公开(公告)号：US4431725A

公开(公告)日：1984-02-14

申请号：US399583

申请日：1982-07-19

申请人： Hiromichi Tachikawa ,  Yohnosuke Takahashi ,  Fumiaki Shinozaki ,  Tomoaki Ikeda

发明人： Hiromichi Tachikawa ,  Yohnosuke Takahashi ,  Fumiaki Shinozaki ,  Tomoaki Ikeda

IPC分类号： G03C1/72 ,  G03F7/004 ,  G03F7/022 ,  G03F7/26 ,  G03C1/58

CPC分类号： G03F7/0226

摘要： A light-sensitive material having on a support a light-sensitive layer containing an o-quinonediazide compound as a main component and, additionally, a particular compound represented by the following general formula (I): ##STR1## wherein Z represents the nonmetallic atoms forming a 5-membered ring; X represents S, O, ##STR2## or .dbd.N--R.sub.c (where R.sub.a, R.sub.b and R.sub.c are each a hydrogen atom or an organic group other than a carboxylic acid group); and Y is a hydrogen atom or an organic group other than a carboxylic acid group, is disclosed. This material can provide both positive and negative working images having high resolution and good adhesiveness to the support. A process for producing positive working images includes the steps of imagewise exposure and development processing, while a process for producing negative working images includes the steps of imagewise exposure, heating, uniform (overall) exposure and development processing. The same conditions regarding imagewise exposure and development processing, respectively, can be applied to both processes.

摘要翻译： 一种感光材料，其在载体上具有含有邻醌二叠氮化合物作为主要成分的感光层，另外还包含由以下通式（I）表示的特定化合物：其中Z表示 形成5元环的非金属原子; X表示S，O，或= N-Rc（其中Ra，Rb和Rc各自为氢原子或除羧酸基团之外的有机基团）; 并且Y是氢原子或除羧酸基以外的有机基团。 该材料可以提供具有高分辨率和对支持体的良好粘附性的正和负工作图像。 用于产生正面工作图像的方法包括成像曝光和显影处理的步骤，而用于产生负面工作图像的处理包括成像曝光，加热，均匀（总体）曝光和显影处理的步骤。 分别对成像曝光和显影处理的相同条件可以应用于两个处理。

公开(公告)号：US4298679A

公开(公告)日：1981-11-03

申请号：US57149

申请日：1979-07-12

申请人： Fumiaki Shinozaki ,  Yasuo Washigawa ,  Tomoaki Ikeda ,  Sho Nakao ,  Syunichi Kondoh

发明人： Fumiaki Shinozaki ,  Yasuo Washigawa ,  Tomoaki Ikeda ,  Sho Nakao ,  Syunichi Kondoh

IPC分类号： C08F2/00 ,  C08F2/50 ,  G03F7/031 ,  H01L21/027 ,  G03C1/68

CPC分类号： G03F7/031 ,  Y10S430/12 ,  Y10S430/124

摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.

摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可以相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子

公开(公告)号：US4264713A

公开(公告)日：1981-04-28

申请号：US35969

申请日：1979-05-04

申请人： Fumiaki Shinozaki ,  Tomoaki Ikeda ,  Sadaharu Ikeda ,  Chiaki Osada

发明人： Fumiaki Shinozaki ,  Tomoaki Ikeda ,  Sadaharu Ikeda ,  Chiaki Osada

IPC分类号： C08F2/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/00 ,  C08F299/04 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L67/00 ,  G03F7/004 ,  G03F7/038 ,  G03C5/00

CPC分类号： G03F7/0384 ,  G03F7/0388

摘要： A light-sensitive lithographic printing plate comprising a support and a layer of a light-sensitive composition thereon consisting of a light-sensitive polymer containing a --CH.dbd.CHCO-- unit in its main chain and a light-sensitive polymer containing a --CH.dbd.CHCO-- unit in its side chain(s).

