摘要:
The present invention relates to porous metal organic frameworks comprising at least one at least bidentate organic compound L coordinated to at least one metal ion M, wherein L has at least one functional group G which bonds noncoordinatively to M and is selected from the group consisting of —SO3H and —PO3H2 and their analogues. The invention further provides processes for their preparation and also their use.
摘要翻译:本发明涉及包含至少一种与至少一种金属离子M配位的至少二齿有机化合物L的多孔金属有机骨架,其中L具有至少一个官能团G,其与M非键合键合并选自 -SO 3 H和-PO 3 H 2及其类似物。 本发明进一步提供了它们的制备方法及其应用。
摘要:
The present invention relates to mixtures comprising, in each case based on the total weight of the mixture, a) from 2 to 60% by weight of a latent heat storage component A and b) from 40 to 98% by weight of a framework component B, wherein the component A comprises at least one microencapsulated latent heat storage material and the component B comprises at least one porous metal organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion. The present invention further relates to the use of such mixtures, in particular in processes for separating substances from a mixture of substances.
摘要:
The present invention relates to a porous metal-organic framework material comprising a bidentate organic compound bound by coordination to a metal ion, the metal ion being AlIII and the bidentate organic compound being 2,6-naphthalenedicarboxylate, wherein the X-ray diffractogram (XRD) of the framework material has a first reflection in the range from 6.5°
摘要:
The present invention relates to processes for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, hydrogen, if appropriate carbon monoxide, carbon dioxide, steam and oxygen; C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) the product gas stream c is contacted with a selective adsorbent which adsorbs propene selectively under the selected adsorption conditions to obtain a propene-laden adsorbent and a propene-depleted gas stream d2 comprising propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide; E) a propene-comprising gas stream e1 is released from the propane-laden adsorbent by pressure reduction and/or heating of the adsorbent.
摘要:
The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 2 to 60 bar into a first reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted γ-butyrolactone; b) removing succinic anhydride from the product obtained in step a), preferably to a residual level of from
摘要:
The invention relates to a fuel reservoir for gaseous fuel in a vehicle, in particular a sorption reservoir. The fuel reservoir is delimited by at least one wall and includes a sorption material that is contained in its interior. The fuel reservoir has a tank inlet valve containing a shut-off valve and a throttle restriction valve. The restriction of the gaseous fuel takes place inside the fuel reservoir.
摘要:
The invention relates to a carrier for a thin layer and a method for the analysis of molecular interactions on and/or in such a thin layer. A thin layer disposed on a carrier is illuminated with electromagnetic radiation from at least one radiation source and a reflected radiation part on boundary surfaces of the thin layer is detected by means of an optoelectronic converter that converts the detected radiation into a frequency- and intensity-dependant photocurrent. A reading voltage is applied to the optoelectronic converter. By changing the reading voltage, the spectral sensitivity of the optoelectronic converter is varied such that a substantially constant photocurrent is obtained. Alternatively or in addition to varying the spectral sensitivity by changing the reading voltage, the reflected radiation part is detected with an optoelectronic converter that is designed as a sensor layer in the carrier. The carrier is particularly characterized in that it comprises a substrate on which at least one sensor layer with optoelectronic properties is disposed.
摘要:
A method of electrochemically preparing a crystalline, porous, metal-organic framework material comprising at least one at least bidentate organic compound coordinately bound to at least one metal ion, in a reaction medium comprising the at least one bidentate organic compound, wherein at least one metal ion is provided in the reaction medium by the oxidation of one anode comprising the corresponding metal.
摘要:
The present invention relates to the use of a porous metal organic framework comprising at least one at least bidentate organic compound coordinate to at least one metal ion as desiccant for reducing the water content of an organic liquid or for removing water from an organic liquid.
摘要:
The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.