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    FUNCTIONALIZED TRIPTYCENE POLYMERS AND THEIR USES
    42.
    发明申请
    FUNCTIONALIZED TRIPTYCENE POLYMERS AND THEIR USES 审中-公开
    功能性三聚体聚合物及其用途

    公开(公告)号：US20170022323A1

    公开(公告)日：2017-01-26

    申请号：US15215410

    申请日：2016-07-20

    Applicant: Massachusetts Institute of Technology

    Inventor： Timothy M. Swager ,  John B. Goods ,  Chuanhui L. Moh

    IPC: C08G65/48 ,  C08L71/00 ,  H01M8/1025 ,  B01J39/18 ,  B01J41/12 ,  C08G65/40 ,  C08J5/22

    CPC classification number: C08G65/48 ,  B01J39/19 ,  B01J41/13 ,  B01J47/12 ,  C08G65/4006 ,  C08G65/4012 ,  C08J5/2256 ,  C08J2371/10 ,  C08L71/00 ,  C08L2205/025 ,  H01M8/04197 ,  H01M8/1025 ,  H01M2008/1095

    Abstract: Embodiments described herein relate to compositions including iptycene-based structures. Some embodiments provide compositions including polymers having a backbone comprising an iptycene-based compound. Some embodiments described herein provide compositions having enhanced properties such as enhanced porosity, increased glass transition temperatures, and/or improved solubility as compared to traditional poly(aryl ether)-based compounds or traditional iptycene-based compounds. In some cases, the compositions may include various aryl ether compounds such as an aryl ether ketone incorporated into the polymer backbone. Non-limiting examples of suitable aryl ether compounds include polyaylethersulfones, polyaryletherketones, polyetherimides, and polyphenylene ethers. The compositions described herein may be useful in a wide variety of applications, including structural materials, flexible composites, ion conductors, fuel cell membranes such as proton exchanging membranes, sensors, preconcentrators, absorbents, or the like.

    Abstract translation: 本文所述的实施方案涉及包含基于iptycene的结构的组合物。 一些实施方案提供包含聚合物的组合物，所述聚合物具有包含基于iptycene的化合物的主链。 本文所述的一些实施方案提供具有增强性能的组合物，例如与传统的基于聚（芳基醚）的化合物或传统的基于iptycene的化合物相比，增强的孔隙率，增加的玻璃化转变温度和/或改善的溶解度。 在一些情况下，组合物可以包括各种芳基醚化合物，例如并入聚合物主链中的芳基醚酮。 合适的芳基醚化合物的非限制性实例包括聚醚醚砜，聚芳醚酮，聚醚酰亚胺和聚苯醚。 本文描述的组合物可用于各种应用，包括结构材料，柔性复合材料，离子导体，燃料电池膜，例如质子交换膜，传感器，预浓缩器，吸收剂等。

    SENSOR OF SPECIES INCLUDING TOXINS AND CHEMICAL WARFARE AGENTS
    46.
    发明申请
    SENSOR OF SPECIES INCLUDING TOXINS AND CHEMICAL WARFARE AGENTS 有权
    包括毒素和化学品保护剂的物种传感器

    公开(公告)号：US20150247805A1

    公开(公告)日：2015-09-03

    申请号：US14332231

    申请日：2014-07-15

    Applicant: Massachusetts Institute of Technology

    Inventor： Timothy M. Swager ,  Samuel W. Thomas, III ,  Koushik Venkatesan

    IPC: G01N21/76 ,  G01N21/64 ,  G01N33/20

    CPC classification number: G01N21/76 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1092 ,  C09K2211/185 ,  G01N21/64 ,  G01N33/0057 ,  G01N33/20 ,  G01N2201/06113 ,  Y10T436/172307 ,  Y10T436/196666

    Abstract: The present invention generally relates to emissive materials, devices, and related methods. In some cases, the present invention provides sensors and methods for the determination of analytes, wherein the analytes may be determined by monitoring, for example, a change in an optical signal of an emissive material upon exposure to an analyte.The analyte and the emissive material may interact via a chemical reaction, such as an oxidative addition reaction, or other chemical, biochemical or biological interaction (e.g., recognition), to form a new emissive species. In some cases, the present invention may be useful in the detection of a wide variety of analytes, such as toxins, chemical warfare agents, and explosives. The present invention also provides emissive compounds, and related methods, including metal complexes that are capable of interacting with an analyte to produce a change in the emission of the compound. Some advantages of the present invention include the determination of analytes with high specificity and sensitivity and the ability to fabricate simplified and highly portable devices.

    Abstract translation: 本发明一般涉及发射材料，器件和相关方法。 在一些情况下，本发明提供用于测定分析物的传感器和方法，其中分析物可以通过例如在暴露于分析物时监测发光材料的光学信号的变化来确定。 分析物和发射材料可通过诸如氧化加成反应或其他化学，生物化学或生物相互作用（例如识别）的化学反应相互作用以形成新的发射物质。 在一些情况下，本发明可用于检测各种分析物，例如毒素，化学战剂和爆炸物。 本发明还提供发射化合物和相关方法，包括能够与分析物相互作用以产生化合物的发射变化的金属络合物。 本发明的一些优点包括具有高特异性和灵敏度的分析物的测定以及制造简化且高度便携的装置的能力。

    Compositions comprising a plurality of discrete nanostructures and related articles and methods
    50.
    发明授权
    Compositions comprising a plurality of discrete nanostructures and related articles and methods 有权

    公开(公告)号：US11091369B2

    公开(公告)日：2021-08-17

    申请号：US16401563

    申请日：2019-05-02

    Applicant: Massachusetts Institute of Technology

    Inventor： Ian W. Hunter ,  Timothy M. Swager ,  Intak Jeon ,  Gee Hoon Park ,  Pan Wang

    IPC: C01B32/194 ,  C10M103/02 ,  C10M105/64 ,  C10M111/02 ,  C01B32/198 ,  C10N50/08

    Abstract: Embodiments described herein generally relate to compositions including discrete nanostructures (e.g., nanostructures including a functionalized graphene layer and a core species bound to the functionalized graphene layer), and related articles and methods. A composition may have a coefficient of friction of less than or equal to 0.02. Discrete nanostructures may have a substantially non-planar configuration. A core species may reversibly covalently bind a first portion of a functionalized graphene layer to a second portion of the functionalized graphene layer. Articles, e.g., articles including a plurality of discrete nanostructures and a means for depositing the plurality of discrete nanostructures on a surface, are also provided. Methods (e.g., methods of forming a layer) are also provided, including depositing a composition onto a substrate surface and/or applying a mechanical force to the composition, e.g., such that the composition exhibits a coefficient of friction of less than or equal to 0.02.

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