摘要翻译： 一种感光平版印刷版，其包含支撑体和其上由其主链中含有-CH = CHCO-单元的光敏聚合物组成的感光组合物和含有-CH = CHCO-单元的光敏聚合物，所述光敏聚合物含有-CH = CHCO-单位在其侧链。

公开(公告)号：US4175971A

公开(公告)日：1979-11-27

申请号：US832864

申请日：1977-09-13

申请人： Fumiaki Shinozaki ,  Yasuo Washigawa ,  Tomoaki Ikeda ,  Sho Nakao ,  Syunichi Kondoh

发明人： Fumiaki Shinozaki ,  Yasuo Washigawa ,  Tomoaki Ikeda ,  Sho Nakao ,  Syunichi Kondoh

IPC分类号： C08F2/00 ,  C08F2/50 ,  G03F7/031 ,  H01L21/027 ,  G03C1/68 ,  C08F2/46

CPC分类号： G03F7/031 ,  Y10S430/12 ,  Y10S430/124

摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## where R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.

摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子

公开(公告)号：US4164421A

公开(公告)日：1979-08-14

申请号：US755308

申请日：1976-12-29

申请人： Fumiaki Shinozaki ,  Tomoaki Ikeda

发明人： Fumiaki Shinozaki ,  Tomoaki Ikeda

IPC分类号： G03F7/095

CPC分类号： G03F7/0955

摘要： A photosensitive printing plate comprising a support having thereon a photosensitive layer comprising a photo-curable composition and an o-quinonediazide compound in an amount of about 0.05 to 4 parts by weight per part by weight of the photo-curable composition.

摘要翻译： 一种光敏印刷版，其包含其上包含光可固化组合物和邻醌二叠氮化合物的感光层的载体，其量为每重量份光固化组合物约0.05至4重量份。

公开(公告)号：US4139391A

公开(公告)日：1979-02-13

申请号：US767865

申请日：1977-02-11

申请人： Tomoaki Ikeda ,  Hiroshi Misu ,  Yoshimasa Aotani ,  Fumiaki Shinozaki

发明人： Tomoaki Ikeda ,  Hiroshi Misu ,  Yoshimasa Aotani ,  Fumiaki Shinozaki

IPC分类号： G03C1/00 ,  G03F1/08 ,  G03F7/027 ,  G03F7/033 ,  H01L21/027 ,  G03C1/68

CPC分类号： G03F1/68 ,  G03F7/033 ,  Y10S430/111

摘要： A light-sensitive resin composition containing (a) at least one ethylenically unsaturated compound having at least two terminal ethylenically unsaturated groups, which is capable of forming a polymer through photo-addition polymerization, and which has a boiling point of about 100.degree. C. or higher at atmospheric pressure, (b) an addition polymerization initiator activatable by irradiation with actinic radiation, and (c) an organic high polymer binder having water-solubilizing groups in the side chains thereof, wherein the improvement comprises the binder being a copolymer containing (A) a repeating unit derived from at least one compound selected from the group consisting of acrylic acid and methacrylic acid and (B) a repeating unit derived from at least one compound selected from the group consisting of benzyl acrylate, benzyl methacrylate, phenethyl acrylate, phenethyl methacrylate, 3-phenylpropyl acrylate, 3-phenylpropyl methacrylate, 4-phenylbutyl acrylate and 4-phenylbutyl methacrylate.

