Novel 2-Cyano-3(Halo)Alkoxy-Benzenesulfonamide Compounds for Combating Animal Pests
    41.
    发明申请
    Novel 2-Cyano-3(Halo)Alkoxy-Benzenesulfonamide Compounds for Combating Animal Pests 失效
    新型2-氰基-3(卤代)烷氧基 - 苯磺酰胺化合物,用于防治动物害虫

    公开(公告)号:US20080063678A1

    公开(公告)日:2008-03-13

    申请号:US11791398

    申请日:2005-11-24

    摘要: The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds I and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula I and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula I and/or at least one agriculturally acceptable salt thereof. a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula I

    摘要翻译: 本发明涉及2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物I,其中变量Alk和R 1至R 5如权利要求1所定义,和 /或其农业上有用的盐。 此外,本发明涉及化合物I和/或其盐对抗动物害虫的用途; 包含至少一种式I化合物和/或至少一种农业上可用的I盐和至少一种惰性液体和/或其农业上可接受的载体的农药组合物,其具有杀虫作用,如果需要 ,至少一种表面活性剂; 以及一种对抗动物害虫的方法,包括使动物有害生物,其习惯,繁殖地,食物供应,植物,种子,土壤,区域,动物害虫生长或可能生长的区域,材料或环境,或材料,植物 ,防止动物攻击或侵染的种子,土壤,表面或空间与杀虫有效量的至少一种式I的2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物和/或至少一种农业上可接受的盐 其中。 包括从土壤和叶面昆虫中保护种子免受土壤昆虫和所得植物的根和芽的方法,包括在种子播种前和/或后发芽后将种子与2-氰基-3-(卤代)烷氧基 - 苯磺酰胺 通式I的化合物

    3-(heterocyclyl)-substituted benzolpyrazols
    43.
    发明授权
    3-(heterocyclyl)-substituted benzolpyrazols 失效
    3-(杂环基)取代的苯并吡唑

    公开(公告)号:US06831039B1

    公开(公告)日:2004-12-14

    申请号:US09857067

    申请日:2001-05-21

    IPC分类号: A01N4356

    CPC分类号: C07D413/10 C07D231/20

    摘要: The invention relates to 3-(heterocyclyl)-substituted benzoylpyrazois of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R1 is alkyl; R2, R3, R4, R5 are hydrogen, alkyl or alkyl halide; R6 is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R7 is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarboyloxy, alkylthiocarbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R8, R9 are alkyl; R10 is hydrogen or alkyl; and R11 is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to intermediate products and methods for producing the inventive compounds and to the use of these compounds or products containing them for combating undesirable plants.

    摘要翻译: 本发明涉及式(I)的3-(杂环基)取代的苯甲酰基吡啶,其中变量具有以下含义:X是O,NH或N-烷基; R 1是烷基; R 2,R 3,R 4,R 5是氢,烷基或烷基卤; R 6是卤素,硝基,烷基卤,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; R 7是羟基,烷氧基,烯氧基,烷基磺酰氧基,烷基羰氧基,烷硫基羰基氧基,苯基磺酰氧基或苯基羰基氧基,苯基可以被取代; R 8,R 9是烷基; R 10是氢或烷基; 和R 11是氢或烷基; 以及其农业上可用的盐类。 本发明还涉及用于生产本发明化合物的中间产物和方法以及含有它们的这些化合物或产品用于对抗不期望的植物的用途。

    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
    46.
    发明授权
    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect 失效
    取代的具有除草效果的2-苯甲酰基 - 环己烷-1,3-二酮

    公开(公告)号:US06576596B1

    公开(公告)日:2003-06-10

    申请号:US09331639

    申请日:1999-06-23

    IPC分类号: A01N3510

    摘要: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.

    摘要翻译: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R 1,R 2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR 5,-OCOR 6,-OSO 2 R 6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环;和其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。

    2-benzoyl-cyclohexane-1,3-diones
    48.
    发明授权

    公开(公告)号:US06559100B1

    公开(公告)日:2003-05-06

    申请号:US09485223

    申请日:2000-02-07

    IPC分类号: C07D2604

    摘要: Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.

    Method of producing 2-alkyl-3-(4,5-dihydroisoxazole-3-yl)-halobenzenes
    49.
    发明授权
    Method of producing 2-alkyl-3-(4,5-dihydroisoxazole-3-yl)-halobenzenes 有权
    2-烷基-3-(4,5-二氢异恶唑-3-基) - 卤代苯的制备方法

    公开(公告)号:US06548677B1

    公开(公告)日:2003-04-15

    申请号:US09856037

    申请日:2001-05-17

    IPC分类号: C07D26118

    CPC分类号: C07D261/04

    摘要: A novel process for preparing the compounds of the formula I where: n is 0, 1 or 2; R1, R2 are C1-C6-alkyl; R3, R4, R5 are hydrogen or C1-C6-alkyl, or R4 and R5 together form a bond; R6 is Cl, Br, which comprises a synthesis sequence starting from 1,2-dialkylbenzenes of the formula II with subsequent halogenation to give 3,6-dihalo-1,2-dialkylbenzenes, haloalkylation to give benzyl bromides, oxidation to give benzaldehydes, oximation, reaction with alkenes to give isoxazoles, conversion into thioethers and, if appropriate, oxidation to give sulfenyl or sulfonyl derivatives of the formula I.

    摘要翻译: 一种制备式I化合物的新方法,其中n为0,1或2; R 1,R 2为C 1 -C 6 - 烷基; R 3,R 4,R 5为氢或C 1 -C 6烷基,或者R 4和R 5一起形成 R 6是Cl,Br,其包含从式II的1,2-二烷基苯开始的合成序列,随后卤化以得到3,6-二卤代-1,2-二烷基苯,卤代烷基化得到苄基溴,氧化得到 苯甲醛,肟化,与烯烃的反应得到异恶唑,转化成硫醚,如果合适,氧化得到式I的磺酰基或磺酰基衍生物。