Abstract:
A packaged fuel unit and a refillable hydrogen generator that uses the fuel unit to produce hydrogen gas are disclosed. The fuel unit includes a reactant that can undergo a thermal decomposition reaction that produces hydrogen gas when heated to at least a minimum initiation temperature. The reactant is contained within a package that includes a poor thermal conductor with one or more thermal conductor sections for conducting heat from outside the package to the reactant. The hydrogen generator includes a holder with a cavity in which the fuel unit can be removably disposed and a heating system for heating the fuel unit when disposed therein. The hydrogen generator can be part of a fuel cell system including a fuel cell battery that is provided with hydrogen gas from the hydrogen generator.
Abstract:
A hydrogen generator having one or more actuators coupled to one or more heating elements in which the actuator(s) are used to improve the transfer of thermal energy from heating element(s) to one or more fuel units contained within the generator. In one embodiment, an actuator allows insertion and/or removal of packaged fuel units without the need of removing the heating element(s) and/or the actuator(s). When the actuator is in a retracted state (e.g., a low temperature state), the packaged fuel unit may be inserted and/or removed from a cavity of the hydrogen generator. When the actuator is in an extended state (e.g., a higher temperature state), the actuator forces contact between itself or the heating element and the fuel unit when a prescribed operating temperature is reached.
Abstract:
A hydrogen generator, a fuel cell for use in the hydrogen generator and a fuel cell system are disclosed. The hydrogen generator includes a housing and a plurality of fuel pellets disposed in the housing. Each fuel pellet includes a hydrogen-containing reactant that will react to release hydrogen gas when heated. The hydrogen generator also includes a plurality of heating elements extending into the plurality of fuel pellets to generate heat to selectively heat one or more fuel pellets to initiate a reaction to produce hydrogen gas. The hydrogen generator further includes a plurality of electrical contacts operatively coupled to the plurality of heating elements to selectively supply electrical power to the plurality of heating elements.
Abstract:
A fuel cartridge and a hydrogen generator are provided for supplying hydrogen gas to a hydrogen gas device. The fuel cartridge includes a fuel composition disposed in a container and a multi-layer package material, such as a laminate, enclosing the fuel composition therein. The laminate includes a polymer layer distal the fuel composition and a conductor layer proximate the fuel composition and including a preformed portion. The hydrogen generator includes a punch thermally coupled to a heater assembly and is configured to move between a retracted state and a puncture state. When the fuel cartridge is disposed in the hydrogen generating apparatus, the punch is configured to puncture the polymer layer and bring the coined portion into contact with the fuel composition. Heat is applied to a hydrogen containing material in the fuel composition through the punch and preformed portion to release hydrogen gas.
Abstract:
The invention to preparing alane-etherate and alane by producing an alane-etherate complex using an acid including one or a combination of hydrochloric acid and methanesulfonic acid and a metal tetrahydroaluminate in a solvent including an ether such as diethyl ether. The alane-etherate can be desolvated using a spray desolvation process such as electrospraying.
Abstract:
A hydrogen generator including an initiator assembly having one or more contact members within a compressible member, and a removable fuel unit adjacent a surface of the compressible member. The fuel unit contains a hydrogen containing material that can release hydrogen gas when heated and an exothermic mixture that can react exothermically upon initiation by the initiator assembly. When no fuel unit is in the hydrogen generator, the compressible member is uncompressed and the contact members are at or below its surface, and when a fuel unit is disposed in the hydrogen generator, the compressible member is compressed so the contact members extend beyond the surface to make thermal contact with the fuel unit. Energy from the initiator assembly is conducted by the contact members to corresponding quantities of the exothermic mixture to initiate an exothermic reaction, providing heat for the release of hydrogen gas from the hydrogen containing material.
Abstract:
Methods for generating hydrogen gas and power and related systems, including a hydrogen generator and a fuel cell system. The hydrogen generator includes a cartridge, a housing with a cavity to removably contain the cartridge, and an initiation system. The cartridge includes a casing; a plurality of pellets including a hydrogen containing material; a plurality of solid heat transfer members in contact with but not penetrating the casing; a hydrogen outlet in the casing; and a hydrogen flow path from each pellet to the hydrogen outlet. A plurality of heating elements is disposed inside the housing. Each heating element is disposed so heat can be conducted from the heating element through the casing to corresponding heat transfer member to initiate the release of hydrogen gas. The initiation system can selectively heat one or more pellets. Hydrogen gas can be provided to a fuel cell battery to generate power.
Abstract:
Methods for generating hydrogen gas and related systems are disclosed. Aspects of methods include providing a solid reactant component to an expandable reactant zone within an expandable reaction chamber, providing a liquid reactant component to a collapsible receptacle, controllably transporting the liquid reactant component in the collapsible receptacle to the expandable reaction chamber, and reacting the liquid reactant component with the solid reactant component. In some instances, components are configured for volume exchange among the expandable reaction chamber, the expandable reactant zone, and the collapsible receptacle.
Abstract:
Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.
Abstract:
A hydrogen generator is provided for generating hydrogen gas for a fuel cell stack. The hydrogen generator includes a container, and a liquid reactant storage area configured to contain a liquid including a first reactant. The hydrogen generator also includes a reaction area within the container, and a solid containing a second reactant within the reaction area and having a concentration gradient that varies along an axis such as length of the solid. The hydrogen generator further includes a liquid delivery member for delivering the liquid to the solid in the reaction area to generate hydrogen. The concentration gradient controls a reaction rate of the first and second reactants.