摘要:
Epoxy resin is pretreated with an organic solvent such as furfuryl alcohol, methyl alcohol, ethyl alcohol, n-propyl alcohol, iso-propyl alcohol, formic acid, acetic acid, propionic acid, butyric acid, methyl formate, ethyl formate, propyl formate, methyl acetate, ethyl acetate, propyl acetate, methyl propionate, ethyl propionate, propyl propionate, methyl butyrate, ethyl butyrate, propyl butyrate, acetone, diethyl ketone, dipropyl ketone, methylethyl ketone, diisopropyl ketone, methylpropyl ketone, ethylpropyl ketone, acetonitrile and nitromethane as a pretreating solution, and the pretreated resin is then etched with an etching solution containing hydrogen peroxide or a persulfate and sulfuric acid, or the resin is pretreated with an organic solvent containing furfuryl alcohol, methyl alcohol, ethyl alcohol, n-propyl alcohol or isopropyl alcohol, and formamide or ethylene glycol, 1,2-propylene glycol or glycerine, and the pretreated resin is etched with an etching solution containing hydrogen peroxide and sulfuric acid to roughen the surface of the resin. A good adhesiveness is obtained between the surface of the resin and a film of metal when the resin is coated with a metal.
摘要:
A membrane for gas separation which comprises a silylated polyphenylene ether is disclosed. Said silylated polyphenylene ether contains a constituting unit containing an organosilane or siloxane group represented by the following formula in at least a part of the repeating unit thereof: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom or a group of the formula --Si(R.sub.5)(R.sub.6)(R.sub.7), wherein R.sub.5, R.sub.6 and R.sub.7 each represents an alkyl group; l and n each represents 0 or an integer from 1 to 3; and m represent an integer of from 1 to 3; with the proviso that R.sub.1, R.sub.2, R.sub.3 and R.sub.4 do not simultaneously represent hydrogen atoms.
摘要:
A polyphenylene ether resin composition containing (A) a polyphenylene ether resin, (B) an aromatic polyester resin, and (C) a phenoxy resin. The resin composition may further contain (D) an unsaturated carboxylic acid or (E) a vinyl copolymer derived from a styrene compound and an alpha,beta-unsaturated dicarboxylic acid anhydride as comonomer components. The resin composition has excellent mechanical strength, solvent resistance, oil resistance and moldability.
摘要:
A polyphenylene ether resin composition comprising:(a) a polyphenylene ether resin,(b) a polystyrene-type resin,(c) an A-B-A' type elastomeric block copolymer, wherein A and A' represent blocks resulting from polymerization of an aromatic vinyl compound, and B represents a block resulting from polymerization of a conjugated diene compound, and(d) an elastomeric stryene/butadiene random copolymer,which is suitable electroless plating. Molded articles formed by using the resin composition of this invention can be plated using conventional electroless plating processes for ABS resins.
摘要:
A curable resin composition comprising (a) a polyphenylene resin, (b) a maleimide compound and/or a cyanate ester compound and (c) at least one compound selected from the group consisting of compounds having one or more acryloyl, methacryloyl, acryloxy or methacryloxy groups is disclosed. The curable resin composition can give a cured resin having resistance to heat, solvent and moisture and adhering property.
摘要:
A curable polyphenylene ether resin composition comprising(a) a polyphenylene ether resin, and(b) at least one polyfunctional compound selected from the group consisting of polyfunctional maleimides having at least two maleimide groups or the prepolymer thereof, polyfunctional cyanate esters having at least two cyanate ester groups or the prepolymer thereof, and pre-copolymers of the polyfunctional maleimides and the polyfunctional cyanate esters.The cured resin composition has utility in rustproofing paints, electrical insulating varnishes, adhesives and molding material.
摘要:
A polyphenylene ether resin composition having improved heat stability, said composition comprising a polymer matrix composed of a polyphenylene ether resin and a vinyl aromatic resin, and dispersed in the polymer matrix, at least one compound selected from the group consisting of(1). 2-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyanilino)-4,6-di-C.sub.5 -C.sub.15 -alkylthio-1,3,5-triazines,(2). .omega.,.omega.'-thiodi(C.sub.2 -C.sub.6 polymethylene)-bis[3-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)-carboxylates],(3). N,N'-C.sub.2 -C.sub.10 polymethylene-bis[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxamides], and(4). tetrakis-{methylene-[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxylate]}methanes.
摘要:
A resin composition comprising(a) a polyphenylene ether resin or a mixture of it with a polystyrene resin, and(b) a grafted block copolymer of an unsaturated polyolefin and butyl rubber obtained by graft copolymerization in the presence of a bifunctional phenolic compound as a grafting vehicle.
摘要:
In a method for mixing a trioxane, a polymerization catalyst and a comonomer for producing of oxymethylene copolymers by continuously copolymerizing trioxane with a cyclic ether or a cyclic acetal as a comonomer, the improved method comprises following steps:spouting a comonomer and a polymerization catalyst from nozzle openings which are set adjacent to each other,while washing both openings at the tip end of the nozzles with a flow of trioxane,whereby mixing said comonomer, said polymerization catalyst and said trioxane,and then feeding the mixture to a polymerization reactor to effect copolymerization.The raw materials are mixed together before they are fed to the polymerization reactor, and no clogging trouble at the tip end of the nozzle for feeding a polymerization catalyst occurs. Further the resulting copolymer has a much superior heat stability. In addition, since each of the reaction raw materials is quantititively fed, the molecular weight and conversion of the copolymer extended from the polymerization reactor is so constant that a stabilized operation of the polymerization reactor can be secured.