公开(公告)号：US06258990B1

公开(公告)日：2001-07-10

申请号：US09517497

申请日：2000-03-02

Applicant: Shun C. Fung ,  Tan-Jen Chen ,  Marcel J. Janssen ,  William A. Wachter ,  B. Erik Henry ,  John E. Asplin

Inventor： Shun C. Fung ,  Tan-Jen Chen ,  Marcel J. Janssen ,  William A. Wachter ,  B. Erik Henry ,  John E. Asplin

IPC: C07C406

CPC classification number: C10G57/02 ,  C10G2400/20

Abstract: A process for producing polymers from C2-C4 olefins selectively produced from a catalytically-cracked or thermally-cracked naphtha stream is disclosed herein. A mixture of the naphtha stream and a stream of steam is feed into a reaction zone where it is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions that include temperatures from about 500° C. to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia.

Abstract translation: 本文公开了从催化裂化或热裂解石脑油流选择性地生产的C2-C4烯烃生产聚合物的方法。 将石脑油流和蒸汽流的混合物进料到反应区，在反应区中与含有约10至50wt。 在包括约500℃至650℃的温度和约10至40psia的烃分压的反应条件下具有平均孔径小于约0.7纳米的结晶沸石的％。

公开(公告)号：US6118035A

公开(公告)日：2000-09-12

申请号：US072632

申请日：1998-05-05

Applicant: Shun C. Fung ,  Tan-Jen Chen ,  Marcel J. G. Janssen ,  William A. Wachter ,  Brian Eric Henry ,  John Ernest Asplin

Inventor： Shun C. Fung ,  Tan-Jen Chen ,  Marcel J. G. Janssen ,  William A. Wachter ,  Brian Eric Henry ,  John Ernest Asplin

IPC: C07C4/02 ,  C07B61/00 ,  C07C11/06 ,  C10G9/26 ,  C10G11/00 ,  C10G11/05 ,  C10G57/02 ,  C07C4/06

CPC classification number: C10G57/02 ,  C10G2400/20

Abstract: A process for selectively producing C.sub.2 -C.sub.4 olefins from a catalytically cracked or thermally cracked naphtha stream is disclosed. A mixture of the naphtha stream and a stream of steam is feed into a reaction zone where it is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500 to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia.

Abstract translation: 公开了一种从催化裂化或热裂解石脑油流中选择性生产C2-C4烯烃的方法。 将石脑油流和蒸汽流的混合物进料到反应区，在反应区中与含有约10至50wt。 ％的平均孔径小于约0.7纳米的结晶沸石在包括约500至650℃的温度和约10至40psia的烃分压的反应条件下进行。

公开(公告)号：US6093867A

公开(公告)日：2000-07-25

申请号：US73083

申请日：1998-05-05

Applicant: Paul K. Ladwig ,  John Ernest Asplin ,  Gordon F. Stuntz ,  Tan-Jen Chen

Inventor： Paul K. Ladwig ,  John Ernest Asplin ,  Gordon F. Stuntz ,  Tan-Jen Chen

IPC: C07C4/02 ,  C07C4/06 ,  C07C11/02 ,  C10G11/02 ,  C10G11/04 ,  C10G11/05 ,  C10G57/02

CPC classification number: C10G57/02 ,  C10G2400/20

Abstract: A process for selectively producing C.sub.3 olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500.degree. to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. Overhead products from the reaction zone are passed to a fractionation zone where a stream of C.sub.3 's is recovered and a stream rich in C.sub.4 and/or C.sub.5 olefins is recycled to the stripping zone.

Abstract translation: 从催化裂化或热裂解的石脑油流中选择性生产C3烯烃的方法。 将石脑油流引入由反应区，汽提区，催化剂再生区和分馏区构成的工艺单元中。 石脑油原料流在反应区中与含有约10至50wt。 ％的平均孔径小于约0.7纳米的结晶沸石在包括约500℃至650℃的温度和约10至40psia的烃分压的反应条件下进行。 蒸气产物被顶部收集，催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用蒸汽汽提，并将催化剂颗粒送入催化剂再生区，其中焦炭从催化剂燃烧，然后再循环到反应区。 来自反应区的高架物质被送入分馏区，其中回收C3的物流，富含C4和/或C5烯烃的物流被循环到汽提区。

公开(公告)号：US5635055A

公开(公告)日：1997-06-03

申请号：US277451

申请日：1994-07-19

Applicant: James R. Sweet ,  Tan-Jen Chen ,  Charles P. Darnell

Inventor： James R. Sweet ,  Tan-Jen Chen ,  Charles P. Darnell

IPC: C10G31/11 ,  C10G55/02 ,  C10G25/00

CPC classification number: C10G31/11 ,  C10G55/02

Abstract: The yield and quality of products secured from cracking units is increased by the process of subjecting the product stream secured from such cracking unit to a selective aromatics removal process and recycling the recovered aromatics lean (saturates rich) stream to the cracking unit whereby such saturates rich stream is subjected to increased conversion to higher value desired products.

公开(公告)号：US08487140B2

公开(公告)日：2013-07-16

申请号：US12996219

申请日：2009-07-14

Applicant: John S. Buchanan ,  Jon E. Stanat ,  Tan-Jen Chen ,  Jihad M. Dakka ,  James R. Lattner

Inventor： John S. Buchanan ,  Jon E. Stanat ,  Tan-Jen Chen ,  Jihad M. Dakka ,  James R. Lattner

IPC: C07C37/07 ,  C07C37/08

CPC classification number: C07C37/06 ,  C07C2/74 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C2601/14 ,  C07C13/28 ,  C07C39/04 ,  C07C49/403 ,  C07C409/14

Abstract: In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.

