Catalyst regeneration process for improving catalyst selectivity
    34.
    发明授权
    Catalyst regeneration process for improving catalyst selectivity 有权
    用于提高催化剂选择性的催化剂再生方法

    公开(公告)号:US08791038B2

    公开(公告)日:2014-07-29

    申请号:US12749996

    申请日:2010-03-30

    摘要: The object of the present invention is to provide a catalyst regeneration process which can improve catalyst selectivity. A first aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a first fluidized bed regenerator and contacted with an oxygen-containing gas stream and optional steam to carry out a coke combustion reaction, wherein the resultant mixture of the partially regenerated catalyst and flue gas is introduced into a second fluidized bed regenerator and contacted with steam and an optional oxygen-containing gas stream to carry out a further regeneration reaction, and then the regenerated catalyst is introduced into the reactor. A second aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a fluidized dense bed regenerator and contacted with an oxygen-containing gas stream and steam to carry out a coke combustion reaction, and then the regenerated catalyst is introduced into the reactor. The inventive processes result in a more uniform distribution of the regenerated catalyst activity; due to the exposure of the catalyst to a low temperature for a long time, a part of the heavy metals are buried by the matrix and the remaining are passivated. Thereby dry gas and coke yields decrease sharply when hydrocarbons are subjected to a catalytic cracking reaction on the regenerated catalyst.

    摘要翻译: 本发明的目的是提供一种能够提高催化剂选择性的催化剂再生方法。 本发明的第一方面的特征在于将来自反应器的废催化剂引入第一流化床再生器中并与含氧气流和任选的蒸汽接触以进行焦炭燃烧反应,其中所得的 将部分再生的催化剂和烟道气引入第二流化床再生器中,并与蒸汽和任选的含氧气流接触以进行进一步的再生反应,然后将再生催化剂引入反应器。 本发明的第二方面的特征在于将来自反应器的废催化剂引入流化密床再生器中并与含氧气流和蒸汽接触以进行焦炭燃烧反应,然后引入再生催化剂 进入反应堆。 本发明的方法导致再生催化剂活性的更均匀分布; 由于催化剂长时间暴露于低温下,部分重金属被基质掩埋,其余的被钝化。 因此当烃在再生催化剂上进行催化裂化反应时,干气和焦炭产量急剧下降。

    Alkaline-earth metal compound-containing zeolite catalyst, method for preparing same, method for regenerating same, and method for producing lower hydrocarbons
    35.
    发明授权
    Alkaline-earth metal compound-containing zeolite catalyst, method for preparing same, method for regenerating same, and method for producing lower hydrocarbons 有权
    含碱土金属化合物的沸石催化剂,其制备方法,其再生方法及其制备方法

    公开(公告)号:US08673803B2

    公开(公告)日:2014-03-18

    申请号:US13654787

    申请日:2012-10-18

    IPC分类号: B01J29/06

    摘要: An alkaline-earth metal compound-containing zeolite catalyst composed of a composite material comprising at least a first component, a second component, and a third component. The first component is composed of at least one of zeolites selected from a group consisting of proton-type zeolites and ammonium type zeolites. The second component is composed of at least one of alkaline-earth metal compounds. The third component is composed of at least one selected from a group consisting of aluminum oxides, aluminum hydroxides, silicon oxides, silicon hydroxides, and clay minerals. The first component has a molar ratio of Si/Al of 10 or more and 300 or less. Content of the second component relative to the first component is 0.3 mass % or more and less than 10 mass % as alkaline-earth metal. Content of the third component relative to the first component is 15 mass % or more and 200 mass % or less.

    摘要翻译: 一种含碱土金属化合物的沸石催化剂,其由至少包含第一组分,第二组分和第三组分的复合材料组成。 第一组分由至少一种选自质子型沸石和铵型沸石的沸石组成。 第二组分由至少一种碱土金属化合物组成。 第三组分由选自氧化铝,氢氧化铝,氧化硅,氢氧化硅和粘土矿物中的至少一种组成。 第一成分的Si / Al摩尔比为10以上且300以下。 第二成分相对于第一成分的含量为碱土金属0.3质量%以上且小于10质量%。 第三成分相对于第一成分的含量为15质量%以上200质量%以下。

    PROCESS FOR THE PREPARATION OF OLEFINS
    37.
    发明申请
    PROCESS FOR THE PREPARATION OF OLEFINS 有权
    制备油脂的方法

    公开(公告)号:US20130225895A1

    公开(公告)日:2013-08-29

    申请号:US13597479

    申请日:2012-08-29

    IPC分类号: C07C1/22 C07C4/06

    摘要: Process for the preparation of olefins comprising reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form a mixture which comprises olefins and at least partially coked catalyst; separating olefins and at least partially coked catalyst as obtained; passing the at least partially coked catalyst to a regenerator; introducing into the regenerator an oxygen-containing gas to regenerate the at least partially coked catalyst, thereby producing a gaseous mixture and at least partially regenerated catalyst; analysing the at least partially regenerated catalyst to control the burning rate of the coke present on the at least partially coked catalyst in the regenerator by adjusting one or more conditions of the regeneration of the at least partially coked catalyst on the basis of the analysis of the at least partially regenerated catalyst; and passing the at least partially regenerated catalyst to the reactor.

