Enhanced olefin yields in a catalytic process with diolefins
    1.
    发明授权
    Enhanced olefin yields in a catalytic process with diolefins 失效
    在二烯烃催化过程中提高烯烃产率

    公开(公告)号:US06090271A

    公开(公告)日:2000-07-18

    申请号:US872808

    申请日:1997-06-10

    CPC分类号: C10G11/00 C10G2400/20

    摘要: The invention provides a process for improving the conversion of a hydrocarbon feedstock to light olefins comprising mixing a hydrocarbon feedstock with a diolefin to form a mixture; and thereafter contacting the mixture with a zeolite cracking catalyst. Preferably the catalyst is contacted at a reaction temperature within the range of about 500.degree. C. to about 750.degree. C. and the feedstock flows at a weight hourly space velocity in the range of about 0.1 Hr.sup.-1 WHSV to about 100 Hr.sup.-1 WHSV. The diolefin can be a straight, branched, or cyclic hydrocarbon having at least two II bonds. Preferably diolefin is a hydrocarbon of 4 to 20 carbons.

    摘要翻译: 本发明提供了一种改进烃原料转化为轻质烯烃的方法,包括将烃原料与二烯烃混合以形成混合物; 然后使该混合物与沸石裂化催化剂接触。 优选地,催化剂在约500℃至约750℃范围内的反应温度下接触,原料以约0.1Hr-1WHSV至约100Hr-1的重时空速流动 WHSV。 二烯烃可以是具有至少两个II键的直链,支链或环状烃。 二烯烃优选为4至20个碳的烃。

    Operating method for fluid catalytic cracking involving alternating feed
injection
    4.
    发明授权
    Operating method for fluid catalytic cracking involving alternating feed injection 有权
    涉及交替进料注入的流化床催化裂化操作方法

    公开(公告)号:US6156189A

    公开(公告)日:2000-12-05

    申请号:US294951

    申请日:1999-04-20

    IPC分类号: C10G11/18 C10G11/00

    CPC分类号: C10G11/18 Y10S208/01

    摘要: The present invention is directed to a Fluid Catalytic Cracking process conducted under fluid catalytic cracking conditions by injecting into at least one reaction zone of a fluid catalytic cracking unit (FCCU) having one or more risers, a plurality of feeds wherein said plurality of feeds comprises at least one feed (.alpha.) and at least another feed (.beta.) wherein said feeds (.alpha.) and (.beta.) (a) differ in Conradson Carbon Residue by at least about 2 wt % points; or (b) differ in hydrogen content by at least about 0.2 wt %; or (c) differ in API gravities by at least about 2 points; or (d) differ in nitrogen content by at least about 50 ppm; or (e) differ in carbon-to-hydrogen ratio by at least about 0.3; or (f) differ in mean boiling point by at least about 200.degree. F; and wherein said feeds (.alpha.) and (.beta.) are alternately injected and wherein said alternate injection maintains said risers in a cyclic steady state, while the rest of the FCC unit is in a steady state.

    摘要翻译: 本发明涉及一种在流化催化裂化条件下进行的流体催化裂化方法,该方法是将具有一个或多个立管的流化催化裂化装置(FCCU)的至少一个反应区注入多个进料,其中所述多个进料包含 至少一种进料(α)和至少另一种进料(β),其中所述进料(α)和(β)(a)在康拉德森碳残余物中不同至少约2重量% 或(b)氢含量不同至少约0.2wt%; 或(c)API重力差异至少约2分; 或(d)氮含量不同至少约50ppm; 或(e)碳 - 氢比率不等于至少约0.3; 或(f)平均沸点不同至少约200°F; 并且其中所述进料(α)和(β)被交替注入,并且其中所述交替喷射维持所述提升管处于循环稳定状态,而FCC装置的其余部分处于稳定状态。

    Conversion of oxygenates to olefins
    5.
    发明授权
    Conversion of oxygenates to olefins 有权
    含氧化合物转化为烯烃

