Fiber electrode for lithium secondary battery, fabrication method therefor, and lithium secondary battery including fiber electrode

    公开(公告)号:US09065139B2

    公开(公告)日:2015-06-23

    申请号:US13147769

    申请日:2010-02-02

    摘要: Provided is a method for mass manufacturing, at low cost, of a fiber positive electrode for a lithium secondary battery, which has excellent charge/discharge cycle characteristics, and which is capable of charging/discharging with high current density, and a main active material of which is a lithium-doped transition metal oxide. The method includes the steps of: (a) forming a tubular coating of either a transition metal oxide or a transition metal hydroxide on a carbon fiber current collector; and (b) performing, in a lithium ion containing solution in a sealed system under presence of an oxidant or a reductant, heat treatment at 100 to 250° C. on the carbon fiber current collector, on which the tubular coating of either the transition metal oxide or the transition metal hydroxide is formed, to obtain a coating of a lithium-doped transition metal oxide on the carbon fiber current collector. Further provided are: a fiber negative electrode for a lithium secondary battery, which has high current density, high energy density, and excellent charge/discharge cycle characteristics, and which can be fabricated in a relatively easy manner; and a method for fabricating the fiber negative electrode. The fiber negative electrode for a lithium secondary battery includes: (c) a carbon fiber current collector; (d) an outer layer which is a tubular composite layer of a Sn oxide and MXOy formed on the carbon fiber current collector; and (e) an intermediate layer formed of a Sn alloy, which has a lithium occlusion capacity and which is present at an interface between the carbon fiber current collector and the outer layer. The method for fabricating the fiber negative electrode for a lithium secondary battery includes: forming a coating of one of Sn and a Sn alloy, and a coating of at least one kind of metal selected from the group consisting of Fe, Mo, Co, Ni, Cr, Cu, In, Sb, and Bi, on a carbon fiber current collector by an electroplating method; and then performing heat treatment on the carbon fiber current collector under a trace oxygen atmosphere at 350 to 650° C. Moreover, the lithium secondary battery includes: the fiber positive electrode and the fiber negative electrode fabricated in the above methods; and an electrolyte.

    Sulfur-modified polyacrylonitrile, manufacturing method therefor, and application thereof
    43.
    发明授权
    Sulfur-modified polyacrylonitrile, manufacturing method therefor, and application thereof 有权
    硫改性聚丙烯腈及其制造方法及其应用

    公开(公告)号:US08940436B2

    公开(公告)日:2015-01-27

    申请号:US13123933

    申请日:2009-10-15

    摘要: Provided is a sulfur-modified polyacrylonitrile manufacturing method that is characterized in that a starting base powder that comprises sulfur powder and polyacrylonitrile powder is mixed and the mixture is heated in a non-oxidizing environment while outflow of sulfur vapor is prevented. Also provided are a cathode for lithium batteries that uses, as the active substance, the sulfur-modified polyacrylonitrile manufactured with the method, and a lithium secondary battery that includes the cathode as a component element. This enables the practical use of an inexpensive sulfur-based material as the cathode material for lithium secondary batteries, and in particular, a sulfur-based cathode material that enables higher output and has excellent cycle life characteristics, as well as other characteristics, and secondary lithium batteries using the same can be obtained.

    摘要翻译: 提供一种硫改性聚丙烯腈制造方法,其特征在于,将包含硫粉末和聚丙烯腈粉末的起始基础粉末混合,并且在非氧化环境中加热混合物,同时防止硫蒸气流出。 还提供了使用以该方法制造的硫改性聚丙烯腈作为活性物质的锂电池阴极和包含阴极作为组分元素的锂二次电池。 这使得可以实际使用廉价的硫基材料作为锂二次电池的阴极材料,特别是能够实现更高产量并且具有优异的循环寿命特性以及其它特性的硫基阴极材料,以及二次 可以获得使用其的锂电池。

    Device, control method thereof, computer program, and storage medium for differentially processing search requests
    44.
    发明授权
    Device, control method thereof, computer program, and storage medium for differentially processing search requests 有权
    装置,其控制方法,计算机程序和用于差分处理搜索请求的存储介质

    公开(公告)号:US08422051B2

    公开(公告)日:2013-04-16

    申请号:US11448069

    申请日:2006-06-07

    申请人: Tetsuo Sakai

    发明人: Tetsuo Sakai

    IPC分类号: G06F3/12

    摘要: Identification information of a user who performs search is shared between an information processing apparatus and a device. When search from the user having the identification information is accepted, the device responds. At this time, when the condition for sending back a response can be set from both the information processing apparatus and device and is satisfied, the device transmits device information to the information processing apparatus.