摘要翻译： 一种感光性树脂组合物，其含有（a）至少一种具有至少两个末端烯键式不饱和基团的烯属不饱和化合物，其能够通过光加成聚合形成聚合物，并且其沸点为约100℃。 或更高，（b）通过用光化辐射照射可激活的加成聚合引发剂，和（c）在其侧链具有水溶性基团的有机高分子粘合剂，其中改进包括粘合剂，其是含有 （A）衍生自至少一种选自丙烯酸和甲基丙烯酸的化合物的重复单元和（B）衍生自至少一种选自丙烯酸苄酯，甲基丙烯酸苄酯，丙烯酸苯乙酯的化合物的重复单元 ，甲基丙烯酸苯乙酯，丙烯酸3-苯基丙酯，甲基丙烯酸3-苯基丙酯，丙烯酸4-苯基丁酯，甲基丙烯酸4-苯基丁酯 叶酸盐。

公开(公告)号：US6133929A

公开(公告)日：2000-10-17

申请号：US392094

申请日：1999-09-08

申请人： Toshihiko Negoro ,  Yoshiyuki Obata ,  Fumiaki Shinozaki

发明人： Toshihiko Negoro ,  Yoshiyuki Obata ,  Fumiaki Shinozaki

IPC分类号： B41J2/335 ,  B41J2/325

CPC分类号： B41J2/33515 ,  B41J2/33545 ,  B41J2/3357

摘要： A melting type thermal transfer recording system capable of providing multi-gradation images of high resolution and high image quality comparable to those of ink jet recording system or sublimation type thermal transfer recording system is disclosed which comprising: a donor film comprising a thin film and a thermal melting type ink layer provided on the thin film, the thermal melting type ink layer having a thickness in a range of 0.5 to 2.5 .mu.m, a surface porous type recording medium comprising a base material and a porous ink receiving layer having numerous minute pores provided on the base material, the ratio of the first total area of aperture portions that are occupied by all the pores to the whole surface area of the porous ink receiving layer being in a range of 10 to 60%, and the ratio of the second total area of aperture portions that are occupied by pores having a pore diameter of 0.5 to 20 .mu.m to the first total area of the aperture portions being 70 to 100%, a thermal head comprising a plurality of heating resistor units arranged in a line at intervals of 8 dots/mm or less, each of the heating resistor units comprising a pair of heating resistor elements of identical shape, a gradation control means for controlling an amount of an ink of the ink layer melted with the heating resistor units by controlling an amount of electricity supplied to the thermal head.

摘要翻译： 公开了一种熔融型热转印记录系统，其能够提供与喷墨记录系统或升华型热转印记录系统相当的高分辨率和高图像质量的多灰度图像，其包括：施主膜，其包括薄膜和 设置在薄膜上的热熔型油墨层，热熔型油墨层的厚度在0.5〜2.5μm的范围内，表面多孔型记录介质包括基材和具有许多微孔的多孔油墨接收层 设置在所述基材上，所述多孔墨水接收层的所有孔的占据的开口部的第一总面积与所述多孔墨接受层的整个表面积的比率为10〜60％的范围，所述第二 孔径为孔径部分的第一总面积为0.5〜20μm的孔所占据的开口部的总面积为70〜100％ ad包括以8点/ mm以下的间隔配置成一行的多个发热电阻体，每个加热电阻单元包括一对相同形状的加热电阻元件，用于控制墨水量的灰度控制装置 通过控制供给到热敏头的电量而与加热电阻器单元熔融的油墨层。

公开(公告)号：US5593802A

公开(公告)日：1997-01-14

申请号：US319567

申请日：1994-10-07

申请人： Morimasa Sato ,  Fumiaki Shinozaki

发明人： Morimasa Sato ,  Fumiaki Shinozaki

IPC分类号： G02F1/1339 ,  C09K19/00 ,  G02F1/13

CPC分类号： G02F1/13394

摘要： A method of forming a spacer for supporting two substrates which constitute a liquid crystal panel, wherein the spacer is disposed between the two substrates, at least one of which has thereon an alignment layer which has been subjected to aligning treatment, comprising the steps of: (1) laminating the substrate having the alignment layer on a transfer sheet comprising projections of substantially uniform thickness on a temporary support in such a manner that the projections closely contact the alignment layer, and (2) peeling-off the temporary support to transfer the projections onto the alignment layer. The inventive method forms a spacer through a simple step and at a uniform density, and prevents damage of an aligning layer.

