公开(公告)号：US12142531B2

公开(公告)日：2024-11-12

申请号：US17661576

申请日：2022-05-02

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L21/02 ,  H01L27/088 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US12087767B2

公开(公告)日：2024-09-10

申请号：US18068647

申请日：2022-12-20

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Kuan-Chang Chiu ,  Chia-Ching Lee ,  Chien-Hao Chen ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chi On Chui ,  Hsuan-Yu Tung ,  Chung-Chiang Wu

IPC: H01L27/088 ,  H01L21/8234 ,  H01L29/417 ,  H01L29/423 ,  H01L29/66 ,  H01L29/78

CPC classification number: H01L27/0886 ,  H01L21/823431 ,  H01L29/41791 ,  H01L29/42372 ,  H01L29/6681 ,  H01L29/785

Abstract: A structure includes a semiconductor substrate including a first semiconductor region and a second semiconductor region, a first transistor in the first semiconductor region, and a second transistor in the second semiconductor region. The first transistor includes a first gate dielectric over the first semiconductor region, a first work function layer over and contacting the first gate dielectric, and a first conductive region over the first work function layer. The second transistor includes a second gate dielectric over the second semiconductor region, a second work function layer over and contacting the second gate dielectric, wherein the first work function layer and the second work function layer have different work functions, and a second conductive region over the second work function layer.

公开(公告)号：US12021145B2

公开(公告)日：2024-06-25

申请号：US18357794

申请日：2023-07-24

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chun-Neng Lin ,  Ming-Hsi Yeh ,  Hung-Chin Chung ,  Hsin-Yun Hsu

IPC: H01L29/78 ,  H01L21/8238 ,  H01L27/092 ,  H01L29/66

CPC classification number: H01L29/785 ,  H01L21/823821 ,  H01L27/0924 ,  H01L29/66545 ,  H01L29/66795

Abstract: A semiconductor device includes a first fin, a second fin, and a third fin protruding above a substrate, where the third fin is between the first fin and the second fin; a gate dielectric layer over the first fin, the second fin, and the third fin; a first work function layer over and contacting the gate dielectric layer, where the first work function layer extends along first sidewalls and a first upper surface of the first fin; a second work function layer over and contacting the gate dielectric layer, where the second work function layer extends along second sidewalls and a second upper surface of the second fin, where the first work function layer and the second work function layer comprise different materials; and a first gate electrode over the first fin, a second gate electrode over the second fin, and a third gate electrode over the third fin.

公开(公告)号：US20240162349A1

公开(公告)日：2024-05-16

申请号：US18421681

申请日：2024-01-24

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chung-Chiang Wu ,  Po-Cheng Chen ,  Kuo-Chan Huang ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chien-Hao Chen

IPC: H01L29/78 ,  H01L21/8234 ,  H01L27/088 ,  H01L29/40 ,  H01L29/423 ,  H01L29/49 ,  H01L29/66

CPC classification number: H01L29/7851 ,  H01L21/823431 ,  H01L27/0886 ,  H01L29/401 ,  H01L29/42372 ,  H01L29/4966 ,  H01L29/66545

Abstract: A device includes a semiconductor fin, and a gate stack on sidewalls and a top surface of the semiconductor fin. The gate stack includes a high-k dielectric layer, a work-function layer overlapping a bottom portion of the high-k dielectric layer, and a blocking layer overlapping a second bottom portion of the work-function layer. A low-resistance metal layer overlaps and contacts the work-function layer and the blocking layer. The low-resistance metal layer has a resistivity value lower than second resistivity values of both of the work-function layer and the blocking layer. A gate spacer contacts a sidewall of the gate stack.

公开(公告)号：US20240021729A1

公开(公告)日：2024-01-18

申请号：US18357794

申请日：2023-07-24

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chun-Neng Lin ,  Ming-Hsi Yeh ,  Hung-Chin Chung ,  Hsin-Yun Hsu

IPC: H01L29/78 ,  H01L21/8238 ,  H01L29/66 ,  H01L27/092

CPC classification number: H01L29/785 ,  H01L21/823821 ,  H01L29/66795 ,  H01L29/66545 ,  H01L27/0924

Abstract: A semiconductor device includes a first fin, a second fin, and a third fin protruding above a substrate, where the third fin is between the first fin and the second fin; a gate dielectric layer over the first fin, the second fin, and the third fin; a first work function layer over and contacting the gate dielectric layer, where the first work function layer extends along first sidewalls and a first upper surface of the first fin; a second work function layer over and contacting the gate dielectric layer, where the second work function layer extends along second sidewalls and a second upper surface of the second fin, where the first work function layer and the second work function layer comprise different materials; and a first gate electrode over the first fin, a second gate electrode over the second fin, and a third gate electrode over the third fin.

