METHOD FOR PRODUCING PROPENE FROM PROPANE
    44.
    发明申请
    METHOD FOR PRODUCING PROPENE FROM PROPANE 审中-公开
    从丙烷生产丙烯的方法

    公开(公告)号:US20090312591A1

    公开(公告)日:2009-12-17

    申请号:US12294748

    申请日:2007-03-13

    IPC分类号: C07C5/327

    摘要: The present invention relates to processes for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, hydrogen, if appropriate carbon monoxide, carbon dioxide, steam and oxygen; C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) the product gas stream c is contacted with a selective adsorbent which adsorbs propene selectively under the selected adsorption conditions to obtain a propene-laden adsorbent and a propene-depleted gas stream d2 comprising propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide; E) a propene-comprising gas stream e1 is released from the propane-laden adsorbent by pressure reduction and/or heating of the adsorbent.

    摘要翻译: 本发明涉及从丙烷制备丙烯的方法,包括以下步骤:A)提供包含丙烷的原料气流a; B)包含丙烷的进料气流a(如果合适的话,蒸汽和适当的话)和含氧气流被送入脱氢区,丙烷经脱氢至丙烯以获得包含丙烷,丙烯,甲烷, 乙烷,乙烯,氢气,如果适用,一氧化碳,二氧化碳,蒸气和氧气; C)产物气流b被冷却,如果合适的话压缩并通过冷凝除去蒸汽,得到蒸汽消耗产物气流c; D)产物气流c与在选择的吸附条件下选择性吸附丙烯的选择性吸附剂接触以获得含有丙烯的吸附剂和包含丙烷,甲烷,乙烷,乙烯和氢气的一种贫含丙烯的气流d2,一氧化碳 和二氧化碳; E)通过吸附剂的减压和/或加热将含丙烯气流e1从载有丙烷的吸附剂中释放。

    Two-stage method for producing butane diol with intermediated separation of succinic anhydride
    45.
    发明申请
    Two-stage method for producing butane diol with intermediated separation of succinic anhydride 失效
    制备丁二酸酐中间分离丁二醇的两阶段方法

    公开(公告)号:US20060167323A1

    公开(公告)日:2006-07-27

    申请号:US10516922

    申请日:2003-06-11

    IPC分类号: C07C31/18

    CPC分类号: C07C29/149 C07C31/207

    摘要: The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 2 to 60 bar into a first reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted γ-butyrolactone; b) removing succinic anhydride from the product obtained in step a), preferably to a residual level of from

    摘要翻译: 本发明涉及通过在具有下列物质的C 4 - 二羧酸和/或其衍生物的气相中通过两阶段催化氢化制备任选的烷基取代的1,4-丁二醇的方法 步骤:a)将200-300℃和2-60巴的C 4-14二羧酸或其衍生物的气流引入第一反应器,并将其催化氢化为 气相至主要含有烷基取代的γ-丁内酯的产物; b)从步骤a)中获得的产物中除去琥珀酸酐,优选残留量为约0.3至0.2重量%; c)将步骤b)中获得的产物流在150℃至240℃的温度和15至100巴的压力下引入第二反应器,并将其在气相中催化氢化为任选的烷基 - 取代的1,4-丁二醇; d)从中间体,副产物和任何未转化的反应物中除去所需的产物; e)任选地将未转化的中间体再循环到一个或两个氢化步骤中,所述氢化步骤各自使用催化剂,所述催化剂包含95重量%,优选5至95重量%,特别是10至80重量%的CuO ,和> = 5重量%,优选5至95重量%,特别是20至90重量%的氧化载体,并且所述第二反应器具有比所述第一反应器更高的压力。

    Analysis of molecular interactions on and/or in thin layers
    47.
    发明授权
    Analysis of molecular interactions on and/or in thin layers 有权
    分析薄层上和/或薄层的分子相互作用

    公开(公告)号:US08174708B2

    公开(公告)日:2012-05-08

    申请号:US12672535

    申请日:2008-08-09

    IPC分类号: G01B11/02

    摘要: The invention relates to a carrier for a thin layer and a method for the analysis of molecular interactions on and/or in such a thin layer. A thin layer disposed on a carrier is illuminated with electromagnetic radiation from at least one radiation source and a reflected radiation part on boundary surfaces of the thin layer is detected by means of an optoelectronic converter that converts the detected radiation into a frequency- and intensity-dependant photocurrent. A reading voltage is applied to the optoelectronic converter. By changing the reading voltage, the spectral sensitivity of the optoelectronic converter is varied such that a substantially constant photocurrent is obtained. Alternatively or in addition to varying the spectral sensitivity by changing the reading voltage, the reflected radiation part is detected with an optoelectronic converter that is designed as a sensor layer in the carrier. The carrier is particularly characterized in that it comprises a substrate on which at least one sensor layer with optoelectronic properties is disposed.

    摘要翻译: 本发明涉及一种用于薄层的载体和用于分析在这种薄层上和/或其中的分子相互作用的方法。 设置在载体上的薄层被来自至少一个辐射源的电磁辐射照射,并且通过光电转换器检测薄层边界表面上的反射辐射部分,该光电转换器将检测到的辐射转换成频率和强度 - 依赖光电流。 读取电压被施加到光电转换器。 通过改变读取电压,改变光电转换器的光谱灵敏度,使得获得基本恒定的光电流。 或者或通过改变读取电压来改变光谱灵敏度,反射的辐射部分被设计为载体中的传感器层的光电转换器来检测。 载体的特征在于其包括其上设置有至少一个具有光电特性的传感器层的基底。

    Process for preparing porous organic framework materials
    50.
    发明授权
    Process for preparing porous organic framework materials 有权
    制备多孔有机骨架材料的方法

    公开(公告)号:US07847115B2

    公开(公告)日:2010-12-07

    申请号:US12161024

    申请日:2007-02-08

    IPC分类号: C07F3/00 C07F15/00 C07F5/02

    CPC分类号: C07F3/003 C07F19/005

    摘要: The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.

    摘要翻译: 本发明涉及一种制备多孔有机骨架的方法,该方法通过在非水有机溶剂存在下和/或与水的释放下在包含合适的起始化合物的液相中反应混合物进行反应,其中后者 在反应期间从反应混合物的液相中排出。 这里,可以以可再现的方式获得比表面积相对较高的框架。