摘要:
The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds I and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula I and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula I and/or at least one agriculturally acceptable salt thereof. a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula I
摘要:
The present invention relates to a method for combating insects or arachnids which comprises contacting the insects or the arachnids, their habitat, breeding ground, food supply, plant, seed, soil, area, material or environment in which the insects or the arachnids are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from insect or arachnid attack or infestation with a pesticidally effective amount of a compound of the general formula (I) or a salt thereof wherein: Ar is a cyclic radical, n is 0 or 1, X is CO or SO2 and R1 to R4 are as defined in claim 1.
摘要:
The invention relates to 3-(heterocyclyl)-substituted benzoylpyrazois of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R1 is alkyl; R2, R3, R4, R5 are hydrogen, alkyl or alkyl halide; R6 is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R7 is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarboyloxy, alkylthiocarbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R8, R9 are alkyl; R10 is hydrogen or alkyl; and R11 is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to intermediate products and methods for producing the inventive compounds and to the use of these compounds or products containing them for combating undesirable plants.
摘要翻译:本发明涉及式(I)的3-(杂环基)取代的苯甲酰基吡啶,其中变量具有以下含义:X是O,NH或N-烷基; R 1是烷基; R 2,R 3,R 4,R 5是氢,烷基或烷基卤; R 6是卤素,硝基,烷基卤,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; R 7是羟基,烷氧基,烯氧基,烷基磺酰氧基,烷基羰氧基,烷硫基羰基氧基,苯基磺酰氧基或苯基羰基氧基,苯基可以被取代; R 8,R 9是烷基; R 10是氢或烷基; 和R 11是氢或烷基; 以及其农业上可用的盐类。 本发明还涉及用于生产本发明化合物的中间产物和方法以及含有它们的这些化合物或产品用于对抗不期望的植物的用途。
摘要:
The present invention describes a process for preparing isoxazoles of the formula I where: R1 is hydrogen, C1-C6-alkyl, R2 is hydrogen, C1-C6-alkyl, R3, R4, R5 are each hydrogen, C1-C6-alkyl or R4 and R5 together form a bond, R6 is a heterocyclic ring, n is 0, 1 or 2; which comprises preparing an intermediate of the formula VI where R1, R3, R4 and R5 are each as defined above, followed by halogenation, thiomethylation, oxidation and acylation to give compounds of the formula I. Furthermore, the invention describes novel intermediates for preparing the compounds of the formula I and novel processes for preparing the intermediates.
摘要:
The invention relates to cyclohexenone derivatives of benzo-condensed, unsaturated 5-ring nitrogen heterocycles of general formula (I) wherein X represents N or a group C—R3, Y represents O, S, SO, SO2 or NR4 or X—Y represent S═N and X represents sulfur, and the variables R1, R2 and Hex have the meanings given in claim 1. The invention also relates to a method for producing these compounds, to agents containing these compounds, and to their use as herbicides.
摘要:
The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.
摘要翻译:本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R 1,R 2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR 5,-OCOR 6,-OSO 2 R 6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环;和其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。
摘要:
Pyrazoles of the formula I where: R1 is hydrogen, nitro, halogen, cyano, thiocyanato or an aliphatic radical; R2 is a substituted sulfur, nitrogen or phosphorus atom; R3 is hydrogen, halogen or an aliphatic radical; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, or an aliphatic radical; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7, R8, R9 are hydrogen, C1-C6-alkyl, but at most one of the radicals R7, R8 and R9 is hydrogen; and their tautomers and agriculturally useful salts are described. Moreover, the invention relates to processes for preparing compounds of the formula I, to compositions comprising them and to the use of the compounds of the formula I and of the compositions comprising them for controlling harmful plants.
摘要翻译:式I的吡唑:其中R 1为氢,硝基,卤素,氰基,氰硫基或脂族基; R 2为取代的硫,氮或磷原子; R 3为氢,卤素或脂族基; R 4,R 5为氢,硝基 卤素,氰基,氰硫基或脂族基; R 6是氢,卤素,C 1 -C 6烷基,C 1 -C 6烷氧基,C 3 -C 8环烷基; R 7,R 8,R 9是氢,C 1 -C 6烷基, 但是R 7,R 8和R 9中的至少一个基团是氢;并且描述了其互变异构体和农业上有用的盐。此外,本发明涉及制备式I化合物的方法,包括它们的组合物以及使用 式I化合物和包含它们的用于控制有害植物的组合物。
摘要:
Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.
摘要:
A novel process for preparing the compounds of the formula I where: n is 0, 1 or 2; R1, R2 are C1-C6-alkyl; R3, R4, R5 are hydrogen or C1-C6-alkyl, or R4 and R5 together form a bond; R6 is Cl, Br, which comprises a synthesis sequence starting from 1,2-dialkylbenzenes of the formula II with subsequent halogenation to give 3,6-dihalo-1,2-dialkylbenzenes, haloalkylation to give benzyl bromides, oxidation to give benzaldehydes, oximation, reaction with alkenes to give isoxazoles, conversion into thioethers and, if appropriate, oxidation to give sulfenyl or sulfonyl derivatives of the formula I.
摘要翻译:一种制备式I化合物的新方法,其中n为0,1或2; R 1,R 2为C 1 -C 6 - 烷基; R 3,R 4,R 5为氢或C 1 -C 6烷基,或者R 4和R 5一起形成 R 6是Cl,Br,其包含从式II的1,2-二烷基苯开始的合成序列,随后卤化以得到3,6-二卤代-1,2-二烷基苯,卤代烷基化得到苄基溴,氧化得到 苯甲醛,肟化,与烯烃的反应得到异恶唑,转化成硫醚,如果合适,氧化得到式I的磺酰基或磺酰基衍生物。
摘要:
3-(Heterocyclyl)benzoylpyrazole derivatives of the formula I where: X is O, NH or N-alkyl; R1 is nitro, halogen, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfonyl or haloalkylsulfonyl; R2,R3,R4,R5 are hydrogen, alkyl or haloalkyl; R6 is halogen, nitro, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfonyl or haloalkylsulfonyl; R7 is hydroxyl, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, where the phenyl radical may be substituted; R8,R9 are alkyl; R10 is hydrogen or alkyl; R11 is hydrogen or alkyl; and their agriculturally useful salts, compounds for their preparation, and the use of these compounds or of compositions comprising them for controlling undesirable plants are described.
摘要翻译:其中:X为O,NH或N-烷基; R1为硝基,卤素,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; R2,R3,R4,R5为氢, 烷基或卤代烷基; R6是卤素,硝基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; R7是羟基,烷氧基,烯氧基,烷基磺酰氧基,烷基羰基氧基,(烷硫基)羰氧基,苯基磺酰氧基或苯基羰基氧基, 描述了R 8,R 9是烷基; R 10是氢或烷基; R 11是氢或烷基;并且描述了它们的农业上有用的盐,它们的制备化合物,以及这些化合物或包含它们的组合物用于防治不期望的植物的用途。