摘要:
The present invention relates to a lubricant composition containing a minor amount of a thermally stable moldified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein an amide functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
摘要:
A thermoplastic polymer having good tensile strength at elevated temperatures is obtained by modifying a block copolymer composed of a conjugated diene compound and an alkenyl arene compound. The block copolymer is first selectively hydrogenated and thereafter modified by grafting silicon or boron containing functional groups primarily in the alkenyl arene block via metalation. Each silicon containing functional group preferably contains at least two functional groups which allow crosslinking by condensation reactions.
摘要:
Block copolymers are prepared by using two successive and different catalytic processes, a Ziegler-Natta type polymerization followed by a conventional anionic polymerization.
摘要:
Acetone cyanohydrin is converted to alpha-hydroxyisobutyric acid by contacting the cyanohydrin with alpha-hydroxymethanesulfonic acid and water at a temperature of about 70.degree.-125.degree. C. The alpha-hydroxymethanesulfonic acid is an equilibrium product of the reaction of water, sulfur dioxide and formaldehyde.
摘要:
A process for laminating a polar substrate with a film cast from a sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units. The film is exposed to water and dried onto a polar or active metal substrate. The laminates do not delaminate in the presence of water and may be used for a variety of applications including energy exchange applications.
摘要:
The present invention relates to selectively hydrogenated block copolymers where one of the blocks is a random copolymer of a mono-alkenyl arene monomer, such as styrene, and a 1,3-cyclodiene monomer, such as 1,3-cyclohexadiene, and one of the other blocks is a hydrogenated polymer or copolymer of an acyclic conjugated diene, such as 1,3-butadiene or isoprene.
摘要:
Star polymers of isoprene or butadiene having terminal hydroxyl groups have reduced viscosity when the hydroxyl groups are located on polymeric arms that are grown from the core of the star molecules. The polymers are useful in making coatings, sealants, and binders.
摘要:
An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.
摘要:
Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70%. Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要:
Novel metallated polyolefins are produced by contacting a polyolefin having a vinylidene group in the terminal portion with organoalkali metal compound in the presence of alkali metal t-alkoxide or tertiary amine. The metallated polyolefin is used to initiate the polymerization of polymerizable monomers to produce block copolymers of at least two blocks, at least one of which is saturated polyolefin.