摘要翻译： 一种形成用于支撑构成液晶面板的两个基板的间隔件的方法，其中所述间隔件设置在所述两个基板之间，其中至少一个在其上具有经过对准处理的取向层，包括以下步骤： （1）将具有取向层的基板在具有基本上均匀厚度的突起的转印片上以临时支撑体的方式层叠，使得突起紧密接触对准层，和（2）剥离临时支撑以转移 投影到对准层上。 本发明的方法通过简单的步骤和均匀的密度形成间隔物，并且防止对准层的损坏。

公开(公告)号：US5455142A

公开(公告)日：1995-10-03

申请号：US964052

申请日：1992-10-21

申请人： Yohnosuke Takahashi ,  Hideyuki Nakamura ,  Fumiaki Shinozaki ,  Shinji Tsuno

发明人： Yohnosuke Takahashi ,  Hideyuki Nakamura ,  Fumiaki Shinozaki ,  Shinji Tsuno

IPC分类号： G03F3/10 ,  G03C3/00

CPC分类号： G03F3/103

摘要： An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively. The process steps include:A) imagewise exposing the first light-sensitive layer;B) contacting the first light-sensitive layer with layer (a') in the first toner element;C) separating the first toner element and the first light-sensitive element, transferring the toner layer portion corresponding to the unexposed portion of the light-sensitive layer to the light-sensitive layer and leaving the toner layer portion corresponding to the exposed portion of the light-sensitive layer on the support for the first toner element;D) contacting the adhesive surface of an image receiving element with the surface of the toner layer of the first toner element on which the toner layer has been left corresponding to the exposed portion of the first light-sensitive layer;E) separating the image receiving element and the first toner element, transferring the toner layer to the image receiving element;F) repeating A) to C) with the second light-sensitive element and toner element, respectively; andG) contacting the surface of the transferred toner layer of the image receiving element on which the hue (a) toner layer has been transferred with the surface of the hue (b) toner layer and separating the image receiving element and the second toner element, transferring the hue (b) toner layer to the image receiving element.

公开(公告)号：US5397678A

公开(公告)日：1995-03-14

申请号：US216327

申请日：1994-03-23

申请人： Morimasa Sato ,  Masayuki Iwasaki ,  Fumiaki Shinozaki ,  Koji Inoue

发明人： Morimasa Sato ,  Masayuki Iwasaki ,  Fumiaki Shinozaki ,  Koji Inoue

IPC分类号： G03F3/10 ,  G03F7/16 ,  G03F7/34 ,  H05K3/00 ,  G03C11/12

CPC分类号： G03F7/161 ,  G03F3/10 ,  G03F7/346 ,  H05K3/0079

摘要： A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer. If the thermoplastic resin layer and the intermediate layer are first removed with a processing method with which the photosensitive resin layer is not substantially developed and then the photosensitive resin layer is developed using a processing solution other than used for revmoving the thermoplastic resin layer and the intermediate layer, excessive fatigue of the developing solution for the photosensitive resin layer and unevenness of development can be prevented.

摘要翻译： 光敏转印材料包括依次设置有碱溶性热塑性树脂树脂层，中间层和感光性树脂层的临时基材，在热塑性树脂层之间的界面处，转印材料中的层间粘合力最小 和临时衬底。 可以将感光性树脂层转印到永久性基板上，而不会由于细小的灰尘，气泡或永久基板的不均匀性而导致故障。 可以通过至少在加热下将转印材料粘附到永久性基板上，并且在剥离临时基板之后，使感光性树脂层成像曝光，并且处理转印层以显影感光性树脂层 。 如果首先用感光性树脂层未显影的处理方法去除热塑性树脂层和中间层，然后使用除了用于将热塑性树脂层和中间体的旋转以外的处理溶液使感光性树脂层显影 可以防止感光性树脂层的显影液的过度疲劳和显影不均匀。