公开(公告)号：US4424110A

公开(公告)日：1984-01-03

申请号：US345340

申请日：1982-02-03

Applicant: Roby Bearden, Jr. ,  William C. Baird, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  William C. Baird, Jr. ,  Clyde L. Aldridge

IPC: C10G1/08 ,  C10G47/00 ,  C10G47/02

CPC classification number: C10G1/086 ,  C10G1/083 ,  C10G2300/107

Abstract: Carbonaceous feeds such as hydrocarbonaceous oils and coal are hydroconverted in the presence of a combination of a hydrogen halide and a metal-containing catalyst produced in situ in the feed. The hydrogen halide is present in an amount to provide from about 0.1 to 20 moles of hydrogen halide per atom of the metal constituent of the catalyst to increase the activity of the catalyst.

Abstract translation: 碳氢化合物如碳氢化合物油和煤炭在原料在原料中生产的卤化氢和含金属催化剂的组合存在下进行加氢转化。 卤化氢的存在量为每原子催化剂金属组分约0.1至20摩尔卤化氢以增加催化剂的活性。

公开(公告)号：US4370224A

公开(公告)日：1983-01-25

申请号：US317116

申请日：1981-11-02

Applicant: Paul E. Eberly, Jr. ,  Charles H. Mauldin ,  William C. Baird, Jr.

Inventor： Paul E. Eberly, Jr. ,  Charles H. Mauldin ,  William C. Baird, Jr.

IPC: B01J23/89 ,  B01J27/057 ,  C10G35/09 ,  C10G35/085

CPC classification number: B01J23/8926 ,  B01J27/0573 ,  C10G35/09

Abstract: A catalyst comprised of platinum, iridium, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable, and can operate at reforming conditions at high severities.

Abstract translation: 由铂，铱，铜，硒和卤素组成的催化剂，与无机氧化物载体或载体，优选氧化铝复合。 催化剂是具有本质上高的活性，稳定的催化剂，并且可以在高浓度的重整条件下操作。

公开(公告)号：US4302359A

公开(公告)日：1981-11-24

申请号：US152669

申请日：1980-05-23

Applicant: Charles H. Mauldin ,  William C. Baird, Jr.

Inventor： Charles H. Mauldin ,  William C. Baird, Jr.

IPC: B01J23/656 ,  B01J23/89 ,  C10G35/09 ,  B01J21/04 ,  B01J23/64 ,  B01J23/72

CPC classification number: B01J23/8986 ,  B01J23/6567 ,  C10G35/09

Abstract: A process for the synthesis of catalysts by pre-forming a porous refractory inorganic oxide support, or carrier from a coarse particulate solid, preferably an alumina extrudate, contacting said preformed support with an acid solution, and then treating, contacting and neutralizing said preformed acid treated support with a base prior to the impregnation of said neutralized support with a metal, or metals, hydrogenation-dehyrdogenation component. The preformed solid support ranges at least about 1/32 inch diameter, and preferably at least about 1/16 inch diameter, and larger.

Abstract translation: 一种通过从粗颗粒固体，优选氧化铝挤出物预先形成多孔耐火无机氧化物载体或载体来合成催化剂的方法，使所述预制载体与酸溶液接触，然后处理，接触和中和所述预成型的酸 在用金属或金属氢化脱硫成分浸渍所述中和的载体之前，用碱处理的载体。 预制的固体支持体的直径至少约为1/32英寸，优选至少约1/16英寸直径，并且更大。

公开(公告)号：US4251391A

公开(公告)日：1981-02-17

申请号：US29675

申请日：1979-04-13

Applicant: Charles H. Mauldin ,  William C. Baird, Jr.

Inventor： Charles H. Mauldin ,  William C. Baird, Jr.

IPC: C10G35/085 ,  B01J23/89 ,  B01J27/02 ,  B01J27/045 ,  B01J27/08 ,  B01J27/10 ,  C10G35/09 ,  B01J27/04 ,  B01J23/64

CPC classification number: B01J23/8986 ,  C10G35/09

Abstract: A catalyst constituted of a composite which includes hydrogenation-dehydrogenation components comprised of platinum and rhenium to which a small amount of copper is added to suppress hydrogenolysis, which is particularly acute in reforming during the early period of operation when the catalyst is placed on stream, i.e., at the startup of a reactor; and process of employing such catalyst in reforming.

公开(公告)号：US4119528A

公开(公告)日：1978-10-10

申请号：US820820

申请日：1977-08-01

Applicant: William C. Baird, Jr. ,  Roby Bearden, Jr.

Inventor： William C. Baird, Jr. ,  Roby Bearden, Jr.

IPC: C10G29/10 ,  C10G45/00 ,  C10G47/00 ,  C10G13/06 ,  B01J23/04 ,  B01J23/90

CPC classification number: C10G45/00 ,  C10G29/10 ,  C10G47/00 ,  Y10S423/12

Abstract: A process for the simultaneous desulfurization and hydroconversion of heavy carbonaceous feeds, including various sulfur-containing heavy petroleum oils, is disclosed. These feedstocks are contacted with potassium sulfide in a conversion zone maintained at elevated temperatures and in the presence of added hydrogen. In this manner, the feeds are substantially desulfurized, and significant upgrading of these feeds is also obtained as demonstrated by decreased Conradson carbon, increased API gravity, and the conversion of substantial portion of the 1,050.degree. F.+ portion of these feeds. In a preferred embodiment, such a process is disclosed employing a combination of potassium sulfide and sodium sulfide, and in particular these processes include procedures for the regeneration of the sulfides and their recycle to the conversion zone.

