公开(公告)号：US5192640A

公开(公告)日：1993-03-09

申请号：US564643

申请日：1990-08-09

申请人： Siegfried Scheler ,  Gerhard Buhr ,  Klaus Bergmann

发明人： Siegfried Scheler ,  Gerhard Buhr ,  Klaus Bergmann

IPC分类号： C09K9/02 ,  C07C303/06 ,  C07C303/22 ,  C07C303/32 ,  C07C309/26 ,  G03F7/022

CPC分类号： G03F7/022 ,  C07C309/26

摘要： A process for preparing 7-hydroxy-1,2-naphthoquinone-2-diazide-4-sulfonic acid or salts thereof, of the general formula Z ##STR1## is disclosed in which X=hydrogen, a metal or an ammonium group, preferably an alkali metal or alkaline earth metal, especially sodium or potassium and the ammonium group.The compounds can be used as much or as intermediates or starting materials for the production of light-sensitive compounds and radiation-sensitive mixtures and materials.

摘要翻译： 公开了一种制备通式为Z＆lt; Z＆gt; Z的7-羟基-1,2-萘醌-2-二叠氮基-4-磺酸或其盐的方法，其中X =氢，金属或铵基， 优选碱金属或碱土金属，特别是钠或钾和铵基。 这些化合物可以用作生产光敏化合物和辐射敏感性混合物和材料的多少或作为中间体或起始材料。

公开(公告)号：US4847018A

公开(公告)日：1989-07-11

申请号：US185286

申请日：1988-04-15

申请人： Jeffery W. Koepke ,  Wen-Ching Hsieh ,  June M. Bostich

发明人： Jeffery W. Koepke ,  Wen-Ching Hsieh ,  June M. Bostich

IPC分类号： C07C303/06 ,  C07C309/62

CPC分类号： C07C303/06

摘要： A petroleum sulfonate is prepared by (a) separately sulfonating each of two or more different petroleum fractions boiling substantially above 700.degree. F. by contact with sulfur trioxide under reaction conditions wherein the ratio of milliliters of sulfur trioxide to grams of aromatic components is adjusted so as to produce from each separate fraction a reaction product capable of producing upon neutralization a sulfonate having a sulfonate requirement in microemulsion below about 20 grams per 100 milliliters of microemulsion; (b) separately neutralizing the sulfonated fractions; and (c) blending the hydrocarbon sulfonates produced from two or more of the fractions in proportions sufficient to yield a product petroleum sulfonate blend useful for enhanced oil recovery.In one embodiment four different petroleum fractions are separately sulfonated using different ratios of sulfur trioxide to aromatic content for each fraction and the sulfonated fractions are blended in a weight ratio between 0:1:1:0 and 1:10:10:1 to yield a sulfonate blend useful for enhanced oil recovery.

摘要翻译： 石油磺酸盐通过以下方法制备：（a）在反应条件下，通过与三氧化硫接触，分别将沸点基本上高于700°F的两种或更多种不同的石油馏分分别磺化，其中将三氧化硫的三氧化硫与芳族成分克的比例调整为 为了从每个单独的级分产生能够在中和时产生的微乳液中磺酸盐需求低于约20克/ 100毫升微乳液的磺酸盐的反应产物; （b）分别中和磺化级分; 和（c）将从两种或多种级分产生的烃磺酸盐以足以产生用于增强油回收率的产物石油磺酸盐共混物的比例混合。 在一个实施方案中，使用不同比例的三氧化硫与每个级分的芳族含量单独磺化四种不同的石油馏分，并且磺化馏分以0：1：1：0至1：10：10：1的重量比共混，得到 一种用于提高采收率的磺酸盐混合物。

公开(公告)号：US4740333A

公开(公告)日：1988-04-26

申请号：US852586

申请日：1986-04-16

申请人： Herbert Diehl ,  Josef Kasbauer ,  Karlfried Wedemeyer

发明人： Herbert Diehl ,  Josef Kasbauer ,  Karlfried Wedemeyer

IPC分类号： C07D215/56 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/06 ,  C07C303/08 ,  C07C309/86 ,  C07C143/70

