公开(公告)号：US4092110A

公开(公告)日：1978-05-30

申请号：US770094

申请日：1977-02-18

申请人： Heinrich Adolphi ,  Matthias Schwarzmann ,  Peter Heinze

发明人： Heinrich Adolphi ,  Matthias Schwarzmann ,  Peter Heinze

IPC分类号： A01N41/04 ,  B27K3/36 ,  A01N9/12 ,  A01N9/24

CPC分类号： A01N41/04 ,  B27K3/18 ,  B27K3/20 ,  B27K3/30 ,  Y10S424/11

摘要： Wood preservatives for protecting wood or wood-base materials against animal pests, and which contain a perfluoroalkane sulfonate of the formula C.sub. n F.sub.2n+1 --SO.sub.3 M where n is one of the integers from 1-14 and M denotes hydrogen or a cation, and a process for protecting wood or wood-base materials against animal pests with these compounds.

摘要翻译： 木质防腐剂用于保护木材或木质材料免受动物害虫影响，并含有式C nF2n + 1-SO3 M的全氟烷基磺酸盐，其中n是1-14的整数之一，M表示氢或阳离子，和 用这些化合物保护木材或木质基料免受动物害虫的过程。

公开(公告)号：US5300269A

公开(公告)日：1994-04-05

申请号：US757387

申请日：1991-09-10

申请人： Heinrich Aichinger ,  Karl-Heinz Boehning ,  Klaus Herzog ,  Hermann Wistuba ,  Gert Buerger ,  Matthias Schwarzmann ,  Guenter Herrmann

发明人： Heinrich Aichinger ,  Karl-Heinz Boehning ,  Klaus Herzog ,  Hermann Wistuba ,  Gert Buerger ,  Matthias Schwarzmann ,  Guenter Herrmann

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J23/50 ,  B01J35/10 ,  B01J8/00 ,  G01B17/00

CPC分类号： B01D53/8628 ,  B01J23/50 ,  B01D2255/104 ,  B01D2255/9207 ,  B01D2257/402 ,  B01J35/1014 ,  Y02C20/10

摘要： A catalyst for decomposing dinitrogen monoxide which is pure or present in gas mixtures comprises metallic silver applied to an alumina carrier with a BET surface area of from 5 to 25 m.sup.2 /g.

摘要翻译： 用于分解纯的或存在于气体混合物中的一氧化二氮的催化剂包括施加到BET表面积为5至25m 2 / g的氧化铝载体上的金属银。

公开(公告)号：US4786402A

公开(公告)日：1988-11-22

申请号：US082139

申请日：1987-08-06

申请人： Thomas Anstock ,  Walter Himmel ,  Matthias Schwarzmann ,  Heinz Dreyer ,  Ulrich Lebert ,  Ansgar Eisenbeis

发明人： Thomas Anstock ,  Walter Himmel ,  Matthias Schwarzmann ,  Heinz Dreyer ,  Ulrich Lebert ,  Ansgar Eisenbeis

IPC分类号： B01J23/755 ,  B01J37/18 ,  C10G45/48 ,  C10G49/04 ,  C10G65/08 ,  C10G67/08 ,  C10G45/04

CPC分类号： B01J23/755 ,  B01J37/18 ,  C10G45/48 ,  C10G49/04 ,  C10G65/08 ,  C10G67/08

摘要： Medicinal white oils and medicinal paraffins are prepared from petroleum fractions containing aromatics and nitrogen, oxygen and sulfur compounds, e.g. light and heavy atmospheric gas oils, vacuum gas oils and residues, which have been pretreated in a first stage by acid treatment or catalytic hydrogenation, by hydrogenation in a second stage over a nickel-containing catalyst under from 50 to 200 bar and at elevated temperatures, by a process in which the catalyst used in the second stage and present in the oxide form is reduced with a hydrogen-containing gas, passivated and then again activated with hydrogen, before the hydrogenation to medicinal white oils or paraffins is carried out.

