High melt flow fluoropolymer
    35.
    发明授权
    High melt flow fluoropolymer 有权
    高熔体流动性氟聚合物

    公开(公告)号:US08674042B2

    公开(公告)日:2014-03-18

    申请号:US13293520

    申请日:2011-11-10

    IPC分类号: C08F14/18

    CPC分类号: H01B3/445 C08F214/18

    摘要: The present invention relates to a partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to HFPI of from about 2.8 to 5.3, and preferably from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether), said copolymer having less than about 50 ppm alkali metal ion, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/106 carbon atoms and which can be extruded at high speed onto conductor over a broad polymer melt temperature range to give insulated wire of high quality.

    摘要翻译: 本发明涉及部分结晶的共聚物,其包含四氟乙烯,六氟丙烯,其数量对应于HFPI为约2.8至5.3,优选约0.2%至3%重量的全氟(烷基乙烯基醚),所述共聚物具有较少的 约50ppm的碱金属离子,其熔体流动速率在约30±3g / 10min的范围内,并且不超过约50个不稳定的端基/ 106个碳原子,并且可以高速挤出到导体上 在广泛的聚合物熔体温度范围内提供高品质的绝缘电线。

    Method for producing fluorine-containing elastomer
    37.
    发明授权
    Method for producing fluorine-containing elastomer 有权
    含氟弹性体的制造方法

    公开(公告)号:US08598290B2

    公开(公告)日:2013-12-03

    申请号:US12307022

    申请日:2007-06-29

    IPC分类号: C08F14/18

    CPC分类号: C08F214/18 C08F14/18 C08F2/22

    摘要: The present invention provides a method of producing a fluoroelastomer excellent in dispersion stability at low cost, at a high rate of polymerization and in high yields. The present invention is a method of producing a fluoroelastomer comprising an emulsion polymerization of a fluorinated monomer in the presence of a water-soluble radical polymerization initiator, wherein the emulsion polymerization is carried out in the presence of a compound (1) containing a functional group reactive in radical polymerization and a hydrophilic group and a fluorinated compound (2) containing a fluorocarbon group comprising 1 to 6 continuously united carbon atom with fluorine atom directly bound to each of them as well as a hydrophilic group.

    摘要翻译: 本发明提供以低成本,高聚合速率和高产率制备分散稳定性优异的含氟弹性体的方法。 本发明是一种在水溶性自由基聚合引发剂的存在下包含含氟单体的乳液聚合的含氟弹性体的方法,其中乳液聚合在含有官能团的化合物(1)的存在下进行, 自由基聚合反应性和亲水性基团以及含有含有1〜6个连续碳原子的碳氟化合物的含氟化合物(2)和与其各自直接键合的氟原子以及亲水基团。

    Ethylene tetrafluoroethylene (meth)acrylate copolymers
    40.
    发明授权
    Ethylene tetrafluoroethylene (meth)acrylate copolymers 失效
    乙烯四氟乙烯(甲基)丙烯酸酯共聚物

    公开(公告)号:US08318877B2

    公开(公告)日:2012-11-27

    申请号:US12154082

    申请日:2008-05-20

    IPC分类号: C08F14/18

    摘要: A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2  (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2  (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.

    摘要翻译: 共聚物组合物,其包含以以下重量百分比共聚的单体:(a)约20%至约95%的式(I)的单体或单体混合物:CnF2n + 1(CH2)x [(CF2CF2) y(CH 2 CH 2)z] mLC(O)-C(R)= CH 2(I)其中R是H,Cl,F或CH 3,L是O,S,NH,S-(CH 2) )R NH,OC(O)NH-CH 2 CH 2 O,NHC(O)NHCH 2 CH 2 O,S-(CH 2)r OC(O)NHCH 2 CH 2 O或S(CH 2)r NHC(O)NHCH 2 CH 2 O,和(b)约5% %的至少一种:(i)具有约6至约18个碳原子的直链,支链或环状烷基的(甲基)丙烯酸烷基酯单体; 或(II)式(II)的单体(R2)2N-R3-O-C(O)-C(R)= CH2(Ⅱ)其中R是H,Cl,F或CH3,每个R2独立地是 C1至C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40%至100%盐碱化; 或(iii)其混合物。