CPC分类号： C07C309/00

摘要： 5-Fluorotoluene-2,4-disulphochloride is prepared by chlorosulphonation of 3-fluorotoluene by first reacting the 3-fluorotoluene with chlorosulfuric acid and then with an inorganic acid chloride at temperatures up to 130.degree. C. until the evolution of gas is complete, and then heating the reaction mixture at temperatures of up to 200.degree. C. and, after the completion of the gas evolution, reacting the product at a lower temperature with further inorganic acid chloride, or reacting the 3-fluorotoluene with powerful sulphonating agents at an elevated temperature, if appropriate in the presence of inert solvents and/or diluents, to give the corresponding disulphonic acid and then treating the disulphonic acid with inorganic acid chlorides.

摘要翻译： 通过首先使3-氟甲苯与氯磺酸反应，然后在高达130℃的温度下与无机酰氯反应直到气体逸出完成，通过3-氟甲苯的氯磺化制备5-氟甲苯-2,4-二氯化亚铜， 然后在高达200℃的温度下加热反应混合物，在气体逸出完成后，使产物在较低温度下与另外的无机酰氯反应，或使3-氟甲苯与强力磺化剂反应， 如果合适的话，在惰性溶剂和/或稀释剂的存在下升温，得到相应的二磺酸，然后用无机酰氯处理二磺酸。

公开(公告)号：US4678611A

公开(公告)日：1987-07-07

申请号：US820751

申请日：1986-01-17

申请人： Rudolf Hurter

发明人： Rudolf Hurter

IPC分类号： C09B29/00 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C309/47 ,  C09B29/01 ,  C09B29/095 ,  C09B43/12 ,  C09B62/006 ,  C09B62/008 ,  C09B62/04 ,  C09B62/085 ,  C09B62/095 ,  C09B62/24 ,  C09B62/245 ,  C09B62/28 ,  C09B62/47 ,  C09B62/473 ,  C09B62/477 ,  C09B62/51 ,  C09B62/515 ,  C07C143/56

CPC分类号： C09B62/006 ,  C09B29/0014 ,  C09B29/0955 ,  C09B62/043

摘要： Dyestuff intermediates of the formula ##STR1## wherein R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, R.sub.2 represents hydrogen or an acyl radical and Z represents hydrogen or a sulfo group, and the use thereof for the manufacture of azo dyes of the formula ##STR2## wherein D represents the radical of a coupling component, R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, and R.sub.2 represents hydrogen or an acyl radical, or of azo dyes of the formula ##STR3## wherein K is the radical of a coupling component, Z represents hydrogen or the sulfo group, and R.sub.2 represents hydrogen or an acyl radical.

摘要翻译： 其中R 1表示氢，1〜8个碳原子的烷基或苯基，R 2表示氢或酰基，Z表示氢或磺基，其制备方法的用途 其中D表示偶联组分的基团，R 1表示氢，1至8个碳原子的烷基或苯基，R 2表示氢或酰基，或偶氮染料 其中K是偶合组分的基团，Z表示氢或磺基，R2表示氢或酰基。

公开(公告)号：US4671900A

公开(公告)日：1987-06-09

申请号：US288769

申请日：1981-07-31

申请人： Karl Schmid ,  Werner Stein ,  Horst Baumann

发明人： Karl Schmid ,  Werner Stein ,  Horst Baumann

IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/42 ,  C07C303/44 ,  C07C309/09 ,  C07C309/17 ,  C07C309/58 ,  C07C309/62 ,  C11C3/00 ,  C11D1/28 ,  C07C143/90

CPC分类号： C07C303/42 ,  C11C3/00 ,  C11D1/28

摘要： This invention is directed to the preparation of .alpha.-sulfofatty acid esters. More particularly, this invention is directed to a process for the simplified preparation of light-colored, wash-active esters of .alpha.-sulfofatty acids with monovalent C.sub.1 to C.sub.8 alcohols or their salts from fats and oils of vegetable and/or animal origin comprising re-esterification with the monovalent alcohols or saponification and esterification with the monovalent alcohols, separation of the fatty acid ester formed, hydrogenation of the fatty acid ester, sulfonation, and bleaching, wherein a fatty acid ester fraction from which accompanying fatty acid glycerides have been removed to the extent of about 1 percent by weight or less, based upon the weight of the material to be sulfonated, is introduced into the sulfonation stage.

