METHOD FOR PRODUCING POLYAMIDE-BASED RESIN MULTI-STAGE-EXPANDED BEADS

    公开(公告)号:US20230407035A1

    公开(公告)日:2023-12-21

    申请号:US18030561

    申请日:2021-10-13

    申请人: JSP CORPORATION

    发明人: Tetsu OTSUKA

    IPC分类号: C08J9/18 C08J9/12 C08J9/228

    CPC分类号: C08J9/18 C08J9/228 C08J9/12

    摘要: A method for producing polyamide-based resin multi-stage expanded beads includes an internal pressure applying step of placing polyamide-based resin expanded beads in a pressure-resistant container, impregnating the polyamide-based resin expanded beads with a physical blowing agent in the pressure-resistant container to apply internal pressure higher than atmospheric pressure; and a heating and foaming step of heating and expanding the polyamide-based resin expanded beads to which internal pressure is applied obtained in the internal pressure applying step to obtain polyamide-based resin multi-stage expanded beads having apparent density lower than that of polyamide-based resin expanded beads used in the internal pressure applying step, in the internal pressure applying step, polyamide-based resin expanded beads in a wet state having a water content of 1% or more being impregnated with the physical blowing agent at a temperature higher than change-point temperature of storage modulus of the polyamide-based resin expanded beads in a wet state.

    POLYAMIDE-BASED RESIN EXPANDED BEADS, MOLDED ARTICLE OF POLYAMIDE-BASED RESIN EXPANDED BEADS, AND METHOD FOR PRODUCING POLYAMIDE-BASED RESIN EXPANDED BEADS

    公开(公告)号:US20230053755A1

    公开(公告)日:2023-02-23

    申请号:US17794760

    申请日:2021-02-01

    申请人: JSP CORPORATION

    发明人: Tatsuya HAYASHI

    IPC分类号: C08J9/16

    摘要: Polyamide-based resin expanded beads contain a polyamide-based resin as a base material resin. The beads have a crystal structure, an intrinsic peak of the polyamide-based resin and a high-temperature peak having a peak top temperature on a higher temperature side than a peak top temperature of the intrinsic peak appear in a DSC curve obtained under a predetermined condition; an amount of heat of fusion of the high-temperature peak is within 5 J/g or more and 50 J/g or less; and a coefficient of variation of the amount of heat of fusion of the high-temperature peak is 20% or less. The beads are produced by in-mold molding. A method for producing the beads includes: impregnating a polyamide-based resin; and releasing expandable polyamide-based resin beads from a sealed container, a temperature in the sealed container is raised at a rate of 0.3° C. or higher and 1.5° C. or lower per 10 minutes.

    Skin material-coated foamed particle molded body

    公开(公告)号:US11529754B2

    公开(公告)日:2022-12-20

    申请号:US16494255

    申请日:2018-03-19

    申请人: JSP CORPORATION

    摘要: A skin material-coated foamed particle molded body includes a skin material made of a polypropylene-based resin molded body and a polypropylene-based resin foamed particle molded body coated with the skin material. The skin material has a multilayer structure including an inner layer adhered to the foamed particle molded body and an outer layer outside the inner layer. The outer layer contains a polypropylene-based resin and a reinforcement fiber. The inner layer contains the polypropylene-based resin and a reinforcement fiber in a lower content ratio than a content ratio of the reinforcement fiber contained in the outer layer or contains the polypropylene-based resin and substantially no reinforcement fiber. An average value of the outer layer thickness ratio to a sum of the outer and inner layer thicknesses is 0.20 or more and 0.65 or less, and a coefficient of variation Cv of the ratio is 30% or less.

    Foam particles, and moulded article thereof

    公开(公告)号:US11466137B2

    公开(公告)日:2022-10-11

    申请号:US16348108

    申请日:2017-11-07

    申请人: JSP Corporation

    摘要: The present invention is concerned with expanded beads that are olefin-based thermoplastic elastomer expanded beads containing a coloring agent, wherein an apparent density of the expanded beads is 40 to 300 g/L, and an average surface layer membrane thickness (a) is 3 to 25 μm, and a molded article thereof, and is able to provide expanded beads capable of producing an expanded beads molded article which is excellent in in-mold moldability and excellent in tensile characteristics and an expanded beads molded article using the expanded beads.

    Method for producing foamed particle molded article provided with skin

    公开(公告)号:US11420365B2

    公开(公告)日:2022-08-23

    申请号:US16469009

    申请日:2017-12-21

    申请人: JSP CORPORATION

    摘要: A method for producing a foamed particle molded article provided with a skin, includes: forming a hollow molded article; filling a hollow part of the hollow molded article with polypropylene-based resin foamed particles; and heating and fusing the particles to each other. A melt elongation at 190° C. of the polypropylene-based resin forming the hollow molded article is 100 m/min or more. A half-crystallization time at 100° C. of the polypropylene-based resin is between 25 to 80 seconds. In heat flux differential scanning calorimetry, a melting peak temperature of the polypropylene-based resin is between 130 to 155° C., a partial heat of fusion at 140° C. or more of the polypropylene-based resin is between 20 to 50 J/g, and a ratio of the partial heat of fusion of the polypropylene-based resin to the total (partial heat of fusion/total heat of fusion) is between 0.2 to 0.8.

    THERMOPLASTIC ELASTOMER FOAM PARTICLES AND MOLDED BODY OF SAME

    公开(公告)号:US20220235216A1

    公开(公告)日:2022-07-28

    申请号:US17610659

    申请日:2020-04-23

    申请人: JSP Corporation

    IPC分类号: C08L53/00

    摘要: The present invention relates to cylindrical expanded thermoplastic elastomer beads provided with through-holes, the expanded thermoplastic elastomer beads including a core layer in an foamed state constituted of a base polymer containing a thermoplastic elastomer and a cover layer covering the core layer and constituted of a thermoplastic polymer, wherein a coefficient of dynamic friction of the thermoplastic polymer is 0.8 or less, and a difference between a melting point (Tmc) of the base polymer and a melting point (Tms) of the thermoplastic polymer is −20° C. or more and 20° C. or less. The present invention also relates to an expanded thermoplastic elastomer beads molded article formed by subjecting expanded thermoplastic elastomer beads provided with through-holes to in-mold molding, the molded article including a core layer in a foamed state and a cover layer covering the core layer, wherein a voidage is 15% or more, a density is 10 kg/m3 or more and 200 kg/m3 or less, and the product of a tensile strength (MPa) and a tensile elongation (%) is 5 or more.