摘要:
In accordance with an embodiment of the invention, an article is provided. The article comprises a substrate comprised of silicon containing material, an environmental barrier coating (EBC) overlying the substrate and a thermal barrier coating (TBC) on the environmental barrier coating. The thermal barrier coating comprising a compound having a rhombohedral phase.
摘要:
According to an embodiment of the invention, a repaired component is disclosed. The repaired component comprises an engine run component having a base metal substrate, a portion of the base metal substrate between about 1-3 mils in thickness and an overlying bond coat having been removed to create a remaining base metal substrate of reduced thickness. The repaired component further comprises a lower growth environmental bond coating comprising an alloy having an aluminum content of about 10-60 atomic percent applied to the remaining base metal substrate so that upon subsequent repair of the component, less than about 1-3 mils in thickness of the remaining base metal substrate is removed because of less environmental coating growth into the substrate than the prior bond coat. Advantageously, the repaired component has extended component life and increased repairability.
摘要:
A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.
摘要翻译:用于将涂层沉积在基材上的涂层和方法。 涂层是主要是β(NiAl)和γ-prime(Ni 3 Al 3 Al)金属间相的镍铝化物覆盖涂层,并且适合用作环境涂层和作为粘合涂层 隔热涂层(TBC)。 可以通过以适当的量沉积镍和铝来形成所述涂层,以产生所需的β+γ初相相含量。 或者,可以沉积镍和铝,使得涂层的铝含量超过适当的量以产生所需的β+γ初相相含量,之后热处理涂层以将过量的铝从涂层扩散到基底中 产生期望的β+γ'相相含量。
摘要:
A process for forming a beta-phase nickel aluminide (NiAl) overlay coating that is suitable for use as a bond coat for a thermal barrier coating (TBC). The overlay coating is deposited by a method that produces a generally columnar grain structure in which grains extend through the coating such that at least some grain boundaries are open at the coating surface. The coating is then peened with a particulate media, followed by heating the overlay coating to a temperature sufficient to cause the overlay coating to recrystallize and form new grain boundaries that are not open to the outer surface of the coating and significantly less susceptible to accelerated oxidation than the original grain boundaries. The particulate media is formed of a composition containing nickel and aluminum, such that an oxide scale that forms on the surface of the coating after the peening operation is substantially free of deleterious oxide compounds, notably iron-containing spinels.
摘要:
A coating applied as a two layer system. The outer layer is an oxide of a group IV metal selected from the group consisting of zirconium oxide, hafnium oxide and combinations thereof, which are doped with an effective amount of a lanthanum series oxide. These metal oxides doped with a lanthanum series addition comprises a high weight percentage of the outer coating. As used herein, lanthanum series means an element selected from the group consisting of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and combinations thereof, and lanthanum series oxides are oxides of these elements. When the zirconium oxide is doped with an effective amount of a lanthanum series oxide, a dense reaction layer is formed at the interface of the outer layer of TBC and the CMAS. This dense reaction layer prevents CMAS infiltration below it. The second layer, or inner layer underlying the outer layer, comprises a layer of partially stabilized zirconium oxide.
摘要:
A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy, a non-metallic oxide or nitride diffusion barrier layer overlying the substrate, and a protective coating overlying the barrier layer, the protective coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The diffusion barrier layer may be a deposited or thermally grown oxide material, especially aluminum oxide. The protective coating may be heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming a protective coating system on the turbine engine component by forming the non-metallic oxide or nitride diffusion barrier layer on the substrate and then depositing the platinum group metal on top of the barrier layer.
摘要:
In accordance with an embodiment of the invention, a thermal barrier coating for inclusion in a thermal barrier coating system is provided. The thermal barrier coating comprises a compound having a rhombohedral phase. In accordance with another embodiment of the invention, a thermal barrier coating is provided that comprises a compound having the formula of: A4B3O12, wherein A is at least one rare earth element; and B is selected from the group consisting of Zr, Hf and mixtures thereof.
摘要翻译:根据本发明的实施例,提供了用于包含在热障涂层系统中的热障涂层。 热障涂层包括具有菱面体相的化合物。 根据本发明的另一个实施方案,提供了一种热障涂层,其包含具有下列结构式的化合物:A 4 S 3 N 12 O / >其中A是至少一种稀土元素; B选自Zr,Hf及其混合物。
摘要:
A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy, a non-metallic oxide or nitride diffusion barrier layer overlying the substrate, and a protective coating overlying the barrier layer, the protective coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The diffusion barrier layer may be a deposited or thermally grown oxide material, especially aluminum oxide. The protective coating may be heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming a protective coating system on the turbine engine component by forming the non-metallic oxide or nitride diffusion barrier layer on the substrate and then depositing the platinum group metal on top of the barrier layer.
摘要:
A TBC system suitable for protecting the surface of a substrate subjected to a hostile thermal environment. The TBC system comprises a bond coat on the substrate surface, an alumina scale on the bond coat, and a multilayer TBC comprising a thermal-sprayed first ceramic layer on the alumina scale and a thermal-sprayed second ceramic layer overlying the first ceramic layer. The first ceramic layer consists essentially of partially stabilized zirconia so as to comprise the tetragonal and cubic phases of zirconia. The second ceramic layer consists essentially of fully stabilized zirconia so as to consist essentially of the cubic phase of zirconia. The second ceramic layer is also characterized by having vertical microcracks that extend through the thickness thereof. The second ceramic layer is thicker and more erosion resistant than the first ceramic layer.
摘要:
A protected article is prepared by depositing a bond coat onto an exposed surface of the article; and producing a thermal barrier coating on an exposed surface of the bond coat. The thermal barrier coating is produced by depositing a primary ceramic coating onto an exposed surface of the bond coat, depositing a cerium-oxide-precursor compound onto an exposed surface of the primary ceramic coating, and heating the cerium-oxide-precursor compound in an oxygen-containing atmosphere to form cerium oxide adjacent to the exposed surface of the primary ceramic coating.