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公开(公告)号：US6096937A
公开(公告)日：2000-08-01
申请号：US195179
申请日：1999-02-08
CPC分类号： B01J8/067 , C07C5/333 , B01J2208/00088 , B01J2208/00398 , B01J2208/00407 , B01J2208/00504 , Y10S585/911
摘要： The present invention discloses a method and apparatus for dehydrogenating ethylbenzene into styrene which method and apparatus eliminate the need for multiple reactors and preheaters by providing a single compact reactor which utilizes the principle of ascending-heat thermal reactor by having an internal heat source such as gas heaters or electric elements.
摘要翻译： 本发明公开了一种将乙苯脱氢成苯乙烯的方法和装置，该方法和设备通过提供一个单一的紧凑型反应器消除了对多反应器和预热器的需要，该反应器利用上热式热反应器的原理是通过内部热源例如气体 加热器或电气元件。
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公开(公告)号：US6057485A
公开(公告)日：2000-05-02
申请号：US193310
申请日：1998-11-17
CPC分类号： C07C15/073 , C07C2/66 , C07C2529/035 , C07C2529/08
摘要： Ethylbenzene is produced by alkylation over a split load of monoclinic silicalite alkylation catalysts having different silica/alumina ratios. A feedstock containing benzene and ethylene is applied to a multi-stage alkylation reaction zone having a plurality of series-connected catalyst beds. At least one catalyst bed contains a first monoclinic silicalite catalyst having a silica/alumina ratio of at least 275. At least one other catalyst bed contains a second monoclinic silicalite catalyst having a silica/alumina ratio of less than about 275. The alkylation reaction zone is operated at temperature and pressure conditions in which the benzene is in a gaseous phase to cause gas-phase alkylation of the aromatic substrate in the presence of the monoclinic silicalite catalysts to produce an alkylation product. The alkylation product is then withdrawn from the reaction zone for separation and recovery. The use of the split load of catalyst allows a higher purity ethylbenzene product to be produced at improved efficiencies than if only one of the catalysts were used by itself.
摘要翻译： 通过在具有不同二氧化硅/氧化铝比的单斜晶硅沸石烷基化催化剂的分裂负载下烷基化来制备乙苯。 将含有苯和乙烯的原料施加到具有多个串联催化剂床的多级烷基化反应区。 至少一个催化剂床含有二氧化硅/氧化铝比至少为275的第一单斜晶硅沸石催化剂。至少一个其它催化剂床含有二氧化硅/氧化铝比小于约275的第二单斜硅沸石催化剂。烷基化反应区 在其中苯处于气相的温度和压力条件下操作，以在单斜硅沸石催化剂的存在下引起芳族底物的气相烷基化以产生烷基化产物。 然后将烷基化产物从反应区取出以进行分离和回收。 与仅使用一种催化剂本身一起使用的催化剂的分离负载的使用允许以提高的效率生产更高纯度的乙苯产物。
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公开(公告)号：US4587371A
公开(公告)日：1986-05-06
申请号：US644885
申请日：1984-08-27
IPC分类号： C07C2/64 , B01J29/00 , B01J29/035 , B01J29/40 , B01J29/65 , B01J29/70 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/02 , C07C67/00 , C07C2/68
CPC分类号： B01J29/65 , B01J29/40 , B01J29/70 , C07C2/66 , C07C2529/035
摘要： A process for the alkylation of aromatic hydrocarbons in a reaction zone containing a crystalline silica polymorph silicalite catalyst. The feed stock to the reaction zone comprises an alkylating agent and an aromatic substrate contains sulfur in an amount, greater than 2 ppm, which heretofore has considered to be unacceptable to zeolite catalysts. A steam cofeed may also be applied to the reaction zone in an amount sufficient to reduce the deposition of coke on the catalyst due to the presence of sulfur. Sulfur may be present as a contaminant in the aromatic substrate or the alkylating agent.
摘要翻译： 在含有结晶二氧化硅多晶硅沸石催化剂的反应区中烷基化芳族烃的方法。 反应区的原料包含烷基化剂，芳族底物含有大于2ppm的硫，迄今为止已被认为是沸石催化剂不可接受的硫。 蒸汽共进料也可以以足以减少由于硫的存在而使焦炭沉积在催化剂上的量施加到反应区。 硫可能作为污染物存在于芳族底物或烷化剂中。
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公开(公告)号：US4520220A
公开(公告)日：1985-05-28
申请号：US350673
申请日：1982-02-22
CPC分类号： C07C2/66 , C07C2529/04
摘要： A process for alkylating aromatic substrates is disclosed which includes contacting the aromatic substrate with an alkylating agent in a reaction zone at temperatures of from about 350.degree. C. to about 500.degree. C. in the presence of a crystalline silica polymorph silicalite catalyst material.
摘要翻译： 公开了一种用于烷基化芳族底物的方法，其包括在结晶二氧化硅多晶硅沸石催化剂材料存在下，在约350℃至约500℃的温度下，在反应区中使芳族底物与烷基化剂接触。
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公开(公告)号：US4468343A
公开(公告)日：1984-08-28
申请号：US483976
申请日：1983-04-11
CPC分类号： C07C7/20
摘要： A compound and a process for utilizing the compound to prevent the polymerization of vinyl aromatic compounds, such as styrene, during heating. The composition includes effective amounts of 2,6-dinitro-p-cresol and either a phenylenediamine or 4-tert-butylcatechol respectively, to act as a polymerization co-inhibitor system in the presence of oxygen.
