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31.发明授权Halogen- and sulfur-free shaped articles containing peroxide curable compounds of butyl rubber 失效含有丁基橡胶的过氧化物可固化化合物的卤素和无硫成型制品公开(公告)号：US06974851B2
公开(公告)日：2005-12-13
申请号：US10436616
申请日：2003-05-13
IPC分类号： C08L23/20 , C08F210/12 , C08J3/24 , C08K3/00 , C08K5/01 , C08K5/14 , C08L23/22 , H01M8/00 , C08K3/34 , C08C19/00 , C08F112/36 , C08F236/00 , C08L9/00
摘要： The present invention relates to a shaped article for high purity applications containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In another of its aspects, the present invention relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to a fuel cell containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to halogen-free and sulfur-free shaped articles.
摘要翻译： 本发明涉及含有至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物的用于高纯度应用的成型制品。 在另一个方面，本发明涉及一种密封材料和医疗装置，其包含至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物。 在其另一方面，本发明涉及一种含有至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物的燃料电池。 在其另一方面，本发明涉及无卤素和无硫成型制品。
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公开(公告)号：US06841642B2
公开(公告)日：2005-01-11
申请号：US10362202
申请日：2001-08-21
申请人： Gabor Kaszas
发明人： Gabor Kaszas
IPC分类号： C08F2/38 , C08F210/12 , C08F236/00
CPC分类号： C08F210/12 , C08F2/38 , C08F212/04 , C08F236/00 , C08F2500/17
摘要： A butyl polymer having improved processability is described, together with a process for production thereof. The butyl polymer derived from a reaction mixture which contains: (i) a monomer mixture comprising a C4 to C7 monoolefin monomer (preferably isobutylene) and a C4 to C14 multiolefin monomer (preferably isoprene); (ii) a multiolefin cross-linking agent (preferably divinyl benzene); and (iii) a chain transfer agent (preferably diisobutylene (2,2,4-trimethyl-1-pentene)). The subject butyl polymer has an improved balance of cold flow, filler dispersion, extrusion rate and die swell.
摘要翻译： 描述了具有改进加工性能的丁基聚合物及其生产方法。 衍生自反应混合物的丁基聚合物，其包含：（i）包含C4-C7单烯烃单体（优选异丁烯）和C4-C14多烯烃单体（优选异戊二烯）的单体混合物; （ii）多烯烃交联剂（优选二乙烯基苯）; 和（iii）链转移剂（优选二异丁烯（2,2,4-三甲基-1-戊烯））。 本发明的丁基聚合物具有改善的冷流平衡，填料分散，挤出速率和模头膨胀。
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33.发明授权
公开(公告)号：US5276094A
公开(公告)日：1994-01-04
申请号：US974552
申请日：1992-11-12
申请人： Gabor Kaszas , Judit E. Puskas
发明人： Gabor Kaszas , Judit E. Puskas
IPC分类号： C08F297/06 , C08L23/18 , C08L23/22 , C08L23/26 , C08L23/28 , C08L53/00 , C08F297/00
CPC分类号： C08L23/22 , C08F297/06 , C08L23/283
摘要： An elastomeric polymer composition that exhibits improved processability and green strength comprises: from about 95 to about 70 parts by weight of one rubbery polymer selected from the group consisting of butyl rubber, chlorinated butyl rubber and brominated butyl rubber and from about 5 to about 30 parts by weight of a block copolymer having an elastomeric polyisobutylene midblock and two plastomeric endblocks of polymerized monovinylidene aromatic monomers and star-shaped block copolymers having from three to six arms wherein the inner elastomeric blocks are polyisobutylene and the outer plastomeric blocs are polymerized monovinylidene aromatic monmers for a total of 100 parts by weight of the rubbery polymer and the block copolymer. Vulcanizates of the composition that exhibit reduced permeability to gases and improved tear strength are provided together with a process for their production.
摘要翻译： 显示改善的加工性和生坯强度的弹性体聚合物组合物包括：约95至约70重量份的一种选自丁基橡胶，氯化丁基橡胶和溴化丁基橡胶的橡胶状聚合物和约5至约30重量份 的具有弹性聚异丁烯中间嵌段的嵌段共聚物和聚合的单亚乙烯基芳族单体的两个塑性端嵌段和具有三至六个臂的星形嵌段共聚物，其中内部弹性体嵌段是聚异丁烯，外部塑性嵌段是聚合的单亚乙烯基芳族单体，用于 共计100重量份的橡胶状聚合物和嵌段共聚物。 提供显示出降低的气体渗透性和改进的撕裂强度的组合物的硫化橡胶与其生产方法一起提供。
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公开(公告)号：US4946899A
公开(公告)日：1990-08-07
申请号：US285207
申请日：1988-12-16
IPC分类号： C08F4/00 , C08F297/00 , C08F297/06
CPC分类号： C08F297/06 , C08F297/00
摘要： Block copolymers compose a polyisobutylene rubbery soft segment of M.sub.n of about 5,000 to above 500,000 and glassy hard segments of M.sub.n of about 5,000 or higher and usually about 10,000 to 35,000 or more, are made by preparing a living polymer block of the polyisobutylene and then polymerizing on said living polyisobutylene block the glassy hard segments by adding thereto an electron donor having a donor number of 15 to 50 and then adding and polymerizing the monomers for the glassy hard segments. The monomers for the glassy hard segments are styrene and its derivatives and indene and its derivatives and mixtures thereof.