摘要翻译： 本发明涉及α-磺基脂肪酸酯的制备。 更具体地，本发明涉及一种简单制备α-磺基脂肪酸的浅色洗涤活性酯与一价C1至C8醇或其植物和/或动物来源的脂肪和油的盐的方法，其包括re 用单价醇进行酯化反应或用单价醇皂化和酯化，形成脂肪酸酯的分离，脂肪酸酯的氢化，磺化和漂白，其中伴随的脂肪酸甘油酯已被除去的脂肪酸酯部分 基于待磺化材料的重量约1重量％或更少的程度引入磺化阶段。

公开(公告)号：US4551283A

公开(公告)日：1985-11-05

申请号：US638845

申请日：1984-08-08

申请人： Rudolf Blattner

发明人： Rudolf Blattner

IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/32 ,  C07C309/47 ,  C07C143/56

CPC分类号： C07C309/47

摘要： There is disclosed a process for isolating 2-naphthylamine-3,6,8-trisulfonic acid in the form of the alkali or ammonium salt from the sulfonation mixture resulting from the sulfonation of the corresponding naphthylaminemonosulfonic or -disulfonic acid in oleum, which process comprises starting from a sulfonation mixture which contains the naphthylaminetrisulfonic acid in the form of the monopotassium or monoammonium salt, charging said mixture into water or dilute sulfuric acid such that the concentration of the sulfuric acid in the dilute solution or suspension of the sulfonation mixture is 30 to 77% by weight, simultaneously allowing the temperature to rise to 90.degree. to 125.degree. C., subsequently slowly cooling said solution or suspension to a temperature below 40.degree. C., during said cooling adding at least 0.1% by weight, based on naphthylaminetrisulfonic acid, of a dispersant, and isolating the precipitated monopotassium or monoammonium salt of 2-naphthylamine-3,6,8-trisulfonic acid.The naphthylaminetrisulfonic acid isolated in this manner in the form of the monopotassium or monoammonium salt from the sulfonation mixture can be used direct for the manufacture of textile dyes.

摘要翻译： 公开了一种从磺酸化混合物中分离出碱金属或铵盐形式的2-萘胺-3,6,8-三磺酸的方法，该磺化混合物是由发烟硫酸中相应的萘基氨基磺酸或二磺酸磺化产生的，该方法包括 从含有单钾盐或单铵盐形式的萘基氨基三磺酸的磺化混合物开始，将所述混合物装入水或稀硫酸中，使磺化混合物的稀溶液或悬浮液中的硫酸浓度为30〜 77重量％，同时允许温度升至90℃至125℃，随后将所述溶液或悬浮液缓慢冷却至低于40℃的温度，在所述冷却期间加入至少0.1重量％，基于萘基氨基三磺酸 酸，分散剂，并分离沉淀的2-萘胺-3,6,8-三磺酸的单钾盐或单铵盐。 从磺化混合物中以这种方式分离为单钾盐或单铵盐形式的萘基氨基四磺酸可以直接用于纺织染料的制造。

公开(公告)号：US4522764A

公开(公告)日：1985-06-11

申请号：US517483

申请日：1983-07-26

申请人： Theo Neukam ,  Wolfgang Brauer ,  Siegfried Korte

发明人： Theo Neukam ,  Wolfgang Brauer ,  Siegfried Korte

IPC分类号： C07C309/22 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/24 ,  C07C309/20 ,  C07C309/65 ,  C07C309/70 ,  C07C143/68

CPC分类号： C07C309/00

摘要： The title compounds are obtained by reacting compounds corresponding to the following formula:R.sub.1 --CH.dbd.CH--CO.sub.2 R.sub.2wherein R.sub.1 represents hydrogen or a methyl group and R.sub.2 represents a primary or secondary C.sub.1 to C.sub.4 alkyl group, with from 0.6 to 1.6 mol. equivalents of SO.sub.3 and, optionally, with from 0.1 to 10 mol. equivalents of an alkylating agent at temperatures in the range from -10.degree. to +25.degree. C., subsequently heating the resulting reaction mixture for 0.5 to 6 hours to 70.degree.-200.degree. C. and then working it up by distillation.