摘要翻译： 药用白油和药用石蜡由含有芳烃和氮，氧和硫化合物的石油馏分制备， 通过酸处理或催化氢化在第一阶段通过第二阶段在含镍催化剂上在50至200巴下氢化并在高温下进行预处理的轻质和重质常压瓦斯油，减压瓦斯油和残余物 通过在氢化之前用含氢气体还原第二阶段中使用的并以氧化物形式存在的催化剂被钝化然后再次用氢活化的方法，在氢化之前进行药用白油或石蜡。

公开(公告)号：US4551321A

公开(公告)日：1985-11-05

申请号：US476577

申请日：1983-03-18

申请人： Laszlo Marosi ,  Hans-Ulrich Schlimper ,  Matthias Schwarzmann ,  Joachim Stabenow

发明人： Laszlo Marosi ,  Hans-Ulrich Schlimper ,  Matthias Schwarzmann ,  Joachim Stabenow

IPC分类号： B01J29/40 ,  C01B39/40 ,  C07C1/20 ,  C01B33/28

CPC分类号： C07C1/20 ,  B01J29/40 ,  C01B33/2876 ,  C01B33/2884 ,  C01B35/1009 ,  C07C2529/40 ,  Y02P30/42 ,  Y10S423/22

摘要： A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO.sub.2 and Al(OH).sub.3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali, at from 100.degree. to 200.degree. C., wherein the crystallization is carried out in the presence of a triamine, tetraamine and/or higher amine and the reaction mixture is formulated to have an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio defined by an equation which involves the chain length and number of amine groups of the amine employed, as well as to have certain molar ratios of H.sub.2 O/amine and amine/Al.sub.2 O.sub.3, and the use of these zeolites as catalysts for the conversion of alcohols and/or dialkyl ethers to olefins and/or aromatics.

摘要翻译： 在不存在碱的情况下，在100〜200℃下，通过在胺水溶液中水热结晶，从SiO 2和Al（OH）3的混合物中制备ZSM-5结构型沸石的方法， 其中所述结晶在三胺，四胺和/或更高级胺的存在下进行，并且所述反应混合物被配制成具有由包含胺的链长度和胺基数的方程定义的SiO 2 / Al 2 O 3摩尔比 以及具有一定摩尔比的H 2 O /胺和胺/ Al 2 O 3，以及这些沸石作为用于将醇和/或二烷基醚转化为烯烃和/或芳族化合物的催化剂的用途。

公开(公告)号：US4530910A

公开(公告)日：1985-07-23

申请号：US543822

申请日：1983-10-20

申请人： Wolf D. Mross ,  Matthias Schwarzmann ,  Juergen Plueckham ,  Juergen Dehler

发明人： Wolf D. Mross ,  Matthias Schwarzmann ,  Juergen Plueckham ,  Juergen Dehler

IPC分类号： B01J21/20 ,  B01J23/50 ,  B01J23/96 ,  B01J38/48 ,  C07B61/00 ,  C07D301/10 ,  C07D303/04

CPC分类号： B01J38/60 ,  B01J21/20 ,  B01J23/66 ,  B01J23/688 ,  B01J23/8926 ,  B01J23/96 ,  B01J38/485 ,  C07D301/10 ,  Y02P20/584 ,  Y10S502/503

摘要： The Al.sub.2 O.sub.3 carrier material from Ag/Al.sub.2 O.sub.3 supported catalysts which is obtained after the silver has been removed from such spent catalysts in a conventional manner is regenerated by a method in which the carrier material(a) is treated with an aqueous solution of a water-soluble salt or hydroxide of a metal of group IIA, IIIB or IVB of the Periodic Table or of aluminum, copper, manganese, zinc, cadmium, tin or lead, and the material treated in this manner is then dried, and/or the material(b) is heated at 750-1,500.degree. C. for not less than 10 minutes.

