PICOLYLAMINE RESINS
    41.
    发明申请
    PICOLYLAMINE RESINS 有权
    PICOLYLAMINE树脂

    公开(公告)号:US20110086935A1

    公开(公告)日:2011-04-14

    申请号:US12919851

    申请日:2009-02-27

    IPC分类号: C08F8/32

    摘要: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

    摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。

    Heat-stable anion exchangers
    43.
    发明申请
    Heat-stable anion exchangers 有权
    热稳定阴离子交换剂

    公开(公告)号:US20080087604A1

    公开(公告)日:2008-04-17

    申请号:US11899125

    申请日:2007-09-04

    IPC分类号: C08J9/00 B01D15/04

    摘要: The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak′, Ak″ are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2 and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ⅓ PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.

    摘要翻译: 本发明涉及基于至少一种芳族单体和至少一种具有通式(I)的结构元件的交联剂的热稳定阴离子交换剂,其中Ak,Ak',Ak“在每种情况下彼此独立地彼此独立地 或者不同的是C 1 -C 18 - 烷基,n是5至18之间的偶数,x + y = 2,X是Cl,Br,OH, HCO 3,HSO 4,½(SO 4 S),1/3 CO 3,NO 3, / SUB,F,H 2 PO 4,1/2 HPO 4,1/3 PO 4,和 结果是这些阴离子交换剂优选为OH形式,在相当长的时间内经受至少60℃,优选至少80℃的工作温度,其制备方法及其用途。

    Process for the preparation of silicon-dioxide-containing polymer beads
    46.
    发明申请
    Process for the preparation of silicon-dioxide-containing polymer beads 审中-公开
    制备含二氧化硅的聚合物珠粒的方法

    公开(公告)号:US20050245664A1

    公开(公告)日:2005-11-03

    申请号:US11108962

    申请日:2005-04-19

    CPC分类号: C08F112/08 C08F2/10 C08F2/44

    摘要: The present invention relates to a process for the preparation of silicon-dioxide-containing polymer beads by producing a mixture of styrene, crosslinker, finely divided surface-modified silicon dioxide, free-radical initiator and, if appropriate, inert agent and curing the resultant mixture in aqueous phase at elevated temperature to give a polymer bead, the silicon-dioxide-containing polymer beads themselves, and also uses thereof.

    摘要翻译: 本发明涉及通过制备苯乙烯,交联剂,细分散的表面改性二氧化硅,自由基引发剂和(如果合适的话)惰性剂的混合物制备含二氧化硅的聚合物珠粒的方法,并固化所得物 在高温下在水相中混合,得到聚合物珠粒,含二氧化硅的聚合物珠粒本身,以及其用途。

    Picolylamine resins
    50.
    发明授权
    Picolylamine resins 有权
    吡啶基胺树脂

    公开(公告)号:US08562922B2

    公开(公告)日:2013-10-22

    申请号:US12919846

    申请日:2009-02-27

    摘要: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

    摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式(I)的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 )作为官能团,其中R 1是由吡啶基,甲基喹啉和甲基哌啶组成的组中的任意取代的基团,R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH( NH 2)COOR 3或-CH 2 -S-CH 2 -CH(OH)-CH 2(OH)或其衍生物或-C = S(NH 2),R 3是由H,Na和K组成的组的基团,m是 1〜4的整数,n和p各自独立地为0.1〜1.9的数,n和p的和为2,M为聚合物基质,其制备方法及其制备方法 尤其用于湿法冶金和电镀。