C08G18/79 ,  C08J3/00 ,  B32B27/00 ,  C08J3/20 ,  C08J7/00

CPC分类号： C08G18/6283 ,  C08G18/0814 ,  C08G18/283 ,  C08G18/6655 ,  C08G18/706 ,  C08G18/758 ,  C08G18/792 ,  Y10T428/31551

摘要： The present invention relates to an aqueous two-component coating composition wherein the binder contains(a) a component which is dissolved and/or dispersed in water, has an average hydroxyl number of 15 to 200 mg KOH/g, and contains(a1) a polyol component having a content of 8 to 450 milliequivalents, per 100 g of component (a1) solids, of chemically incorporated ammonium groups, .dbd.N.dbd..sup.+, comprising one or more polyaddition resins which are water-dilutable, contain hydroxyl groups, and have a molecular weight (M.sub.n) of 500 to 20,000 and(a2) up to 10 wt %, based on the weight of component (a1), of one or more reactive diluents which are water-soluble, have a molecular weight (M.sub.n) below 500, and contain at least one isocyanate-reactive group, and(b) a polyisocyanate component having an NCO content of 5 to 25 wt % comprising one or more polyisocyanates which are emulsified in the aqueous solution and/or dispersion of hydroxyl group-containing component (a),wherein components (a) and (b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups of component (b) to isocyanate-reactive groups of component (a) of 0.5:1 to 5:1.The present invention also relates to a process for the production of this coating composition and to their use for the production of coatings on water-resistant substrates.

摘要翻译： 本发明涉及水性双组分涂料组合物，其中粘合剂含有（a）溶解和/或分散在水中的组分，其平均羟值为15-200mg KOH / g，并含有（a1） 含有8至450毫当量的多元醇组分，每100g组分（a1）固体，化学掺入的铵基，= N = +，包含一种或多种可水稀释的加聚树脂，含有羟基，和 基于组分（a1）的重量，分子量（Mn）为500至20,000的（a2）至多10重量％，一种或多种水溶性的具有分子量（Mn）的反应性稀释剂， 低于500，并且含有至少一个异氰酸酯反应性基团，和（b）NCO含量为5至25重量％的多异氰酸酯组分，其包含在水溶液中乳化的一种或多种多异氰酸酯和/或羟基 - （a），其中组分（a）和（b） 以足以提供组分（b）的异氰酸酯基与组分（a）的异氰酸酯反应性基团的当量比为0.5:1至5:1的量存在。 本发明还涉及一种生产该涂料组合物的方法及其在耐水基材上生产涂料的用途。

公开(公告)号：US5612408A

公开(公告)日：1997-03-18

申请号：US593036

申请日：1996-01-29

申请人： Klaus Konig ,  Jurgen Schwindt ,  Jan Mazanek ,  Josef Pedain ,  Manfred Dietrich ,  Gerhard Klein ,  Karl-Roland Jerg

发明人： Klaus Konig ,  Jurgen Schwindt ,  Jan Mazanek ,  Josef Pedain ,  Manfred Dietrich ,  Gerhard Klein ,  Karl-Roland Jerg

IPC分类号： C09K3/00 ,  C08G18/28 ,  C08G18/48 ,  C08G65/28 ,  C08L75/00 ,  C08L75/08 ,  C09D7/00 ,  C09D175/00 ,  C09D175/04 ,  C08G18/12 ,  C08G18/42

CPC分类号： C08G18/4833 ,  C08G18/283 ,  C09D7/002 ,  C08L75/04

摘要： The present invention relates to a process for the preparation of polyurethanes suitable for use as thickeners for aqueous compositions by reacting at an NCO/OH equivalent ratio of 0.9:1 to 1.2:1a) a polyether component having an OH number of 10 to 30 mg KOH/g and obtained by the alkoxylation of a mixture ofa1) 30 to 80 mole % of a monofunctional alcohol or alkylphenol having 8 to 30 carbon atoms,a2) 2 to 10 mole % of sodium hydroxide or potassium hydroxide,a3) 10 to 60 mole % of water anda4) 0 to 10 mole % of a trihydric to hexahydric alcohol having a molecular weight of 92 to 600, with ethylene oxide or a mixture of ethylene oxide with up to 20 mole %, based on the total moles of alkylene oxides, of propylene oxide, in which the percentages of a1) to a4) add up to 100,withb) a polyisocyanate component containing at least one organic diisocyanate, optionally in admixture with up to 20 mole %, based on the total moles of component b), of higher than difunctional polyisocyanates.The invention also relates to the polyurethanes obtainable by this method and their use, optionally in combination with other thickeners, for the thickening of aqueous systems.

