Biodegradable free-radical addition polymers
    42.
    发明授权
    Biodegradable free-radical addition polymers 失效
    可生物降解的自由基加成聚合物

    公开(公告)号:US5264510A

    公开(公告)日:1993-11-23

    申请号:US973856

    申请日:1992-11-09

    摘要: This invention is directed to a terpolymer containing as polymerized units at least one first monomer selected from the group of vinyl acetate, vinyl ethers and vinyl carbonates, at least one second monomer of an ethylenically unsaturated monocarboxylic acid, and at least one third monomer of an anhydride of a dicarboxylic acid. The terpolymer is formed by a free-radical polymerization in a nonaqueous solvent. It has further been discovered that the partial hydrolysis, saponification, and saponification followed by oxidation of this terpolymer leads to terpolymer derivatives with improved detergent properties and improved biodegradability.

    摘要翻译: 本发明涉及含有作为聚合单元的三元共聚物,所述三元共聚物含有至少一种选自乙酸乙烯酯,乙烯基醚和碳酸乙烯酯的第一单体,至少一种烯属不饱和一元羧酸的第二单体和至少一种第三单体 二羧酸的酐。 三元共聚物通过在非水溶剂中的自由基聚合形成。 进一步发现,部分水解,皂化和皂化随后氧化该三元共聚物,导致三元共聚物衍生物具有改进的洗涤剂性能和改善的生物降解性。

    Emulsion polymer of heterogeneous molecular weight and preparation
thereof
    43.
    发明授权
    Emulsion polymer of heterogeneous molecular weight and preparation thereof 失效
    非均相分子量的乳液聚合物及其制备方法

    公开(公告)号:US4501845A

    公开(公告)日:1985-02-26

    申请号:US499127

    申请日:1983-05-31

    IPC分类号: C08F2/16 C08F2/22 C08F2/38

    CPC分类号: C08F2/38 C08F2/22

    摘要: Disclosed is a polymer and its preparation by reacting part of the monomers in the reactor in such a way as to obtain a high molecular weight product, and reacting at least one other portion of the monomer in the same reactor in such a way as to obtain at least one low molecular weight fraction. The products are useful in contact adhesives, particularly when blended with an aminoplast or phenoplast as a tackifier and crosslinker, and with a thickening agent such as polyvinyl alcohol.

    摘要翻译: 公开了聚合物及其制备方法,其中反应器中的部分单体以获得高分子量产物的方式反应,并使单体的至少一个其它部分在同一反应器中以获得 至少一种低分子量级分。 该产品在接触粘合剂中是有用的,特别是当与氨基塑料或酚醛树脂作为增粘剂和交联剂以及增稠剂如聚乙烯醇混合时。

    Pigment dispersions containing copolymer of oxazolidinylalkyl or
oxazolidinylalkoxyalkyl (meth)acrylate
    44.
    发明授权
    Pigment dispersions containing copolymer of oxazolidinylalkyl or oxazolidinylalkoxyalkyl (meth)acrylate 失效
    含有恶唑烷基烷基或(甲基)丙烯酸恶唑烷基烷氧基烷基酯的共聚物的颜料分散体

    公开(公告)号:US4310453A

    公开(公告)日:1982-01-12

    申请号:US114544

    申请日:1980-01-23

    摘要: Low molecular weight addition copolymers, of (1) (meth)acrylic acid esters of alcohols such as methanol and butanol with (2) esters of alcohols such as N-(.beta.-hydroxyethyl)oxazolidine and unsaturated acids such as a (meth)acrylic acid, and (3) optional .alpha.,.beta.-ethylenically unsaturated monomers such as a (meth)acrylic acid, are found to be exceptional dispersants for inorganic and organic pigments and colorants which are insoluble in organic solvents, for lacquers, and are compatible with practically all types of lacquer resins such as vinyls, nitrocellulose, and alkyds, and with many other types of lacquer film-forming materials. Usually, when small amounts of unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymers, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints and printing inks are examples of uses for such blends.

    摘要翻译: (1)(甲基)丙烯酸酯(如甲醇和丁醇)与(2)醇类如N-(β-羟乙基)恶唑烷和不饱和酸如(甲基)丙烯酸酯的(1)(甲基)丙烯酸酯的低分子量加成共聚物 酸和(3)任选的α,β-烯属不饱和单体如(甲基)丙烯酸被发现是无机和有机颜料和着色剂的特殊分散剂,它们不溶于有机溶剂,用于漆,并且与 几乎所有类型的漆树脂如乙烯基,硝化纤维素和醇酸树脂,以及许多其它类型的漆膜形成材料。 通常,当少量不饱和羧酸或其它极性单体及其组合引入聚合物时,它们变成改进的颜料分散剂。 意外地,这种颜料分散体可以用许多类型的合成树脂放下,并通过空气干燥或烘烤涂覆的制品来使用。 用于金属,油漆和印刷油墨的油漆是用于这种共混物的实例。