摘要翻译： 通过常规方法从这种废催化剂除去银后获得的Ag / Al 2 O 3载体催化剂的Al 2 O 3载体材料通过其中载体材料（a）用水溶液处理的方法再生， 然后将经过该方法处理的物质的铝，铜，锰，锌，镉，锡或铅的IIA，IIIB或IVB族金属的可溶性盐或氢氧化物干燥，和/或材料 （b）在750-1,500℃下加热不少于10分钟。

公开(公告)号：US4489170A

公开(公告)日：1984-12-18

申请号：US470942

申请日：1983-03-01

申请人： Richard Krabetz ,  Matthias Schwarzmann

发明人： Richard Krabetz ,  Matthias Schwarzmann

IPC分类号： B01J27/188 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J27/14 ,  C07C51/16

CPC分类号： B01J27/19 ,  C07C51/252

摘要： Oxidation catalysts which in addition to oxygen ions, with or without NH.sub.4.sup.+ ions, contain molybdenum, tungsten, phosphorus and antimony as basic components, in the atomic ratio Mo:W:P:Sb=12:0.1-3:0.1-4:0.1-3, and which are prepared in a conventional manner by combining molybdenum, phosphorus, antimony and tungsten compounds in aqueous solutions or suspensions, removing the water and calcining the residues, the combination being carried out at chloride ion concentrations of less than 0.3 mole per mole of molybdenum and in the presence of ions of monocarboxylic acids of 1 or 2 carbon atoms, dicarboxylic acids or hydroxycarboxylic acids, are particularly suitable for the gas phase oxidation of methacrolein to methacrylic acid.

摘要翻译： 除了具有或不具有NH 4+离子的氧离子之外，氧原子催化剂以Mo，W：P：Sb = 12：0.1-3：0.1-4：0.1的原子比含有钼，钨，磷和锑作为碱性组分 -3，并且以常规方式通过在水溶液或悬浮液中组合钼，磷，锑和钨化合物来制备，除去水和煅烧残余物，所述组合在氯离子浓度小于0.3摩尔/ 摩尔钼，在1或2个碳原子的一元羧酸的离子存在下，二羧酸或羟基羧酸，特别适用于将甲基丙烯醛气相氧化成甲基丙烯酸。

公开(公告)号：US4404175A

公开(公告)日：1983-09-13

申请号：US268379

申请日：1981-05-29

申请人： Laszlo Marosi ,  Hans-Ulrich Schlimper ,  Matthias Schwarzmann ,  Joachim Stabenow

发明人： Laszlo Marosi ,  Hans-Ulrich Schlimper ,  Matthias Schwarzmann ,  Joachim Stabenow

IPC分类号： B01J29/40 ,  C01B39/40 ,  C07C1/20 ,  C01B33/28

CPC分类号： C07C1/20 ,  B01J29/40 ,  C01B33/2876 ,  C01B33/2884 ,  C01B35/1009 ,  C07C2529/40 ,  Y02P30/42 ,  Y10S423/22

摘要： A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO.sub.2 and Al(OH).sub.3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali, at from 100.degree. to 200.degree. C., wherein the crystallization is carried out in the presence of a triamine, tetraamine and/or higher amine and the reaction mixture is formulated to have an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio defined by an equation which involves the chain length and number of amine groups of the amine employed, as well as to have certain molar ratios of H.sub.2 O/amine and amine/Al.sub.2 O.sub.3, and the use of these zeolites as catalysts for the conversion of alcohols and/or dialkyl ethers to olefins and/or aromatics

摘要翻译： 在不存在碱的情况下，在100〜200℃下，通过在胺水溶液中水热结晶，从SiO 2和Al（OH）3的混合物中制备ZSM-5结构型沸石的方法， 其中所述结晶在三胺，四胺和/或更高级胺的存在下进行，并且所述反应混合物被配制成具有由包含胺的链长度和胺基数的方程定义的SiO 2 / Al 2 O 3摩尔比 并且具有一定摩尔比的H 2 O /胺和胺/ Al 2 O 3

公开(公告)号：US4401637A

公开(公告)日：1983-08-30

申请号：US234925

申请日：1981-02-17

申请人： Laszlo Marosi ,  Joachim Stabenow ,  Matthias Schwarzmann

发明人： Laszlo Marosi ,  Joachim Stabenow ,  Matthias Schwarzmann

IPC分类号： C01G17/00 ,  B01J29/00 ,  B01J29/04 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J31/02 ,  C01B33/26 ,  C01B35/12 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/12 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  C07C1/00 ,  C07C1/20 ,  C07C2/00 ,  C07C67/00 ,  C07F5/06 ,  C01B33/28 ,  B01D29/16