公开(公告)号：US20230343648A1

公开(公告)日：2023-10-26

申请号：US18345148

申请日：2023-06-30

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Shao-Jyun Wu ,  Hung-Chi Wu ,  Chia-Ching Lee ,  Pin-Hsuan Yeh ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chien-Hao Chen ,  Sheng-Liang Pan ,  Huan-Just Lin

IPC: H01L29/78 ,  H01L21/02 ,  H01L29/417 ,  H01L21/8234 ,  H01L29/66

CPC classification number: H01L21/823431 ,  H01L21/0234 ,  H01L29/41791 ,  H01L29/66795 ,  H01L29/785

Abstract: An improved work function layer and a method of forming the same are disclosed. In an embodiment, the method includes forming a semiconductor fin extending from a substrate; depositing a dielectric layer over the semiconductor fin; depositing a first work function layer over the dielectric layer; and exposing the first work function layer to a metastable plasma of a first reaction gas, a metastable plasma of a generation gas, and a metastable plasma of a second reaction gas, the first reaction gas being different from the second reaction gas.

公开(公告)号：US11538805B2

公开(公告)日：2022-12-27

申请号：US17089291

申请日：2020-11-04

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Kuan-Chang Chiu ,  Chia-Ching Lee ,  Chien-Hao Chen ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chi On Chui ,  Hsuan-Yu Tung ,  Chung-Chiang Wu

IPC: H01L27/088 ,  H01L21/8234 ,  H01L29/417 ,  H01L29/423 ,  H01L29/66 ,  H01L29/78

Abstract: A structure includes a semiconductor substrate including a first semiconductor region and a second semiconductor region, a first transistor in the first semiconductor region, and a second transistor in the second semiconductor region. The first transistor includes a first gate dielectric over the first semiconductor region, a first work function layer over and contacting the first gate dielectric, and a first conductive region over the first work function layer. The second transistor includes a second gate dielectric over the second semiconductor region, a second work function layer over and contacting the second gate dielectric, wherein the first work function layer and the second work function layer have different work functions, and a second conductive region over the second work function layer.

公开(公告)号：US20220262685A1

公开(公告)日：2022-08-18

申请号：US17661576

申请日：2022-05-02

Applicant: Taiwan Semiconductor Manufacturing Co. Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L27/088 ,  H01L21/02 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US20220238715A1

公开(公告)日：2022-07-28

申请号：US17658708

申请日：2022-04-11

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chung-Chiang Wu ,  Po-Cheng Chen ,  Kuo-Chan Huang ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chien-Hao Chen

IPC: H01L29/78 ,  H01L27/088 ,  H01L29/423 ,  H01L21/8234 ,  H01L29/66 ,  H01L29/40 ,  H01L29/49

Abstract: A device includes a semiconductor fin, and a gate stack on sidewalls and a top surface of the semiconductor fin. The gate stack includes a high-k dielectric layer, a work-function layer overlapping a bottom portion of the high-k dielectric layer, and a blocking layer overlapping a second bottom portion of the work-function layer. A low-resistance metal layer overlaps and contacts the work-function layer and the blocking layer. The low-resistance metal layer has a resistivity value lower than second resistivity values of both of the work-function layer and the blocking layer. A gate spacer contacts a sidewall of the gate stack.

公开(公告)号：US20210407995A1

公开(公告)日：2021-12-30

申请号：US17089291

申请日：2020-11-04

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Kuan-Chang Chiu ,  Chia-Ching Lee ,  Chien-Hao Chen ,  Hung-Chin Chung ,  Hsien-Ming Lee ,  Chi On Chui ,  Hsuan-Yu Tung ,  Chung-Chiang Wu

IPC: H01L27/088 ,  H01L29/417 ,  H01L29/66 ,  H01L29/78 ,  H01L21/8234 ,  H01L29/423

Abstract: A structure includes a semiconductor substrate including a first semiconductor region and a second semiconductor region, a first transistor in the first semiconductor region, and a second transistor in the second semiconductor region. The first transistor includes a first gate dielectric over the first semiconductor region, a first work function layer over and contacting the first gate dielectric, and a first conductive region over the first work function layer. The second transistor includes a second gate dielectric over the second semiconductor region, a second work function layer over and contacting the second gate dielectric, wherein the first work function layer and the second work function layer have different work functions, and a second conductive region over the second work function layer.