摘要:
In a method for examining a negative electrode of a battery, a total thickness of a current collector and an active material layer is measured. Then, in order to estimate a composition of the active material layer, the total resistivity of the current collector and the active material layer is measured.
摘要:
In a method for manufacturing a negative electrode for a battery, an active material layer including a metallic element M and an element A that is at least any one of oxygen, nitrogen, and carbon is formed on a current collector. This active material layer is irradiated with an X-ray and at least one of intensity of a Kα ray of the element A and intensity of a Kα ray of the metallic element M in fluorescent X-rays generated from the active material layer is measured.
摘要:
A method for manufacturing a negative electrode for a non-aqueous electrolyte secondary battery is provided. A negative electrode precursor of the non-aqueous electrolyte secondary battery is allowed to absorb lithium ions, the negative electrode precursor includes a current collector and an active material layer formed on the current collector. The precursor is provided with an exposed portion of the current collector. In this method, a negative electrode active material layer is allowed to absorb lithium ions by electrolysis in the non-aqueous electrolyte solution. At this time, by measuring a potential of a portion immersed in the non-aqueous electrolyte solution, the exposed portion is detected and an electric current of the electrolysis is controlled. Thereby, the deposition of lithium metal on the exposed portion is suppressed.
摘要:
A battery pack 1 of the present invention includes: a secondary battery 2; a molded body 11 configured to store therein the secondary battery; a temperature increase suppressing layer 13 provided between the secondary battery and an inner surface of the molded body to suppress a temperature increase of an outer surface of the molded body; and a block layer 12 provided between the secondary battery and the temperature increase suppressing layer to block leakage from the secondary battery. With this, if a malfunction, such as a case where contents, such as a molten material, flows out from the secondary battery, occurs, the contents are prevented from flowing out to the outside of the battery pack, and the temperature increase of the surface of the battery pack is suppressed.
摘要:
A portable electronic device of the present invention includes a package, an electronic device body, a battery housing portion including a battery fitting portion for fitting a secondary battery therein, a foaming agent-containing layer provided on a surface of the battery housing portion, and a secondary battery to be fitted in the battery fitting portion. The foaming agent-containing layer is normally thin and, in the event of the battery generating heat, the layer turns into a thicker foamed layer which exhibits superior thermal insulation properties. Thus, it is possible to provide a portable electronic device having the degree of freedom in design for size and thickness reduction achieved at a high level, while offering high-level safety and reliability.
摘要:
A negative electrode for a non-aqueous electrolyte secondary battery including: a current collector; and an active material layer including at least two alloy-based active materials selected from the group consisting of silicon, tin, a silicon oxide, and a tin oxide. The active material layer includes a first portion supported on a surface of the current collector, a second portion supported on a surface of the first portion, and a third portion supported on a surface of the second portion. The first portion includes the silicon oxide or the tin oxide, and the oxygen content in the silicon oxide or the tin oxide in the first portion decreases continuously or stepwise as approaching the second portion. The second portion includes silicon or tin. The third portion includes the silicon oxide or the tin oxide, and the oxygen content in the silicon oxide or the tin oxide in the third portion increases continuously or stepwise with distance from the second portion.
摘要:
A positive electrode for use in a lithium secondary battery comprises a positive electrode current collector, and a positive electrode film which is carried on the positive electrode current collector and includes a plurality of mixture layers. The positive electrode film contains, as a positive electrode active material, two or more kinds of lithium-containing compounds having exothermic initiation temperatures different from each other. At least one kind of the two or more kinds of lithium-containing compounds has the exothermic initiation temperature of 300 ° C. or higher. A first mixture layer of the plural mixture layers closest to the positive electrode current collector contains at least one kind of the lithium-containing compound having the exothermic initiation temperature of 300 ° C. or higher.
摘要:
A lithium secondary battery of this invention includes: a positive electrode including a positive electrode active material; a negative electrode including a negative electrode active material; a separator; and a non-aqueous electrolyte. The negative electrode active material includes a first portion capable of absorbing and desorbing lithium ions and a second portion covering at least a part of a surface of the first portion. The second portion includes at least one material that is less reactive with oxygen than the first portion.
摘要:
A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including a positive electrode material mixture, a negative electrode including a negative electrode material mixture, and a non-aqueous electrolyte including a non-aqueous solvent and a first lithium salt and a second lithium salt dissolved in the non-aqueous solvent. The negative electrode material mixture includes a material capable of absorbing and desorbing lithium ions, and carbon nanofibers. The material capable of absorbing and desorbing lithium ions has a ratio A/B of a volume A in a charged state to a volume B in a discharged state of 1.2 or more. The first lithium salt is at least one selected from the group consisting of LiBF4 and LiB(C2O4)2. The second lithium salt is a salt other than the first lithium salt. The first lithium salt is included in the non-aqueous electrolyte at a weight ratio of 10−4 or more relative to the carbon nanofibers. The first lithium salt included in the non-aqueous electrolyte has a concentration of 0.05 mol/dm3 or less.
摘要:
A method of manufacturing a negative electrode for a non-aqueous electrolyte secondary battery includes a step of imparting lithium to a precursor of the negative electrode capable of storing and releasing lithium, by a film forming method in a dry process. In this step, the precursor is brought into contact with a measuring terminal having a non-aqueous electrolyte and a counter electrode. The amount of lithium stored in the precursor is calculated from an open circuit potential of the precursor with respect to the counter electrode. Further, according to the calculated amount of stored lithium, the amount of lithium to be imparted to the precursor is controlled.