CPC分类号： C07C1/20 ,  B01J29/04 ,  B01J31/0254 ,  C01B33/2876 ,  C01B35/1009 ,  C07C2529/04 ,  C07C2529/06 ,  Y10S423/34

摘要： Crystalline isotactic zeolites having the composition2/.pi.R.multidot.W.sub.2 O.sub.3 .multidot.m YO.sub.2 .multidot.p H.sub.2 Owhere R is an organic amine and n is the number of amine groups in the amine molecule, W is one or more of the elements B, Al, Ga and Fe and Y is Si and/or Ge, and a process for the preparation of these crystalline isotactic metal silicate zeolites from mixtures of YO.sub.2 and W(OH).sub.3 by hydrothermal crystallization at from 100.degree. to 200.degree. C. with the aid of an organic amine, in the absence of an alkali metal base, alkaline earth metal base or quaternary nitrogen base or their intermediates, the number m depending on the chain length of the organic amine used in the crystallization.

摘要翻译： 具有组成2 / pi RxW2O3xm YO2xpH2O的结晶全同立构沸石，其中R是有机胺，n是胺分子中的胺基数，W是元素B，Al，Ga和Fe中的一种或多种，​​Y是Si 和/或Ge，以及通过在100℃至200℃下借助于有机胺通过水热结晶从YO 2和W（OH）3的混合物制备这些结晶全同立构金属硅酸盐沸石的方法， 不存在碱金属碱，碱土金属碱或季氮碱或其中间体，其数量取决于用于结晶的有机胺的链长。

公开(公告)号：US4278562A

公开(公告)日：1981-07-14

申请号：US959684

申请日：1978-11-13

申请人： Wolf D. Mross ,  Eckart Titzenthaler ,  Juergen Koopmann ,  Matthias Schwarzmann ,  Volker Vogt

发明人： Wolf D. Mross ,  Eckart Titzenthaler ,  Juergen Koopmann ,  Matthias Schwarzmann ,  Volker Vogt

IPC分类号： B01J23/66 ,  B01J23/78 ,  B01J31/22 ,  C07B61/00 ,  C07D301/10 ,  C07D303/04 ,  B01J31/02 ,  B01J23/50 ,  B01J23/96

CPC分类号： C07D301/10 ,  B01J23/66 ,  Y02P20/52 ,  Y10S502/514

摘要： A catalyst for the manufacture of ethylene oxide, giving improved yield and having a long life, based on an alkali metal-modified silver catalyst on an oxide carrier is obtained by providing the silver-containing catalyst, in the reduced state, with the alkali metal by applying an alcoholic alkali metal salt solution which also contains an organic oxygen compound or nitrogen compound which forms complexes with silver ions.

摘要翻译： 通过提供还原状态的含银催化剂与碱金属来制备用于制备氧化乙烯的催化剂，其提供基于氧化物载体上的碱金属改性的银催化剂提高产率并且具有长寿命的催化剂 通过应用还含有与银离子形成络合物的有机氧化合物或氮化合物的醇类碱金属盐溶液。

公开(公告)号：US3950368A

公开(公告)日：1976-04-13

申请号：US415416

申请日：1973-11-13

申请人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

发明人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

IPC分类号： C10G11/20 ,  B01J23/00 ,  B01J23/755 ,  C07B61/00 ,  C07C1/00 ,  C07C1/02 ,  C07C4/00 ,  C07C4/06 ,  C07C9/04 ,  C07C67/00 ,  C07C27/06

CPC分类号： C07C1/02 ,  B01J23/755 ,  C07C4/00 ,  C10G11/02 ,  C10G11/10 ,  C07C2527/236

摘要： A two-stage process for the manufacture of methane from hydrocarbons is described. In the first stage, the hydrocarbons are converted into methane-rich gases, using the nickel catalyst described below. The cracked gases thus obtained are cooled and converted into methane-rich gases in a further catalytic process stage, using a methanization catalyst or the nickel catalyst mentioned below. To produce the nickel catalyst, the compound Ni.sub.6 Al.sub.2 (OH).sub.16.CO.sub.3.4H.sub.2 O is prepared in aqueous solution. The catalyst is obtained from this compound by drying, calcination and subsequent reduction in a stream of hydrogen whilst maintaining very specific temperature gradients between the drying stage and the calcination stage.