    摘要翻译: 执行搜索的用户的识别信息在信息处理设备和设备之间共享。 当接收到具有识别信息的用户的搜索时,设备进行响应。 此时,当可以从信息处理设备和设备两者设置用于发送回应的条件时,设备将设备信息发送到信息处理设备。

    Continuous repetitive rolling method for metal strip
    47.
    发明授权
    Continuous repetitive rolling method for metal strip 有权
    金属带连续重复轧制方法

    公开(公告)号:US08210011B2

    公开(公告)日:2012-07-03

    申请号:US12874498

    申请日:2010-09-02

    IPC分类号: B21B13/00 B21B13/16

    摘要: A continuous repetitive method of rolling a series combination of asymmetric rolling and skin pass rolling operations is provided. Differential-speed rolling is performed as the asymmetric rolling, and a winder temporarily winds a metal strip with a collapsed plate shape by traverse winding (loose winding which allows the metal strip to be wound in a zigzag manner). Then, the skin pass rolling is performed, and orderly winding is performed in a coil form. In the flow of rolling, tandem rolling may be performed by arranging two or more rolling mills side by side so that the asymmetric rolling and the skin pass rolling operations are continuously performed without the traverse winding therebetween.

    摘要翻译: 提供了一种滚动不对称滚动和皮肤滚动操作的串联组合的连续重复方法。 作为不对称轧制进行差速轧制,卷绕机通过横动卷绕(允许金属带以锯齿形的方式卷绕的松散卷绕)暂时卷绕具有压扁板形状的金属带。 然后,进行表皮通过轧制,并以线圈形式进行有序卷绕。 在轧制流程中,串联轧制可以通过并排布置两台或多台轧机来进行,从而不间断轧制和表面轧制操作在其间不进行横向卷绕而连续地进行。

    Nickel Positive Electrode for Fiber Battery
    49.
    发明申请
    Nickel Positive Electrode for Fiber Battery 有权
    镍电极用于光纤电池

    公开(公告)号:US20110287320A1

    公开(公告)日:2011-11-24

    申请号:US13130000

    申请日:2009-11-18

    IPC分类号: H01M4/32 H01M4/29

    摘要: Disclosed is a nickel positive electrode for a fiber battery having a long life duration, and also being enabling a high output and high capacity to be attained. For this purpose, the nickel positive electrode for a fiber battery is obtained by coating a carbon fiber with nickel, then causing a cathodic polarization in a nickel nitrate bath using the nickel-coated carbon fiber as a cathode, and then immersing the precipitate, which was deposited on the surface of the carbon fiber by the cathodic polarization, in an aqueous caustic alkali solution.

    摘要翻译: 公开了一种寿命长的纤维电池用镍正极,能够实现高输出,高容量化。 为此,通过用镍涂覆碳纤维,然后使用镍包覆的碳纤维作为阴极在硝酸镍浴中引起阴极极化,然后将沉淀物浸渍,得到用于纤维电池的镍正极, 在苛性碱水溶液中通过阴极极化沉积在碳纤维的表面上。

    Hydrogen absorbing alloy, hydrogen absorbing alloy electrode, secondary battery and production method of hydrogen absorbing alloy
    50.
    发明授权
    Hydrogen absorbing alloy, hydrogen absorbing alloy electrode, secondary battery and production method of hydrogen absorbing alloy 有权
    吸氢合金,吸氢合金电极,二次电池及吸氢合金的制备方法

    公开(公告)号:US07951326B2

    公开(公告)日:2011-05-31

    申请号:US12063394

    申请日:2006-08-11

    IPC分类号: C22C19/03

    摘要: The present invention provides a hydrogen absorbing alloy containing a phase of a Pr5Co19 type crystal structure having a composition defined by a general formula A(4−w)B(1+w)C19 (A denotes one or more element(s) selected from rare earth elements including Y (yttrium); B denotes an Mg element; C denotes one or more element(s) selected from a group consisting of Ni, Co, Mn, and Al; and w denotes a numeral in a range from −0.1 to 0.8) and having a composition as a whole defined by a general formula R1xR2yR3z (15.8≦x≦17.8, 3.4≦y≦5.0, 78.8≦z≦79.6, and x+y+z=100; R1 denotes one or more element(s) selected from rare earth elements including Y (yttrium); R2 denotes an Mg element, R3 denotes one or more element(s) selected from a group consisting of Ni, Co, Mn, and Al; the numeral of Mn+Al in the z is 0.5 or higher; and the numeral of Al in the z is 4.1 or lower).

    摘要翻译: 本发明提供一种含有由通式A(4-w)B(1 + w)C 19定义的组成的Pr5Co19型晶体结构相的吸氢合金(A表示选自以下的一种或多种元素: 包括Y(钇)的稀土元素; B表示Mg元素; C表示选自Ni,Co,Mn和Al中的一种或多种元素; w表示在-0.1的范围内的数字 至0.8),并且具有由通式R1xR2yR3z(15.8≦̸ x≦̸ 17.8,3.4和nlE; y≦̸ 5.0,78.8和n1; z和n1E; 79.6和x + y + z = 100定义的整体组成); R1表示一个 或更多选自包括Y(钇)的稀土元素的元素; R2表示Mg元素,R3表示选自Ni,Co,Mn和Al中的一种或多种元素; z中的Mn + Al为0.5以上,z中的Al的数值为4.1以下)。