    公开(公告)号:US07166757B2

    公开(公告)日:2007-01-23

    申请号:US10909014

    申请日:2004-07-30

    IPC分类号: C07C1/00

    摘要: A process is described for converting an oxygenate-containing feedstock into one or more olefins in which the feedstock is contacted in a reaction zone with a fluidized bed of a particulate catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide whereby at least part of the feedstock is converted into a product stream comprising one or more olefins and a carbonaceous material is deposited on the catalyst composition to produce a coked catalyst composition. The coked catalyst composition is separated from the product stream and divided into at least first and second portions. The first portion of the coked catalyst composition is contacted with a regeneration medium in a regeneration zone under conditions to remove at least part of the carbonaceous material from the coked catalyst composition and produce a regenerated catalyst composition, which is subsequently recycled to the reaction zone. The second portion of the coked catalyst composition is also recycled to the reaction zone but without being initially contacted with a regeneration medium.

    摘要翻译: 描述了一种用于将含氧化合物的原料转化成一种或多种烯烃,其中原料在反应区中与包含分子筛和至少一种具有碳吸收性的金属氧化物的颗粒催化剂组合物的流化床接触的烯烃 二氧化碳在100℃下为至少0.03mg / m 2的金属氧化物,由此至少部分原料转化为包含一种或多种烯烃的产物流,并将碳质材料沉积在 用于生产焦化催化剂组合物的催化剂组合物。 将焦炭催化剂组合物与产物流分离并分成至少第一和第二部分。 焦化催化剂组合物的第一部分与再生区中的再生介质接触,在从焦炭催化剂组合物中除去至少一部分碳质材料的条件下,并产生再生催化剂组合物,随后再循环到反应区。 焦炭催化剂组合物的第二部分也被循环到反应区,但不最初与再生介质接触。

    Method for depositing catalyst metals into zeolite to produce hydrocarbon processing catalyst
    6.
    发明授权
    Method for depositing catalyst metals into zeolite to produce hydrocarbon processing catalyst 失效
    将催化剂金属沉积到沸石中以产生烃加工催化剂的方法

    公开(公告)号:US06506703B1

    公开(公告)日:2003-01-14

    申请号:US09341717

    申请日:2000-01-24

    IPC分类号: B01J2962

    摘要: An ion exchange method is provided for loading and uniformly distributing noble metals into a catalyst substrate comprising a zeolite to make a monofunctional, non-acidic reforming catalyst. The catalyst substrate is contacted with an aqueous loading solution comprising noble metal cations and non-noble metal cations. The loading solution is formulated such that the equivalents of non-noble metal cations remaining in the catalyst not ionically bonded to the zeolite when loading is complete is 1.2 to 6.0 times the equivalents of non-noble metal cations displaced from the zeolite when the noble metal cations ion exchange into the zeolite, and simultaneously the endpoint pH of the loading solution is between 10.0 and 11.5. The required 1.2 to 6.0 ratio is achieved when the ratio of moles of non-noble metal cations added to the loading solution to moles of noble metal added to the loading solution is between 1 and 10. The use of ion exchange method results in zeolite catalysts having reduced amounts of detrital material in the micropores of the zeolite.

    摘要翻译: 提供了一种离子交换方法,用于将贵金属负载并均匀分布到包含沸石的催化剂基质中以制备单官能的非酸性重整催化剂。 催化剂底物与包含贵金属阳离子和非贵金属阳离子的含水负载溶液接触。 配制装载溶液使得当装载完成时,残留在催化剂中不与离子键合的催化剂中的非贵金属阳离子的当量是贵金属离子从沸石中排出的非贵金属阳离子的当量的1.2至6.0倍 离子交换成沸石,同时加载溶液的终点pH在10.0和11.5之间。 当添加到负载溶液中的非贵金属阳离子的摩尔比与添加到负载溶液中的贵金属的摩尔数的比例在1和10之间时,实现所需的1.2至6.0的比率。使用离子交换法产生沸石催化剂 在沸石的微孔中具有减少的碎屑物质的量。