Abstract:
Polystyrene-based composite resin particles includes 100 to 500 parts by weight of a polystyrene-based resin with respect to 100 parts by weight of an ethylene-vinyl acetate copolymer resin. The polystyrene-based composite resin particles are impregnated with a volatile blowing agent and are pre-expanded to obtain pre-expanded particles; the obtained pre-expanded particles are immersed in tetrahydrofuran for 24 hours to obtain an extract A; and the pre-expanded particles are divided into two halves through the center to prepare halved particles, and the halved particles are immersed in tetrahydrofuran for 24 hours to obtain an extract B; and the obtained extract A and extract B are subjected to a GPC (gel permeation chromatography) measurement and obtain the following results: the polystyrene-based resin having a weight-average molecular weight (Mw) of 100,000 to 500,000 gives a peak obtained from chromatograms for the extract A and for the extract B.
Abstract:
An extruded polystyrene foam which is obtained by performing extrusion foaming using a styrene resin and a foaming agent, contains a flame retardant in a proportion of 0.5 parts by weight or more and 8.0 parts by weight or less based on 100 parts by weight of the styrene resin and has an apparent density of 20 kg/m3 or more and 45 kg/m3 or less and a closed cell ratio of 90% or more, in which the foaming agent at least contains HFO and another organic foaming agent, (i) the blended amount of the HFO is 0.030 mol or more and 0.125 mol or less based on 100 g of the styrene resin, (ii) an organic foaming agent having a polystyrene permeability of 0.5×10−10 cc·cm/cm2·s·cmHg or more is contained as the another organic foaming agent, (iii) an organic foaming agent having a polystyrene permeability of less than 0.5×10−10 cc·cm/cm2·s·cmHg is not contained as the another organic foaming agent, and (iv) the total blended amount of the HFO and the another organic foaming agent is 0.105 mol or more and 0.300 mol or less based on 100 g of the styrene resin.
Abstract translation:通过使用苯乙烯树脂和发泡剂进行挤出发泡而获得的挤出聚苯乙烯泡沫体,相对于100重量份的苯乙烯,含有0.5重量份以上且8.0重量份以下的阻燃剂 树脂,其表观密度为20kg / m 3以上且45kg / m 3以下,闭孔比为90%以上,其中发泡剂至少含有HFO和另一种有机发泡剂,(i) 基于100g苯乙烯树脂,HFO的配合量为0.030摩尔以上且0.125摩尔以下,(ii)聚苯乙烯透射度为0.5×10 -10 cc·cm 2·s·cm·cm的有机发泡剂 作为另一种有机发泡剂,不含有(3)聚苯乙烯渗透性小于0.5×10 -10 cc·cm 2·s·cmHg的有机发泡剂作为另一种有机发泡剂, (iv)HFO和另一种有机发泡剂的总混合量为0.10 5mol以上且0.300mol以下,基于100g苯乙烯树脂。
Abstract:
Rigid polyurethane foam is made in a vacuum assisted process using a blowing agent mixture that includes water and hydrofluoroolefin and/or hydrofluorochloroolefin. In preferred embodiments, the blowing agent mixture further includes a hydro carbon such as cyclopentane.
Abstract:
A composition including 2,4,4,4-10-tetrafluorobut-1-ene and cis-1,1,1,4,4,4-hexafluorobut-2-ene, and also the use thereof in particular as a heat transfer fluid. The composition may include: from 1% to 99% of 2,4,4,4-tetrafluorobut-1-ene and from 1% to 99% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 5% to 70% of 2,4,4,4-tetrafluorobut-1-ene and from 30% to 95% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 20% to 65% of 2,4,4,4-tetrafluorobut-1-ene and from 35% to 80% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 25% to 60% of 2,4,4,4-tetrafluorobut-1-ene and from 40% to 75% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 28% to 51% of 2,4,4,4-tetrafluorobut-1-ene and from 49% to 72% of cis-1,1,1,4,4,4-hexafluorobut-2-ene.
Abstract:
A polymeric foam is described which can be obtained by extrusion of a composition comprising a) a polymer blend of polystyrene, polyphenylene oxide and/or polyphenyl ether, b) at least one blowing agent, and c) at least one nucleating agent, as well as the use thereof for the filling of hollow bodies, in particular in the form of a window or door profile, with foam. The invention also relates to foam-filled hollow bodies, extrudates, and a method for producing the polymeric foam.
Abstract:
A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234ze in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
Abstract:
A composition including 2,4,4,4-10-tetrafluorobut-1-ene and cis-1,1,1,4,4,4-hexafluorobut-2-ene, and also the use thereof in particular as a heat transfer fluid. The composition may include: from 1% to 99% of 2,4,4,4-tetrafluorobut-1-ene and from 1% to 99% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 5% to 70% of 2,4,4,4-tetrafluorobut-1-ene and from 30% to 95% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 20% to 65% of 2,4,4,4-tetrafluorobut-1-ene and from 35% to 80% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 25% to 60% of 2,4,4,4-tetrafluorobut-1-ene and from 40% to 75% of cis-1,1,1,4,4,4-hexafluorobut-2-ene; preferably from 28% to 51% of 2,4,4,4-tetrafluorobut-1-ene and from 49% to 72% of cis-1,1,1,4,4,4-hexafluorobut-2-ene.
Abstract:
A process for the production of a polyurethane foam product includes reacting a polyisocyanate component and a polyol component in the presence of a tetraalkylstannoxy based catalyst.
Abstract:
Processes for producing impact copolymers are provided. Ethylene and at least one copolymer can be polymerized in the presence of one or more catalysts, polypropylene particles, and one or more halocarbon compounds to produce an impact copolymer that includes the polypropylene particles and an ethylene copolymer.
Abstract:
The present invention, which is characterized by the employment of blowing agents comprising fluorinated ethers with a boiling point in the range of from about 0 DEG C to 75° C., pertains to a composition of microcellular polyurethane, a method for preparing the same, and its use in manufacturing shoe materials. Compared to shoe soles made from traditional microcellular polyurethane, in particular those made using 1,1,1,2-tetrafluoroethane (HFC 134a) as the blowing agent, the polyurethane shoe soles prepared according to the present invention exhibit similar shrinkage characteristics, and their linear shrinkage is compatible with the current processing conditions, thus can replace traditional blowing systems comprising 1,1,1,2-tetrafluoroethane (HFC 134a) in shoe manufacturing without the need of changing molds. On the premise of being more environmental-friendly, the present invention also effectively saves production cost for shoe manufacturers.