Processes to produce organo-aluminoxane compositions
    46.
    发明授权
    Processes to produce organo-aluminoxane compositions 有权
    生产有机铝氧烷组合物的方法

    公开(公告)号:US06353071B1

    公开(公告)日:2002-03-05

    申请号:US09489728

    申请日:2000-01-21

    IPC分类号: C08F21000

    摘要: Processes are provided that produce organo-aluminoxane compositions. Said processes comprise: desiccating a first mixture, where said first mixture comprises organo-aluminoxane molecules intermixed with a solvent, to produce a first composition, where said first composition comprises organo-aluminoxane molecules; mixing said first composition with a solvent to produce a second mixture, where said second mixture comprises organo-aluminoxane molecules and said solvent; contacting said second mixture with a insolublization agent to produce said organo-aluminoxane compositions. A polymerization process using a catalyst that comprises an organo-aluminoxane composition is also provided.

    摘要翻译: 提供了产生有机铝氧烷组合物的方法。 所述方法包括:干燥第一混合物,其中所述第一混合物包含与溶剂混合的有机铝氧烷分子,以产生第一组合物,其中所述第一组合物包含有机铝氧烷分子; 将所述第一组合物与溶剂混合以产生第二混合物,其中所述第二混合物包含有机铝氧烷分子和所述溶剂; 使所述第二混合物与不溶解剂接触以制备所述有机铝氧烷组合物。 还提供了使用包含有机铝氧烷组合物的催化剂的聚合方法。

    Method and catalyst system for producing polyolefins with broadened molecular weight distributions
    48.
    发明授权
    Method and catalyst system for producing polyolefins with broadened molecular weight distributions 失效
    用于生产具有更宽分子量分布的聚烯烃的方法和催化剂体系

    公开(公告)号:US06384161B1

    公开(公告)日:2002-05-07

    申请号:US09474864

    申请日:1999-12-30

    IPC分类号: C08F402

    摘要: The present invention provides a process for preparing a supported metallocene catalyst system that can be used to catalyze formation of polyolefins having a wide molecular weight range. In accordance with the process of the present invention, a first portion of an inorganic oxide is dried under a first set of conditions, wherein upon treatment with an organoaluminoxide and a metallocene, a first catalyst system is formed usable to produce a polyolefin product having a first molecular weight average distribution. A second portion of an inorganic oxide under a second set of conditions, wherein upon treatment with an organoaluminoxane and a metallocene, a second catalyst system is formed usable to produce polyolefin product having a second molecular weight distribution. An amount of the first portion is mixed with an amount of the second portion to produce a final inorganic oxide support. The final inorganic oxide support is combined with an organoaluminoxane and a metallocene to produce a supported metallocene catalyst system usable to catalyze formation of polyolefins with a broadened molecular weight average distribution. In another aspect, the present invention provides a process for polymerizing polyolefins using the inventive supported metallocene catalyst system. The process comprises preparing the final catalyst as mentioned above and then contacting an olefin with the final metallocene catalyst system under conditions supporting polymerization.

    摘要翻译: 本发明提供了一种制备负载型茂金属催化剂体系的方法,该体系可用于催化具有宽分子量范围的聚烯烃的形成。 根据本发明的方法,在第一组条件下将无机氧化物的第一部分干燥,其中在用有机铝氧化物和茂金属处理时,形成可用于生产聚烯烃产品的第一催化剂体系,所述聚烯烃产物具有 第一分子量平均分布。 在第二组条件下的无机氧化物的第二部分,其中在用有机铝氧烷和茂金属处理时,形成可用于制备具有第二分子量分布的聚烯烃产物的第二催化剂体系。 将第一部分的量与第二部分的量混合以产生最终的无机氧化物载体。 最终的无机氧化物载体与有机铝氧烷和茂金属组合以产生可用于催化分子量平均分布扩大的聚烯烃形成的负载金属茂催化剂体系。另一方面,本发明提供使用本发明聚合聚烯烃的方法 负载金属茂催化剂体系。 该方法包括如上所述制备最终催化剂,然后在支持聚合的条件下使烯烃与最终茂金属催化剂体系接触。