Abstract translation: 在生产苯酚的方法中，将环己基苯氧化生产环己基苯氢过氧化物，然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。 然后将至少一部分流出物流送入至少一个脱氢反应区，其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。

公开(公告)号：US08106243B2

公开(公告)日：2012-01-31

申请号：US12933709

申请日：2009-02-23

Applicant: Tan-Jen Chen ,  Jane C. Cheng ,  Francisco M. Benitez ,  Terry E. Helton ,  Jon E. Stanat

Inventor： Tan-Jen Chen ,  Jane C. Cheng ,  Francisco M. Benitez ,  Terry E. Helton ,  Jon E. Stanat

IPC: C07C45/53 ,  C07C37/08 ,  C07C2/68

CPC classification number: C07C37/06 ,  C07C2/74 ,  C07C6/126 ,  C07C37/08 ,  C07C45/53 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C49/403 ,  C07C39/04

Abstract: In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide and the inorganic oxide has an average particle size less than 40 μm (microns).

Abstract translation: 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50重量％的所述氢化金属负载在无机氧化物上，无机氧化物具有平均粒度 小于40μm（微米）。

公开(公告)号：US20100179351A1

公开(公告)日：2010-07-15

申请号：US12663303

申请日：2008-08-12

Applicant: Tan-Jen Chen ,  Jane C. Cheng ,  Terry E. Helton ,  John Scott Buchanan

Inventor： Tan-Jen Chen ,  Jane C. Cheng ,  Terry E. Helton ,  John Scott Buchanan

IPC: C07C2/02 ,  C07C45/27 ,  C07C37/08

CPC classification number: C07C2/74 ,  C07C37/08 ,  C07C45/53 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C39/04 ,  C07C49/403

Abstract: In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.

Abstract translation: 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。

公开(公告)号：US20060021912A1

公开(公告)日：2006-02-02

申请号：US10903152

申请日：2004-07-30

Applicant: Tan-Jen Chen ,  Paul Keusenkothen ,  J. Wu ,  John Buchanan ,  Guang Cao ,  Larry Laccino ,  David Stern ,  Matthew Vincent

Inventor： Tan-Jen Chen ,  Paul Keusenkothen ,  J. Wu ,  John Buchanan ,  Guang Cao ,  Larry Laccino ,  David Stern ,  Matthew Vincent

IPC: C10G11/05

CPC classification number: C10G11/05 ,  C10G2400/20

Abstract: There is provided a catalyst composition having improved hydrothermal stability for the catalytic cracking of a hydrocarbon feedstock to selectively produce propylene. The catalyst composition comprises a first crystalline molecular sieve selected from the group consisting of IM-5, MWW, ITH, FER, MFS, AEL, and AFO and an effective amount of a stabilization metal (copper, zirconium, or mixtures thereof) exchanged into the molecular sieve. The catalyst finds application in the cracking of naphtha and heavy hydrocarbon feedstocks. When used in the catalytic cracking of heavier hydrocarbon feedstocks, the catalyst composition preferably comprises a second molecular sieve having a pore size that is greater than the pore size of the first molecular sieve. The process is carried out by contacting a feedstock containing hydrocarbons having at least 4 carbon atoms is contacted, under catalytic cracking conditions, with the catalyst composition.

公开(公告)号：US06090271A

公开(公告)日：2000-07-18

申请号：US872808

申请日：1997-06-10

Applicant: Joseph Francis Carpency ,  Tan-Jen Chen ,  Shun Chong Fung ,  Andrew Brennek

Inventor： Joseph Francis Carpency ,  Tan-Jen Chen ,  Shun Chong Fung ,  Andrew Brennek

IPC: C07C4/06 ,  C07B61/00 ,  C07C11/04 ,  C07C11/06 ,  C10G11/00 ,  C10G11/05 ,  C07C4/02 ,  C10G11/02

CPC classification number: C10G11/00 ,  C10G2400/20

Abstract: The invention provides a process for improving the conversion of a hydrocarbon feedstock to light olefins comprising mixing a hydrocarbon feedstock with a diolefin to form a mixture; and thereafter contacting the mixture with a zeolite cracking catalyst. Preferably the catalyst is contacted at a reaction temperature within the range of about 500.degree. C. to about 750.degree. C. and the feedstock flows at a weight hourly space velocity in the range of about 0.1 Hr.sup.-1 WHSV to about 100 Hr.sup.-1 WHSV. The diolefin can be a straight, branched, or cyclic hydrocarbon having at least two II bonds. Preferably diolefin is a hydrocarbon of 4 to 20 carbons.

Abstract translation: 本发明提供了一种改进烃原料转化为轻质烯烃的方法，包括将烃原料与二烯烃混合以形成混合物; 然后使该混合物与沸石裂化催化剂接触。 优选地，催化剂在约500℃至约750℃范围内的反应温度下接触，原料以约0.1Hr-1WHSV至约100Hr-1的重时空速流动 WHSV。 二烯烃可以是具有至少两个II键的直链，支链或环状烃。 二烯烃优选为4至20个碳的烃。

公开(公告)号：US5318695A

公开(公告)日：1994-06-07

申请号：US982933

申请日：1992-11-30

Applicant: Paul E. Eberly ,  William E. Winter ,  William L. Schuette ,  William A. Wachter ,  Tan-Jen Chen

Inventor： Paul E. Eberly ,  William E. Winter ,  William L. Schuette ,  William A. Wachter ,  Tan-Jen Chen

IPC: C10G11/05 ,  C10G11/00 ,  C10G11/02

CPC classification number: C10G11/05

Abstract: A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

Abstract translation: 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。