摘要翻译： 嵌段共聚物通过制备聚异丁烯的活性聚合物嵌段而制备约5,000至500,000以上的上链＆Mn的聚异丁烯橡胶状软链段和约5000或更高，通常约10,000-35,000或更高的玻璃状硬链段， 然后在所述活性聚异丁烯上聚合，通过向其中加入供体数为15至50的电子给体，然后加入并聚合用于玻璃状硬链段的单体，阻断玻璃状硬链段。 玻璃状硬链段的单体是苯乙烯及其衍生物和茚及其衍生物及其混合物。
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公开(公告)号：US08613298B2
公开(公告)日：2013-12-24
申请号：US12120970
申请日：2008-05-15
申请人： Gabor Kaszas
发明人： Gabor Kaszas
CPC分类号： C08C19/12 , B60C1/0016 , C08C19/28 , C08K3/013 , C08K3/04 , C08K3/36 , C08L9/06 , C08L15/02 , C08L19/006 , C08L21/00 , Y10T152/10495 , C08L2666/08
摘要： The present invention is directed to a method of preparing a functionalized elastomer, comprising the steps of A) obtaining a diene-based elastomer; B) mixing the diene-based elastomer with a halogenating agent to form an intermediate elastomer; and C) mixing the intermediate elastomer with a dienophile comprising a filler-active functional group to form a functionalized elastomer.
摘要翻译： 本发明涉及一种制备官能化弹性体的方法，包括以下步骤：A）获得二烯类弹性体; B）将二烯基弹性体与卤化剂混合以形成中间弹性体; 和C）将中间弹性体与包含填料活性官能团的亲二烯体混合以形成官能化弹性体。
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公开(公告)号：US20130144021A1
公开(公告)日：2013-06-06
申请号：US13600687
申请日：2012-08-31
申请人： Gabor Kaszas , Judit Puskas , Kevin Kulbaba
发明人： Gabor Kaszas , Judit Puskas , Kevin Kulbaba
IPC分类号： C08F236/08
CPC分类号： C08F290/042 , C08F210/12 , C08F236/08 , C08F293/00 , C08F297/08 , C08L53/00 , C08L2666/04 , C08L2666/02 , C08F2500/03
摘要： The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (Tg), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (Tg), and to a process for making such arborescent polymers.
摘要翻译： 本发明涉及树状聚合物及其制备方法。 在一个实施方案中，本发明涉及由具有低玻璃化转变温度（Tg）的聚合物或共聚物端基官能化的由至少一个同位物和至少一种异烯烃形成的芳族聚合物，以及制备这种聚合物的方法 树枝状聚合物。 在另一个实施方案中，本发明涉及由至少一种异聚体和至少一种异烯烃形成的芳族聚合物，其已由具有高玻璃化转变温度的聚合物或共聚物衍生的少于约5重量％的端嵌段端基官能化 Tg），以及制备这种芳族聚合物的方法。
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37.发明申请公开(公告)号：US20120048446A1
公开(公告)日：2012-03-01
申请号：US13079907
申请日：2011-04-05
IPC分类号： B60C1/00 , C08F8/42 , C08F8/00 , C08F236/22
CPC分类号： C08C19/28 , B60C1/0016 , C08C19/22 , C08C19/25 , C08F8/30 , C08F8/42 , C08F236/06 , C08F236/08 , C08F236/10 , C08F236/22 , C08G77/00 , C08K3/04 , C08K3/045 , C08K5/5419 , C08L19/006 , C08L21/00 , C08L9/00 , C08L2666/08 , C08F220/06 , C08F210/10 , C08F4/48
摘要： The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like. The present invention more specifically discloses a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer. The subject invention further reveals a rubbery composition which is comprised of the reaction product of (I) a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer and (II) a dienophile and/or dienophile which is functionalized with a group which is capable of reacting with a filler selected from the group consisting of carbon black, silica, starch, and cellulose.
