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    Process for forming a ziegler-natta catalyst system having a controlled morphology
    31.
    发明申请
    Process for forming a ziegler-natta catalyst system having a controlled morphology 失效
    用于形成具有受控形态的齐格勒 - 纳塔催化剂体系的方法

    公开(公告)号：US20050004329A1

    公开(公告)日：2005-01-06

    申请号：US10898739

    申请日：2004-07-26

    申请人： Joseph Thorman

    发明人： Joseph Thorman

    IPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C09K8/62 ,  C09K8/68 ,  C08F4/44 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F4/6546 ,  C08F4/6541 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F2500/24

    摘要： A pre-catalyst is formed by reacting butylethylmagnesium with an alcohol to form a magnesium alkoxide compound, followed by contacting the magnesium alkoxide compound with a phosphorous compound to form a magnesium alkoxide phosphorous compound mixture. The magnesium alkoxide phosphorous compound mixture is subsequently reacted with TiCl4 to form a MgCl2 support. The MgCl2 support is then contacted with an internal donor while being heated to form a first catalyst slurry, which is then contacted with TiCl4 while being heated to form a second catalyst slurry. The second catalyst slurry is next contacted with TiCl4 while being heated to form a third catalyst slurry, which is washed and dried, resulting in a highly active pre-catalyst with controlled morphology. The pre-catalyst may be combined with one or more co-catalysts and optionally one or more external electron donors to form an active catalyst system, which may be used for the polymerization of olefins.

    摘要翻译： 通过使丁基乙基镁与醇反应以形成烷氧基镁化合物形成预催化剂，然后使烷氧基化镁与磷化合物接触以形成烷氧基镁磷化合物混合物。 随后将烷氧基镁磷化合物混合物与TiCl 4反应形成MgCl 2载体。 然后将MgCl 2载体与内部供体接触，同时被加热以形成第一催化剂浆料，然后将其与TiCl 4接触，同时加热形成第二催化剂浆料。 接着第二催化剂浆料与TiCl 4接触，同时被加热以形成第三催化剂浆液，将其洗涤和干燥，得到具有受控形态的高活性预催化剂。 预催化剂可以与一种或多种助催化剂和任选的一种或多种外部电子给体结合以形成可用于烯烃聚合的活性催化剂体系。

    Process for the Oxidative Coupling of Hydrocarbons
    33.
    发明申请
    Process for the Oxidative Coupling of Hydrocarbons 失效
    碳氢化合物的氧化偶合过程

    公开(公告)号：US20100331593A1

    公开(公告)日：2010-12-30

    申请号：US12494138

    申请日：2009-06-29

    申请人： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

    发明人： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

    IPC分类号： C07C15/46

    CPC分类号： C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

    摘要： A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译： 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

    Polymerization catalyst system using di-sec-butyldimethoxysilane for preparation of polypropylene
    35.
    发明授权
    Polymerization catalyst system using di-sec-butyldimethoxysilane for preparation of polypropylene 失效
    使用二仲丁基二甲氧基硅烷制备聚丙烯的聚合催化剂体系

    公开(公告)号：US07078468B2

    公开(公告)日：2006-07-18

    申请号：US10724925

    申请日：2003-12-01

    申请人： Joseph Thorman

    发明人： Joseph Thorman

    IPC分类号： C08F4/42

    CPC分类号： B01J31/122 ,  B01J31/128 ,  B01J2231/122 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  Y02P20/52 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/18 ,  C08F4/6465

    摘要： It has been discovered that using di-sec-butyldialkoxysilanes, such as di-sec-butyldimethoxysilane (DSBDMS), as external electron donors for Ziegler-Natta catalysts can provide a catalyst system that may prepare polypropylene films with improved properties and processing. The catalyst systems of the invention provide high activity, high bulk density, moderate hydrogen response, moderate donor response and high polydispersity (MWD). Suitable di-sec-butyldialkoxysilanes have the formula (SBu)2Si(OR″)2, where R″ is independently a straight or branched alkyl group of 1–5 carbon atoms.

    摘要翻译： 已经发现，使用二仲丁基二烷氧基硅烷如二仲丁基二甲氧基硅烷（DSBDMS）作为齐格勒 - 纳塔催化剂的外部电子供体可以提供可制备具有改进的性能和加工性的聚丙烯膜的催化剂体系。 本发明的催化剂体系提供高活性，高堆积密度，中等氢响应，中等供体响应和高多分散性（MWD）。 合适的二仲丁基二烷氧基硅烷具有式（其中R“独立地为氢原子， 1-5个碳原子的直链或支链烷基。