摘要:
This disclosure relates to a continuous solution polymerization process where ethylene interpolymer products having an improved color index; for example, products having higher whiteness (Whiteness Index (WI)) and lower yellowness (Yellowness Index (YI)). Product color was improved by adjusting selected solution polymerization reaction conditions. The disclosed ethylene interpolymer products have improved color relative to comparative polyethylene compositions.
摘要:
This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Yd) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.
摘要:
This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.
摘要:
This disclosure relates to a continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a single site catalyst formulation are injected into a first reactor forming a first ethylene interpolymer. Process solvent, ethylene, optional comonomers, optional hydrogen and a heterogeneous catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in an optional third reactor, wherein an optional heterogeneous catalyst formulation may be employed. In a solution phase, the first, second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is passivated and following a phase separation process an ethylene interpolymer product is recovered.
摘要:
The polymer film comprises a carbonyl bond-containing polymer and a compound having δh of equal to or higher than 11.0 and δχ of equal to or lower than 1.50, wherein the δh is a value of hydrogen-bonding capacity calculated by Hoy method and the δχ is a value calculated by equation 1: δχ=|x−13.3| Equation 1 wherein, in equation 1, χ represents an interatomic distance in the polymer film between atoms most distant from each other among molecules in the compound, excluding a hydrogen atom, calculated by molecular dynamics calculation.
摘要:
Provided is a method for producing an α-olefin polymer, comprising the step of polymerizing one or more kinds of α-olefins each having 3 to 30 carbon atoms with a polymerization catalyst obtained by using: (A) a metallocene compound; (B) an ionic compound capable of reacting with the metallocene compound to transform the compound into a cation; (C) an organometallic compound; and (D) one or more kinds of compounds selected from the group consisting of (d-1) an alcohol, (d-2) a phenol, and (d-3) an ether compound, the catalyst having a ratio between the component (A) and the component (D) of from 10:1 to 1:100 in terms of a molar ratio, and having a ratio of the component (D) to the component (C) of less than 1 in terms of a molar ratio.
摘要:
A long obliquely-stretched film wound into a roll shape includes a thermoplastic resin and has an orientation angle oriented in a direction inclined with respect to a widthwise direction thereof. In a longitudinal direction of the long obliquely-stretched film, an angle defined between the orientation angle and the widthwise direction has a longitudinal cycle length of 10 mm to less than 1500 mm. An amplitude of the angle is in the range of 0.2° to 1.0° in the longitudinal cycle length.