摘要翻译： 本发明涉及一种制备适合用作水性组合物增稠剂的聚氨酯的方法，其通过以0.9:1至1.2:1的NCO / OH当量比反应a）OH数为10至30的聚醚组分 mg KOH / g，通过a1）30〜80摩尔％的单官能醇或碳原子数为8〜30的烷基酚的混合物的烷氧基化得到，a2）2〜10摩尔％的氢氧化钠或氢氧化钾，a3）10 至60摩尔％的水和a4）0至10摩尔％的分子量为92至600的三元至六元醇与环氧乙烷或环氧乙烷的混合物至多20摩尔％，基于总摩尔数 的环氧丙烷，其中a1）至a4）的百分比加到100，其中b）含有至少一种有机二异氰酸酯的多异氰酸酯组分，任选地与至多20摩尔％的混合物，基于总计 组分b）的摩尔数高于双官能多异氰酸酯。 本发明还涉及通过该方法获得的聚氨酯，以及它们用于任选与其它增稠剂组合的用于增稠水性体系的用途。

公开(公告)号：US5179187A

公开(公告)日：1993-01-12

申请号：US655019

申请日：1991-02-14

申请人： Josef Pedain ,  Jurgen Schwindt ,  Klaus Konig ,  Manfred Schonborn

发明人： Josef Pedain ,  Jurgen Schwindt ,  Klaus Konig ,  Manfred Schonborn

IPC分类号： C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/79 ,  C09D7/80 ,  C09D175/00 ,  C09D175/04

CPC分类号： C08G18/792 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/2825

摘要： The present invention relates to a process for the preparation of a coating composition bya) treating moisture-containing auxiliaries and additives at 60.degree. to 120.degree. C. with urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight andb) after completion of the isocyanate/water reaction, combining the mixture obtained in step a) with iscyanate prepolymers having (cyclo)aliphatically bound isocyanate groups.The present invention also relates to the coating composition obtained by this process and to a composition containing urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight and moisture-containing auxiliaries or additives.

摘要翻译： 本发明涉及一种通过以下方法制备涂料组合物的方法：a）在含有（环）脂族结合的异氰酸酯基团的氨基甲酸酯基的异氰酸酯基团上，在60〜120℃下处理含水助剂和添加剂， ）NCO官能度为0.8至小于2.0，NCO含量为5至17重量％，b）异氰酸酯/水反应完成后，将步骤a）中获得的混合物与具有（环）脂族结合异氰酸酯的异氰酸酯预聚物 团体 本发明还涉及通过该方法获得的涂料组合物和含有具有（环）脂族结合的异氰酸酯基团，（平均）NCO官能度为0.8至小于2.0，NCO含量为5的含氨基甲酸酯基异氰酸酯的组合物 至17重量％，含水分的助剂或添加剂。

公开(公告)号：US4684691A

公开(公告)日：1987-08-04

申请号：US757800

申请日：1985-07-22

申请人： Hans G. Stahl ,  Peter Hohlein ,  Hans-Joachim Traenckner ,  Lothar Fleiter ,  Jurgen Schwindt

发明人： Hans G. Stahl ,  Peter Hohlein ,  Hans-Joachim Traenckner ,  Lothar Fleiter ,  Jurgen Schwindt

IPC分类号： C08F279/00 ,  C08C19/28 ,  C08F279/02 ,  C09D7/80 ,  C09D151/00 ,  C09D151/04 ,  C09F9/00 ,  C08L51/00

CPC分类号： C08F279/02 ,  C08C19/28 ,  C09D151/04

摘要： Aqueous lacquers, which contain grafted polybutadiene/maleic acid semi-esters or semi-amides as bonding agent, can be siccativated while the siccative is firstly dispersed in the aqueous phase and the bonding agent is dispersed in this dispersion.

摘要翻译： 含有接枝聚丁二烯/马来酸半酯或半酰胺作为粘合剂的水性漆可以在首先分散在水相中并将粘合剂分散在该分散体中的同时被干燥。