摘要翻译： 本发明通过在橡胶状聚合物的整个聚合物链中或在橡胶状聚合物的链末端随机引入少量（每个链的橡胶状聚合物链）的共轭三烯单体如异环烯烃来实现增加的填料相互作用 。 共轭三烯单体的引入导致形成含高活性共轭二烯单元的聚合物。 这些共轭二烯单元可以与炭黑发生化学反应，从而实现优异的增强。 或者，这些共轭二烯单元可用于使用Diels Alder反应用二氧化硅相互作用/反应性基团对聚合物进行官能化。 橡胶状聚合物的这种功能化可以方便地在混合器中进行，例如班伯里密炼机，研磨混合机等。 本发明更具体地公开了具有重复单元的橡胶状聚合物，其包含（1）选自共轭二烯烃单体和单烯烃单体的烯烃单体和（2）共轭三烯单体。 本发明还揭示了一种橡胶组合物，其由（I）具有重复单元的橡胶状聚合物的反应产物组成，所述重复单元包括（1）选自共轭二烯烃单体和单烯烃单体的烯烃单体和（2 ）共轭三烯单体和（II）亲二烯体和/或亲二烯体，其可以与能够与选自炭黑，二氧化硅，淀粉和纤维素的填料反应的基团官能化。
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38.发明授权Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer 有权异丁烯，二烯单体和苯乙烯单体的卤化三元共聚物公开(公告)号：US07868100B2
公开(公告)日：2011-01-11
申请号：US12146078
申请日：2008-06-25
申请人： Gabor Kaszas
发明人： Gabor Kaszas
IPC分类号： C08F8/00
CPC分类号： C08F8/20 , C08F210/00 , C08F210/12
摘要： A halogenated butyl polymer having improved properties, the butyl polymer derived from a monomer mixture comprising a C4 to C8 monoolefin monomer, a C4 to C14 multiolefin monomer and a styrenic monomer with a catalyst system to produce the butyl polymer. The improved properties include faster cure, higher maximum torque, higher delta torque, relatively stable modulus over time, improved hot air aging properties and improved aged flexure properties. These improved properties are believed to result from direct interaction between the styrenic moieties in the polymer backbone with a crosslinking agent added to vulcanize the halogenated butyl rubber.
摘要翻译： 具有改进性能的卤化丁基聚合物，衍生自包含C 4至C 8单烯烃单体，C 4至C 14多烯烃单体的单体混合物的丁基聚合物和具有催化剂体系的苯乙烯单体以制备丁基聚合物。 改进的性能包括更快的固化，更高的最大扭矩，更高的三角扭矩，随时间推移的相对稳定的模量，改善的热空气老化性能和改善的老化挠曲性能。 这些改进的性质被认为是由聚合物主链中的苯乙烯部分与添加的交联剂之间的直接相互作用产生的，以硫化卤化丁基橡胶。
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公开(公告)号：US20090283186A1
公开(公告)日：2009-11-19
申请号：US12120812
申请日：2008-05-15
申请人： Gabor Kaszas
发明人： Gabor Kaszas
CPC分类号： C08C19/14 , B60C1/0016 , C08C19/12 , C08K3/013 , C08K3/04 , C08K3/36 , C08L9/00 , C08L9/06 , C08L15/02 , C08L21/00 , C08L2666/08
摘要： The present invention is directed to a method of making a rubber composition, comprising the steps of A) obtaining a diene-based elastomer selected from the group consisting of natural rubber, synthetic polyisoprene, polybutadiene, solution polymerized styrene-butadiene rubber (SSBR), and emulsion polymerized styrene-butadiene rubber (ESBR); B) mixing the diene-based elastomer with a halogenating agent to form an intermediate elastomer; and C) mixing the intermediate elastomer with a carbon black. There is further disclosed a rubber composition made by the foregoing method, and a pneumatic tire comprising the rubber composition.
摘要翻译： 本发明涉及一种制备橡胶组合物的方法，包括以下步骤：A）获得选自天然橡胶，合成聚异戊二烯，聚丁二烯，溶液聚合的丁苯橡胶（SSBR），聚苯乙烯 - 丁二烯橡胶 和乳液聚合苯乙烯 - 丁二烯橡胶（ESBR）; B）将二烯基弹性体与卤化剂混合以形成中间弹性体; 和C）将中间弹性体与炭黑混合。 还公开了通过上述方法制备的橡胶组合物和包含橡胶组合物的充气轮胎。
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公开(公告)号：US06420489B2
公开(公告)日：2002-07-16
申请号：US09796182
申请日：2001-02-28
IPC分类号： C08F818
CPC分类号： C08F8/22 , C08F210/12
摘要： An improved process is provided for the bromination of isoolefin-conjugated diolefin polymers by brominating said polymer in solution in selected halogen-containing hydrocarbons as solvent. There is also provided an improved product of said process wherein the brominated polymer contains not less than 80 percent of the bound bromine atoms in a form suitable to participate in the vulcanization of the polymer and wherein not less than 70 percent of the bound conjugated diolefin units are similarly so brominated.
摘要翻译： 提供了一种改进的方法，用于通过将所述聚合物在选择的含卤素烃溶剂中的溶液中溴化所述异烯烃共轭二烯烃聚合物进行溴化。 还提供了所述方法的改进的产物，其中溴化聚合物含有不少于80％的结合溴原子，其形式适于参与聚合物的硫化，并且其中不少于70％的结合的共轭二烯单元 类似地如此溴化。
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