摘要翻译： 标题化合物通过使对应于下式的化合物R1-CH = CH-CO2R2反应获得，其中R 1表示氢或甲基，R 2表示伯或仲C1至C4烷基，具有0.6至1.6mol。 SO 3的当量，和任选的0.1至10mol。 在-10℃〜+ 25℃的温度范围内加入烷基化剂，随后将得到的反应混合物加热0.5〜6小时至70〜-200℃，然后蒸馏除去。

公开(公告)号：US4447368A

公开(公告)日：1984-05-08

申请号：US364083

申请日：1982-03-31

申请人： Herbert Emde ,  Heinz U. Blank ,  Peter Schnegg

发明人： Herbert Emde ,  Heinz U. Blank ,  Peter Schnegg

IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C303/04 ,  C07C303/06 ,  C07C303/08 ,  C07C309/45 ,  C07C143/56 ,  C07C143/64

CPC分类号： C07C309/45

摘要： Aromatic aminosulphonic acids which have a reduced content of discoloring by-products are obtained when aromatic amines are reacted with a sulphonating agent in a reaction medium at least some of which consists of tetramethylene sulphone.

摘要翻译： 当芳族胺与反应介质中的磺化剂反应时，获得具有降低的变色副产物含量的芳族氨基磺酸，其中至少一些由四亚甲基砜形成。

公开(公告)号：US4435336A

公开(公告)日：1984-03-06

申请号：US364082

申请日：1982-03-31

申请人： Herbert Emde ,  Heinz U. Blank ,  Peter Schnegg

发明人： Herbert Emde ,  Heinz U. Blank ,  Peter Schnegg

IPC分类号： C07C309/45 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/28 ,  C07C309/46 ,  C07D295/10 ,  C07C143/58 ,  C07C143/60

CPC分类号： C07C309/46

摘要： Aminoarylsulphonic acids which have a relatively high purity and a relatively low content of aminoaryldisulphonic acids can be obtained, if they are prepared, from the corresponding arylammonium hydrogen sulphates, by an improved version of the so-called baking process, wherein the reaction is carried out under pressure at a temperature of at least 140.degree. C. and, at least partially, in the presence of water.

摘要翻译： 通过所谓的烘烤过程的改进形式，可以从对应的芳基硫酸氢铵制备具有相对较高纯度和相对低含量的氨基芳基二磺酸的氨基芳基磺酸，其中反应进行 在至少140℃的温度下，至少部分地在水的存在下进行。

公开(公告)号：US4390475A

公开(公告)日：1983-06-28

申请号：US306504

申请日：1981-09-28

申请人： Fusao Kondo ,  Toshimi Terao ,  Katsumasa Nagano ,  Kyozo Kitano

发明人： Fusao Kondo ,  Toshimi Terao ,  Katsumasa Nagano ,  Kyozo Kitano

IPC分类号： C07C309/30 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C309/31 ,  C07C309/37 ,  C07C143/24

CPC分类号： C07C303/06

摘要： Alkylbenzene is sulfonated in a thin film type sulfonation process by adding 2 through 20 parts by weight, based on 100 parts by weight of said alkylbenzene, of alkylbenzene sulfonic acids having alkyl groups of 1 through 20 carbon atoms and/or benzene sulfonic acids to the alkylbenzene prior to the contact thereof with diluted gaseous sulfur trioxide. The addition of alkylbenzene sulfonic acids and/or benzenesulfonic acid effectively prevents the formation of adherent deposits on the surface of a reaction wall.

摘要翻译： 基于100重量份的所述烷基苯，具有1至20个碳原子的烷基和/或苯磺酸的烷基苯磺酸将2至20重量份加入到薄膜型磺化方法中，将烷基苯磺化至 烷基苯在与稀释的气态三氧化硫接触之前。 加入烷基苯磺酸和/或苯磺酸有效地防止在反应壁表面上形成附着沉积物。