摘要翻译： 化合物和在加热期间利用该化合物防止乙烯基芳族化合物如苯乙烯聚合的方法。 该组合物分别包含有效量的2,6-二硝基对甲酚和分别为苯二胺或4-叔丁基邻苯二酚，以在氧存在下用作聚合共抑制剂体系。
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公开(公告)号：US4466905A
公开(公告)日：1984-08-21
申请号：US483978
申请日：1983-04-11
CPC分类号： C07C7/20
摘要： A compound and a process for utilizing the compound to prevent the polymerization of vinyl aromatic compounds, such as styrene, during heating. The composition includes effective amounts of 2,6-dinitro-p-cresol and either a phenylenediamine or 4-tert-butylcatechol respectively, to act as a polymerization co-inhibitor system in the presence of oxygen.
摘要翻译： 化合物和在加热期间利用该化合物防止乙烯基芳族化合物如苯乙烯聚合的方法。 该组合物分别包含有效量的2,6-二硝基对甲酚和分别为苯二胺或4-叔丁基邻苯二酚，以在氧存在下用作聚合共抑制剂体系。
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47.发明授权Removal of heparin from heparin-containing blood plasma samples using a triethylaminoethyl cellulose tablet 失效使用三乙基氨基乙基纤维素片从含肝素的血浆样品中除去肝素
公开(公告)号：US4226599A
公开(公告)日：1980-10-07
申请号：US050355
申请日：1979-06-20
CPC分类号： G01N33/86 , G01N2400/40 , Y10T436/25125
摘要： A tableted form of fibrous triethylaminoethyl cellulose suitable for the removal of heparin from heparin-containing blood plasma. The tablet is composed of granular microcrystalline cellulose and fibrous triethylaminoethyl cellulose in a ratio of from about 5.4:1 to about 10:1. The triethylaminoethyl cellulose tablet, which is formulated to provide from about 5 to about 26 mg. of triethylaminoethyl cellulose per milliliter of plasma sample, is added to a heparin-containing blood plasma sample, the sample is agitated or allowed to stand for a time sufficient to permit adsorption of substantially all heparin present. The sample is then centrifuged and the remaining heparin-free plasma can be subjected to coagulation testing in order to determine the true clotting time.
摘要翻译： 纤维状三乙基氨基乙基纤维素的片状形式，适用于从含有肝素的血浆中除去肝素。 片剂由粒状微晶纤维素和纤维状三乙基氨基乙基纤维素组成，比例约为5.4:1至约10:1。 三乙氨基乙基纤维素片剂，其配制成提供约5至约26mg。 的三乙胺基乙基纤维素/毫升血浆样品加入含肝素的血浆样品中，将样品搅拌或静置足以允许存在基本上所有肝素的吸附。 然后将样品离心，然后将剩余的无肝素血浆进行凝血试验，以确定真实的凝血时间。
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48.发明授权Method for providing a co-feed in the coupling of toluene with a carbon source 有权在甲苯与碳源的偶合中提供共进料的方法公开(公告)号：US08653314B2
公开(公告)日：2014-02-18
申请号：US13457503
申请日：2012-04-27
摘要： A process for making styrene is disclosed that includes reacting toluene with a C1 source and a co-feed in the presence of a catalyst in a reactor to form a first product stream comprising styrene, ethylbenzene, carbon monoxide, and hydrogen; separating the hydrogen and carbon monoxide from the first product stream to form a second stream; separating the hydrogen from the second stream to form a third stream comprising hydrogen and a fourth stream comprising carbon monoxide; wherein the fourth stream is recycled to the reactor and forms at least a portion of the co-feed.
摘要翻译： 公开了一种制备苯乙烯的方法，其包括在反应器中在催化剂存在下使甲苯与C1源和共进料反应以形成包含苯乙烯，乙苯，一氧化碳和氢的第一产物流; 将氢和一氧化碳与第一产物流分离以形成第二流; 从第二流分离氢气以形成包含氢的第三料流和包含一氧化碳的第四料流; 其中第四料流被再循环到反应器中并形成共进料的至少一部分。
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公开(公告)号：US08314282B2
公开(公告)日：2012-11-20
申请号：US13290211
申请日：2011-11-07
申请人： James R. Butler , Joseph E. Pelati
发明人： James R. Butler , Joseph E. Pelati
CPC分类号： C07C15/46 , C07C2/66 , C07C2/84 , C07C5/48 , Y10S585/921 , Y10S585/943 , C07C15/073
摘要： A process for making ethylbenzene and/or styrene by reacting toluene with methane is disclosed. In one embodiment the process can include reacting toluene with methane to form a product stream comprising ethylbenzene and further processing the ethylbenzene to form styrene in an existing styrene production facility.
摘要翻译： 公开了通过使甲苯与甲烷反应制备乙苯和/或苯乙烯的方法。 在一个实施方案中，该方法可以包括使甲苯与甲烷反应以形成包含乙苯的产物流，并进一步处理乙苯以在现有的苯乙烯生产设备中形成苯乙烯。
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公开(公告)号：US08269053B2
公开(公告)日：2012-09-18
申请号：US13286271
申请日：2011-11-01
申请人： James R. Butler
发明人： James R. Butler
CPC分类号： C07C15/46 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , C07C2/66 , C07C2/84 , C07C5/48 , Y10S585/921 , Y10S585/943 , Y10T29/49716 , C07C15/073
摘要： A process for making ethylbenzene and/or styrene by reacting toluene with methane in one or more microreactors is disclosed. In one embodiment a method of revamping an existing styrene production facility by adding one or more microreactors capable of reacting toluene with methane to produce a product stream comprising ethylbenzene and/or styrene is disclosed.
摘要翻译： 公开了通过在一个或多个微反应器中使甲苯与甲烷反应制备乙苯和/或苯乙烯的方法。 在一个实施方案中，公开了通过加入能够使甲苯与甲烷反应以产生包含乙苯和/或苯乙烯的产物流的一种或多种微反应器来改进现有苯乙烯生产设备的方法。
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