Abstract:
A hydrogen generating apparatus or the like is able to detect an excess water state or an excess steam state in the interior of a shift converter or a selective oxidation device. The hydrogen generating apparatus (120) comprise a hydrogen generator (118) including a reformer (100) configured to generate a reformed gas from a material and steam; a shift converter (103) configured to cause the reformed gas supplied from the reformer (100) to be subjected to a shift reaction; and a selective oxidation device (105) configured to decrease a concentration of carbon monoxide in the reformed gas after the shift reaction to a predetermined concentration or less; a temperature sensor (116, 117) configured to detect one of a temperature of the shift converter (103) and a temperature of the selective oxidation device (105); and a controller (205) configured to determine that excess water or excess steam exists in an interior of the hydrogen generator (118) when an increasing rate of the temperature detected by the temperature sensor is less than a predetermined threshold.
Abstract:
A hydrogen generation system comprises a reformer 1 that contains a reforming catalyst, an evaporator 4 that supplies steam to the reformer 1, a heater 3 that heats the reformer 1 and the evaporator 4, a material feed portion 5 that feeds a feed material containing hydrocarbon compound to the reformer 1 through the evaporator 4, and a water supply portion 6 that has a flow rate switch 6a and supplies water to the reformer 1 and the evaporator 4.
Abstract:
The present invention is a method for recovering a catalyst from a catalyst body comprising a carrier having a catalyst layer formed on at least a part of the surface thereof, which comprises (a) a step of forming an overcoat layer on the surface of the catalyst layer, and (b) a step of allowing the catalyst body having the overcoat layer formed thereon to stand under the condition to result in a difference in expansibility or contractility exhibited by the overcoat layer from that exhibited by the carrier, wherein exfoliation of the catalyst layer from the carrier is permitted by means of the resulting difference in expansibility or contractility under the condition.
Abstract:
The present invention provides a fuel cell system comprising a hydrogen generator (1) which generates hydrogen gas by allowing a source material to undergo a reforming reaction and a fuel cell (3) which is equipped with a anode and an cathode and which generates electric power by allowing the hydrogen gas supplied to the anode and oxygen gas supplied to the cathode to react electrochemically with each other. The fuel cell system further comprises a water recovering portion (5) configured to recover water from water vapor discharged from at least one of the fuel and cathodes, a water storing portion (6) which is equipped with a tank (6a) for storing water recovered by the water recovering portion (5), and a water supply portion (10) configured to supply water stored in the tank (6a) to the hydrogen generator (1), wherein the tank (6a) is configured, in order to prevent water stored in the tank (6a) from decaying, such that the stored water is dischargable to the outside, and wherein the fuel cell system is so configured as to make a decision on whether or not to discharge the stored water to the outside for the prevention of water decay.
Abstract:
A fuel cell system (301) of the present invention comprises a fuel cell (1); a water circulating path (9) through which water associated with an operation of the fuel cell (1) circulates; a water circulator (10) for circulating water in the water circulating path (9); a heater (14) for heating the water circulating path (9); a first abnormality detector (29, 30) for detecting a first abnormality which is an abnormality relating to leakage of water from the water circulating path (9); and a controller (16); the fuel cell system being configured to cause the water circulator (10) to perform a water circulating operation for circulating the water in the water circulating path (9) and cause the heater (14) to perform a heating operation for heating the water circulating path (9), to suppress freezing in the water circulating path, wherein the controller (16) is configured to inhibit the water circulating operation for suppressing freezing and not to inhibit the heating operation for suppressing freezing, in a case where the fuel cell system (301) is shut down in response to detection of the first abnormality by the first abnormality detector (29, 30).
Abstract:
A hydrogen generation apparatus including: a first desulfurizer; a second desulfurizer; a reformer to generate a hydrogen-containing reformed gas from a raw material gas from which sulfur has been removed by at least one of the first desulfurizer and the second desulfurizer; and a recycle passage through which a part of the reformed gas generated by the reformer is mixed into the raw material gas to be supplied to the second desulfurizer. After installation or maintenance of the hydrogen generation apparatus, the raw material gas is supplied to the reformer through the first desulfurizer until a catalyst in the second desulfurizer is activated by a mixed gas of the reformed gas supplied through the recycle passage and the raw material gas, and after the catalyst in the second desulfurizer is activated, the raw material gas is supplied to the reformer through the second desulfurizer.
Abstract:
A fuel cell includes a reforming unit, a carbon monoxide decreasing unit, a fuel cell, a burner unit and a raw gas supply device. At the star-up operation of the fuel cell system, an amount of combustion air delivered to the burner unit by an air blower is adjusted according to a total amount of a raw gas to be supplied to the burner unit and an amount of a desorbed raw gas desorbed out of raw gas components adsorbed to at least one of catalysts in a fuel processor.
Abstract:
Provided are a fuel cell system capable of shortening the wait time of an observer who confirms set points of a system interconnection protective device before starting a system interconnection operation, and a method for operating the fuel cell system.A fuel cell system 100 includes: a hydrogen generating unit 16 configured to generate a hydrogen-containing gas by using a raw material; a heater 18 configured to heat the hydrogen generating unit; an electric power generation start command unit 32 configured to receive a command of start of an electric power generating operation of the fuel cell system, the command being input by a manual operation of an operator, the electric power generating operation being interconnected with an electric power system; and a controller 28 configured to: execute electric power generation stand-by, in which the fuel cell system stands by for the start of the electric power generating operation interconnected with the electric power system, while executing a temperature maintaining process of the hydrogen generating unit by the heater after completion of a temperature increasing process of the hydrogen generating unit by the heater; and when the electric power generation start command unit receives the command of the start of the electric power generating operation, stop the electric power generation stand-by and start the electric power generating operation interconnected with the electric power system.
Abstract:
A hydrogen generator of the present invention includes a reformer (16) for generating a hydrogen-containing gas through a reforming reaction using a raw material; a combustor (102a) for heating the reformer (16); a combustion air supplier (117) for supplying combustion air to the combustor (102a); and an abnormality detector (110a) for detecting an abnormality; and a controller (110) configured to control the combustion air supplier (117) such that the reformer (16) is cooled with a higher rate in an abnormal shut-down process executed after the abnormality detector (110a) detects the abnormality, than in a normal shut-down process.
Abstract:
A hydrogen generator comprises a reformer which generates a hydrogen-containing gas from a steam and a material gas, a first gas supply device which supplies the material gas, a combustor which combusts an exhaust gas exhausted from the reformer to heat the reformer, a combustion air supply device which supplies air to the combustor, a second gas supply device which supplies another gas different from the material gas to the reformer or to a passage connecting the reformer to the combustor, and a controller. The controller is configured to control the combustion air supply device to increase an amount of the air supplied to the combustor (S103), in association with start of supply of the another gas from the second gas supply device (S104), in a state where the material gas is supplied from the first gas supply device to the reformer and the exhaust gas is combusted in the combustor (S101).