    摘要翻译: 包括在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应以形成包含烯烃和至少部分焦化的催化剂的混合物的方法; 分离烯烃和至少部分焦化的催化剂; 将所述至少部分焦化的催化剂通过再生器; 向所述再生器中引入含氧气体以再生所述至少部分焦化的催化剂,由此产生气态混合物和至少部分再生的催化剂; 分析所述至少部分再生的催化剂以通过基于对所述至少部分再生催化剂的分析来调节所述至少部分焦化的催化剂的再生的一个或多个条件来控制存在于所述再生器中的所述至少部分焦化的催化剂上的焦炭的燃烧速率 至少部分再生催化剂; 并将至少部分再生的催化剂通入反应器。

    CATALYST REGENERATION PROCESS FOR IMPROVING CATALYST SELECTIVITY
    39.
    发明申请
    CATALYST REGENERATION PROCESS FOR IMPROVING CATALYST SELECTIVITY 有权
    催化再生方法提高催化选择性

    公开(公告)号:US20100248942A1

    公开(公告)日:2010-09-30

    申请号:US12749996

    申请日:2010-03-30

    IPC分类号: B01J38/30

    摘要: The object of the present invention is to provide a catalyst regeneration process which can improve catalyst selectivity. A first aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a first fluidized bed regenerator and contacted with an oxygen-containing gas stream and optional steam to carry out a coke combustion reaction, wherein the resultant mixture of the partially regenerated catalyst and flue gas is introduced into a second fluidized bed regenerator and contacted with steam and an optional oxygen-containing gas stream to carry out a further regeneration reaction, and then the regenerated catalyst is introduced into the reactor. A second aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a fluidized dense bed regenerator and contacted with an oxygen-containing gas stream and steam to carry out a coke combustion reaction, and then the regenerated catalyst is introduced into the reactor. The inventive processes result in a more uniform distribution of the regenerated catalyst activity; due to the exposure of the catalyst to a low temperature for a long time, a part of the heavy metals are buried by the matrix and the remaining are passivated. Thereby dry gas and coke yields decrease sharply when hydrocarbons are subjected to a catalytic cracking reaction on the regenerated catalyst.

    摘要翻译: 本发明的目的是提供一种能够提高催化剂选择性的催化剂再生方法。 本发明的第一方面的特征在于将来自反应器的废催化剂引入第一流化床再生器中并与含氧气流和任选的蒸汽接触以进行焦炭燃烧反应,其中所得的 将部分再生的催化剂和烟道气引入第二流化床再生器中,并与蒸汽和任选的含氧气流接触以进行进一步的再生反应,然后将再生催化剂引入反应器。 本发明的第二方面的特征在于将来自反应器的废催化剂引入流化密床再生器中并与含氧气流和蒸汽接触以进行焦炭燃烧反应,然后引入再生催化剂 进入反应堆。 本发明的方法导致再生催化剂活性的更均匀分布; 由于催化剂长时间暴露于低温下,部分重金属被基质掩埋,其余的被钝化。 因此当烃在再生催化剂上进行催化裂化反应时,干气和焦炭产量急剧下降。

    ALKALINE EARTH METAL COMPOUND-CONTAINING ZEOLITE CATALYST, PREPARATION METHOD AND REGENERATION METHOD THEREOF, AND METHOD FOR PRODUCING LOWER HYDROCARBON
    40.
    发明申请
    ALKALINE EARTH METAL COMPOUND-CONTAINING ZEOLITE CATALYST, PREPARATION METHOD AND REGENERATION METHOD THEREOF, AND METHOD FOR PRODUCING LOWER HYDROCARBON 审中-公开
    碱土金属化合物的沸石催化剂,其制备方法和再生方法以及生产下层烃的方法

    公开(公告)号:US20100168492A1

    公开(公告)日:2010-07-01

    申请号:US12377036

    申请日:2007-08-29

    IPC分类号: B01J29/04 C07C1/20 B01J38/12

    摘要: An alkaline-earth metal compound-containing zeolite catalyst composed of a composite material comprising at least a first component, a second component, and a third component, wherein the first component is composed of at least one of zeolites selected from a group consisting of proton-type zeolites and ammonium type zeolites, the second component is composed of at least one of alkaline-earth metal compounds, and the third component is composed of at least one selected from a group consisting of aluminum oxides, aluminum hydroxides, silicon oxides, silicon hydroxides, and clay minerals. The first component has a molar ratio of Si/Al of 10 or more and 300 or less. Content of the second component relative to the first component defined is 0.3 mass % or more and less than 10 mass % as alkaline-earth metal. Content of the third component relative to the first component is 15 mass % or more and 200 mass % or less.

    摘要翻译: 一种含碱土金属化合物的沸石催化剂,由包含至少第一组分,第二组分和第三组分的复合材料组成,其中所述第一组分由选自质子中的至少一种沸石组成 型沸石和铵型沸石,第二组分由至少一种碱土金属化合物组成,第三组分由选自氧化铝,氢氧化铝,氧化硅,硅中的至少一种组成 氢氧化物和粘土矿物。 第一成分的Si / Al摩尔比为10以上且300以下。 相对于所定义的第一成分的第二成分的含量为碱土类金属0.3质量%以上且小于10质量%。 第三成分相对于第一成分的含量为15质量%以上200质量%以下。