摘要:
An improved hot-melt pressure-sensitive adhesive (HMPSA) composition contains an elastomeric component, such as a blend of SIS and SB block copolymers, and a tackifying component comprising one or more intermediate softening point resins (ISPRs) having a ring and ball softening point of from 35 to 60° C. The improved adhesive compositions are characterized by reduced volatility, less bleed and staining tendencies, and improved overall adhesive performance. The invention also provides improved label constructions in which a release liner is coated with an HMPSA composition and laminated to a flexible facestock. Notably, even when low basis weight paper facestocks are used, the construction can be converted at high speeds.
摘要:
A rubber-modified styrene resin composition which can provide a molding having a good balance between surface gloss and impact resistance and a styrene resin composition and a molding thereof having good toughness and excellent adhesion, transparency, and moldability is formed from a styrene resin composition comprising (A) an epoxidized block copolymer of a styrene monomer with a conjugated diene compound, (B) a non-modified synthetic rubber and (C) a styrene polymer and a molded article thereof.
摘要:
A material for liquid keeping containers comprising a resin composition which contains a syndiotactic polystyrene resin and a polypropylene resin and includes a compatibilized structure of the syndiotactic polystyrene resin phase and the polypropylene resin phase, the proportion of these phases being 90-10/10-90 (weight ratio).
摘要:
The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 150 parts by weight of a peroxide-crosslinking type olefinic resin and/or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposing type olefinic resin and/or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c), at least a part of component (d) and at least a part of 1.0 to 1,200 parts by weight of component (e) in the presence of an organic peroxide to cause crosslinking, wherein component (e) is at least one thermoplastic polymer selected from the group consisting of polyester type (co)polymers, polyamide type (co)polymers and polyurethane type (co)polymers, and a subsequent step of blending these with the remaining part of component (c), and, the remaining part of component (d) and component (e), if any. The obtained composition is soft and excellent in heat deformation resistance and mechanical strength, moldability and processability, particularly in oil resistance and stain resistance.
摘要:
The present invention is an improved block copolymer composition for extruding films having excellent stress relaxation and increased retained tension or load at elevated temperatures. The compound is comprised of: (a) from 52 to 60 percent by weight of a block copolymer having at least two polystyrene endblocks and a midblock of hydrogentated polymerized butadiene which has a vinyl content of 45 percent by weight or less (b) from 13 to 22 percent by weight of polystyrene, and (c) from 19 to 28 percent by weight of oil.
摘要:
A nonallergenic synthetic rubber elastomer having physical qualities equal to or superior to natural rubber latex is provided. The synthetic rubber elastomer is composed of at least one high molecular weight hydrogenated tri-block thermoplastic elastomer (HTPE), at least one low molecular weight HTPE and a crosslinkable cyclic unsaturated polyolefin crystalline polymer. Articles are formed from the synthetic rubber elastomers and then exposed to crosslinking agents. The articles thus formed possess physical qualities equal to or superior to natural rubber latex and improved biocompatability.
摘要:
A polymer alloy and method of making same comprising a block copolymer thermoplastic elastomer comprising a microscopic porosity rapidly plasticized by environmental contaminants and a binder of a polymer or copolymer, the binder binding block copolymer particles while preserving the microscopic porosity and providing a macroscopic porosity to allow fluid penetration. The block copolymer preferably comprises styrene-butadiene-styrene (SBS) triblock copolymer, styrene-butadiene (SB) diblock copolymer, or styrene-isoprene-styrene (SIS) triblock copolymer, or a combination thereof, and the binder preferably comprises styrene-ethylene-butadiene (SEB) terpolymer, ethylene-propylene-diene monomer (EPDM) terpolymer, ethylene-propylene (EPR) copolymer, or styrene-butene butadiene (SBB) terpolymer, or a combination thereof. Most preferably the block copolymer comprises styrene-butadiene-styrene (SBS) triblock copolymer and the binder comprises ethylene-propylene-diene monomer (EPDM) terpolymer.
摘要:
Bituminous compositions modified with self-adhesive cold-application polymers generally used for manufacturing of watertight roofing panels, said compositions comprising a mixture containing a rubbery styrene-diene polymeric mixture, one or more tackifying resins, and bitumen.
摘要:
The present invention provides a composition which comprises a radial poly(aromatic vinyl)/polyisoprene block copolymer as a major component and which can be used as a more excellent pressure-sensitive ingredient. This composition is obtained by reacting a diblock polymer with a coupling agent having a functionality of 4 or higher in the presence of a coupling accelerator, and it contains (a) 1 to 34% by weight of a diblock polymer, (b) 34 to 99% by weight of a four-branch polymer, and (c) 0 to 50% by weight of a two-branch polymer and/or a three-branch polymer. The poly(aromatic vinyl)/polyisoprene block copolymer contained in the composition has a weight-average molecular weight (Mw) of 260,000 to 500,000, and the poly(aromatic vinyl)/polyisoprene block copolymer has a poly(aromatic vinyl) block content of 5 to 24% by weight.
摘要:
The present invention is a hot melt pressure sensitive positioning adhesive for use with an absorbent article. The adhesive comprises: (a) from greater than 6 to less than 15 percent by weight of the total of (a), (b) and (c) of a hydrogenated styrene-(butadiene and/or isoprene)-styrene block copolymer having a vinyl content of greater than 50% by weight; and (b) from 50 to 80 percent by weight of the total of (a), (b) and (c) of a tackifying resin which has an aromaticity such that the MMAP cloud point is at least 45° C.; and (c) from 5 to 35 percent by weight of the total of (a), (b) and (c) of a plasticizer.