摘要:
A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2−E1≧(V−4.25)×4.
摘要:
An electrode for non-aqueous secondary batteries that is capable of intercalating and de-intercalating an alkali metal, such as lithium, and a non-aqueous secondary battery comprising the electrode are disclosed. The electrode comprises an electrode current collector, and, on the electrode current collector, an electrode active material. The electrode active material has the overall composition: SiaMbPc; in which 0
摘要:
A negative electrode of a non-aqueous electrolyte secondary battery comprises a current collector and a mixture comprising a negative electrode active material, a conductive material, and a binder on the current collector. The negative electrode active material has the overall composition: MaSibPcBd; in which: 0
摘要:
The invention relates to a method for producing an anode for a lithium-ion battery, said anode comprising a current collector formed from a transition metal M in the form of a foam and an active material comprising a binary phosphide of said metal M, said active material corresponding to the formula MPx in which 1≦x≦4. The method consists in subjecting the metal M foam to the action of phosphorus vapor at a temperature between 300° C. and 600° C., the phosphorus being present in a proportion which differs by at most 10% from the stoichiometric proportion relative to the metal M.The invention also relates to an anode for a lithium-ion battery, and to a lithium-ion battery comprising such an anode.
摘要:
An object is to provide a power storage device with high discharge capacity and high energy density. The power storage device includes a positive electrode in which a positive electrode active material is formed over a positive electrode current collector; and a negative electrode which faces the positive electrode with an electrolyte interposed therebetween. The positive electrode active material includes a film-form first region which includes a compound containing lithium and nickel; and a film-form second region which includes a compound containing lithium and one or more of iron, manganese, and cobalt, but not containing nickel. The first region is covered with the second region. Since a superficial portion of the positive electrode active material does not contain nickel, nickel is not in contact with an electrolyte solution; thus, generation of a catalyst effect of nickel can be suppressed, and a high discharge potential of nickel can be utilized.
摘要:
A process of manufacturing a positive active material for a lithium secondary battery includes adding a metal source to a doping element-containing coating liquid to surface-treat the metal source, wherein the metal source is selected from the group consisting of cobalt, manganese, nickel, and combination thereof; drying the surface-treated metal source material to prepare a positive active material precursor; mixing the positive active material precursor with a lithium source; and subjecting the mixture to heat-treatment. Alternatively, the above drying step during preparation of the positive active material precursor is substituted by preheat-treatment or drying followed by preheat-treatment.
摘要:
A battery with a high capacity and superior cycle characteristics, and an anode active material used for it are provided. An anode active material contains tin as a first element, a second element, and a third element. The second element is at least one from the group consisting of boron, carbon, aluminum, and phosphorus, and the third element is at least one from the group consisting of silicon, magnesium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, zirconium, niobium, molybdenum, silver, indium, cerium, hafnium, tantalum, tungsten, and bismuth. The content of the second element in the anode active material is from 9.8 wt % to 49 wt %.
摘要:
The present invention relates to a nonaqueous electrolyte secondary battery comprising an anode capable of doping with and dedoping from lithium, a cathode and a nonaqueous electrolyte. The anode includes a carbon material, a polymer material and an Sn-containing compound expressed by a below general formula (1). SnM1xM2yM3z (1) (In the formula, M1 designates at least one kind of material selected from Co and Cu, and M2 designates at least one kind of material selected from Cr, Fe, Mn, Nb, Mo, W, B and P. M3 designates at least one kind of material selected from In, Ag, Zn and Al. x, y and z are respectively represented by 0.1
摘要:
Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.
摘要:
An aluminum-air secondary battery is provided. In an aluminum-air secondary battery capable of being charged and discharged multiple times, the aluminum-air secondary battery may comprise: a positive electrode including an electrode structure formed of a compound containing a transition metal, a chalcogen element, and phosphorus; a negative electrode disposed on the positive electrode and containing aluminum; and a solid electrolyte disposed between the positive electrode and the negative electrode and containing a base composite fiber having bacterial cellulose and chitosan bound to the bacterial cellulose.