Abstract translation: 公开了重质碳质饲料（包括各种含硫重质石油）的同时脱硫和加氢转化的方法。 这些原料在保持在升高的温度和加入的氢气存在下的转化区中与硫化钾接触。 以这种方式，进料基本上脱硫，并且还获得了这些进料的显着升级，这通过降低的康拉逊碳，增加的API重力以及这些进料的部分的1050°F的大部分的转化来证明。 在优选的实施方案中，公开了使用硫化钾和硫化钠的组合的这种方法，特别地，这些方法包括硫化物的再生和循环到转化区的方法。

公开(公告)号：US4051015A

公开(公告)日：1977-09-27

申请号：US695072

申请日：1976-06-11

Applicant: Roby Bearden, Jr. ,  William C. Baird, Jr.

Inventor： Roby Bearden, Jr. ,  William C. Baird, Jr.

IPC: C10G49/12 ,  C10G23/02

CPC classification number: C10G49/12

Abstract: A heavy hydrocarbonaceous oil is converted to lower boiling products by treatment with hydrogen in the presence of a particulate acidic copper chloride catalyst.

Abstract translation: 在颗粒状酸性氯化铜催化剂存在下，通过用氢处理将重质烃油转化为较低沸点产物。

公开(公告)号：US06623626B2

公开(公告)日：2003-09-23

申请号：US09897193

申请日：2001-07-02

Applicant: William C. Baird, Jr. ,  Jingguang G. Chen ,  Gary B. McVicker

Inventor： William C. Baird, Jr. ,  Jingguang G. Chen ,  Gary B. McVicker

IPC: C10G3509

CPC classification number: C10G45/62 ,  B01J23/40 ,  B01J23/58 ,  B01J23/60 ,  B01J23/622 ,  B01J23/8926 ,  B01J35/0006 ,  C07C5/13 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/50 ,  C07C2523/52 ,  C07C2523/72

Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The ring opening is accomplished using a ring opening catalyst system which combines an Ir ring opening catalyst with a Pt and Pd catalyst. The combination of the Pt and Pd-containing catalyst with an Ir-containing catalyst incorporates desirable isomerization activity and also results in substantial ring opening activity that enables Ir to be loaded at a level that is substantially below that of Ir-only ring opening processes.

公开(公告)号：US5925239A

公开(公告)日：1999-07-20

申请号：US918639

申请日：1997-08-22

Applicant: Darryl P. Klein ,  Michele S. Touvelle ,  Edward S. Ellis ,  Carl W. Hudson ,  Sylvain Hantzer ,  Jingguang G. Chen ,  David E. W. Vaughan ,  Michel Daage ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Gary B. McVicker

Inventor： Darryl P. Klein ,  Michele S. Touvelle ,  Edward S. Ellis ,  Carl W. Hudson ,  Sylvain Hantzer ,  Jingguang G. Chen ,  David E. W. Vaughan ,  Michel Daage ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Gary B. McVicker

IPC: C10G25/00 ,  C10G45/10 ,  C10G45/00

CPC classification number: C10G25/003 ,  C10G45/10

Abstract: A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.

Abstract translation: 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。

公开(公告)号：US5013704A

公开(公告)日：1991-05-07

申请号：US375224

申请日：1989-07-03

Applicant: William C. Baird, Jr. ,  Ehsan I. Shoukry

Inventor： William C. Baird, Jr. ,  Ehsan I. Shoukry

IPC: B01J21/04 ,  B01J21/10 ,  B01J21/12 ,  B01J21/14 ,  B01J23/58 ,  B01J23/656 ,  C10G35/085 ,  C10G35/09

CPC classification number: B01J21/14 ,  B01J21/04 ,  B01J23/58 ,  B01J23/6567 ,  C10G35/085 ,  C10G35/09 ,  B01J21/10 ,  B01J21/12

Abstract: Disclosed is a catalyst for reforming gasoline boiling range naphthas which catalysts are comprised of Pt and Re on alumina and a modifier comprised of at least 100 to 500 wppm Si and 10 wppm of one or more alkaline earth metals selected from Ca, Mg, Ba, and Sr wherein the total amount of modifier does not exceed about 5000 wppm.

Abstract translation: 公开了用于重整汽油沸程石脑油的催化剂，其催化剂由氧化铝上的Pt和Re组成，以及由至少100至500wppm的Si和10wppm的一种或多种选自Ca，Mg，Ba， 和Sr，其中改性剂的总量不超过约5000wppm。

公开(公告)号：US4966682A

公开(公告)日：1990-10-30

申请号：US375221

申请日：1989-07-03

Applicant: William C. Baird, Jr. ,  Ehsan I. Shoukry

Inventor： William C. Baird, Jr. ,  Ehsan I. Shoukry

IPC: B01J21/04 ,  B01J21/10 ,  B01J21/12 ,  B01J21/14 ,  B01J23/58 ,  B01J23/656 ,  C10G35/085 ,  C10G35/09

CPC classification number: B01J21/04 ,  B01J21/14 ,  B01J23/58 ,  B01J23/6567 ,  C10G35/085 ,  C10G35/09 ,  B01J21/10 ,  B01J21/12

Abstract: A process for reforming naphtha and straight run gasoline feeds by contacting the feed, and hydrogen, with a supported platinum catalyst on an alumina support modified with at least about 100 wppm Si and at least 10 wppm of one or more alkaline-earth metal selected from Ca, Mg, Ba, and Sr, wherein the total amount of modifier does not exceed about 5000 wppm.

Abstract translation: 通过使进料和氢与负载的铂催化剂接触在用至少约100wppm的Si和至少10wppm的一种或多种碱土金属改性的氧化铝载体上进行重整的方法，所述碱土金属选自 Ca，Mg，Ba和Sr，其中改性剂的总量不超过约5000wppm。