公开(公告)号：US20150203417A1

公开(公告)日：2015-07-23

申请号：US14379187

申请日：2012-02-29

Applicant: Zhijian Tian ,  Congxin Wang ,  Lei Wang ,  Bingchun Wang ,  Lijun Yan ,  Wei Qu ,  Peng Li ,  Huaijun Ma ,  Renshun Xu

Inventor： Zhijian Tian ,  Congxin Wang ,  Lei Wang ,  Bingchun Wang ,  Lijun Yan ,  Wei Qu ,  Peng Li ,  Huaijun Ma ,  Renshun Xu

IPC: C07C1/207 ,  B01J19/24 ,  B01J29/76 ,  B01J29/85 ,  B01J29/74 ,  C07C5/27 ,  B01J29/00

CPC classification number: C07C1/2078 ,  B01J19/24 ,  B01J19/2445 ,  B01J29/005 ,  B01J29/40 ,  B01J29/65 ,  B01J29/703 ,  B01J29/7034 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/7484 ,  B01J29/7684 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J2219/24 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/2076 ,  C07C5/2754 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/652 ,  C07C2523/883 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/83 ,  C07C2529/85 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/04 ,  C07C9/14 ,  C07C9/22

Abstract: A process is described for producing a hydrocarbon product. In examples, the process comprising contacting a feedstock with a catalyst composition in the presence of hydrogen, the feedstock including a lipid, and the catalyst composition being active for conversion of the lipid to the hydrocarbon product in a single step. The catalyst composition comprises an M1-8 Sup] catalyst, where M1 is an active metal and [Sup] comprises an acidic support. In examples described, the process is used in the production of diesel-range fuel and/or jet fuel from lipid having a high yield of C11-C24 branched alkanes with high cetane value and low freeing point. In examples, the hydrocarbon product includes greater than 70% measured by weight of C11-C24 alkanes based on the weight of the lipid, and the content of branched alkanes of the C11-C24 alkanes is greater than 60% measured by weight of branched C11-C24 alkanes based on the weight of the C11-C24 alkanes.

Abstract translation: 描述了用于生产烃产物的方法。 在实施例中，该方法包括在氢存在下使原料与催化剂组合物接触，所述原料包括脂质，并且所述催化剂组合物在单一步骤中用于将脂质转化成烃产物是有活性的。 催化剂组合物包含M1-8 Sup]催化剂，其中M1是活性金属，[Sup]包含酸性载体。 在所描述的实施例中，该方法用于从具有高十八烷值和低释放点的C11-C24支链烷烃的高产率的脂质生产柴油范围燃料和/或喷气燃料。 在实施例中，基于脂质重量，烃产物包含大于70重量％的C 11 -C 24烷烃，C 11 -C 24烷烃的支链烷烃含量大于支化C 11重量的60％ -C 24烷烃，基于C 11 -C 24烷烃的重量。

公开(公告)号：US08558042B2

公开(公告)日：2013-10-15

申请号：US13742255

申请日：2013-01-15

Applicant: Syntroleum Corporation

Inventor： Ramin Abhari ,  H. Lynn Tomlinson ,  Gary Roth

IPC: C10L1/04 ,  C10G3/00

CPC classification number: C07C9/02 ,  C07C9/14 ,  C07C9/22 ,  C10G3/46 ,  C10G3/50 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/301 ,  C10G2300/308 ,  C10G2400/02 ,  C10L1/06 ,  Y02E50/13 ,  Y02P30/20

Abstract: The present invention generally relates to a method for producing a naphtha product from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins, and hydrocracking the hydrotreating unit heavy fraction to produce a hydrocracking unit product that includes the naphtha product. The method also includes separating the naphtha fraction and optionally recycling the hydrocracking unit heavy fraction through the hydrocracking unit. The present invention also relates to a biorenewable naphtha product suitable for use as feed stock for steam crackers and catalytic reforming units, and for use as fuel, or fuel blend stock.

Abstract translation: 本发明一般涉及从可再生原料生产石脑油产品的方法。 该方法包括加氢处理可再生原料以产生包含正链烷烃的加氢处理单元重馏分，以及加氢处理单元重馏分加氢裂化以产生包含石脑油产物的加氢裂化装置产品。 该方法还包括分离石脑油馏分并任选地通过加氢裂化装置再循环加氢裂化装置重馏分。 本发明还涉及一种适用于蒸汽裂化装置和催化重整装置的原料的生物可再生石脑油产品，用作燃料或燃料混合原料。

公开(公告)号：US08404225B2

公开(公告)日：2013-03-26

申请号：US12591535

申请日：2009-11-23

Applicant: Peter Silk ,  Jon Sweeney ,  Krista Ryall ,  Barry Lyons

Inventor： Peter Silk ,  Jon Sweeney ,  Krista Ryall ,  Barry Lyons

IPC: A01N25/08 ,  A01N25/32 ,  A01N27/00 ,  A01N65/00

CPC classification number: C07C1/326 ,  A01N27/00 ,  C07C1/34 ,  C07C5/03 ,  C07C45/40 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2527/122 ,  C07C2527/138 ,  C07C11/02 ,  C07C9/22 ,  C07C47/02

Abstract: The invention disclosed relates to the detection of the Emerald Ash Borer (EAB), Agrilus planipennis Fairmaire (Coleoptra: B-prestidae) and in particular to the use of contact sex phenomones therefor. Analysis of the elytral hydrocarbons from male and female emerald ash borer, that were freshly emerged vs. sexually mature (>10 days old) revealed a female-specific compound, 9-methyl-pentacosane (9-Me-C25), only present in sexually mature females. This material was synthesized by the Wittig reaction of 2-decanone with (n-hexadecyl)-triphenylphosphonium bromide followed by catalytic reduction to yield racemic 9-Me C25, which matched the natural compound by GC/MS (retention time and EI-mass spectrum). In field bioassays with freeze-killed sexually mature A. planipennis females, feral males spent significantly more time in contact and attempting copulation with unwashed females than with females that had been washed in n-hexane to remove the cuticular hydrocarbons. Hexane-washed females to which 9-Me-C25 had been reapplied elicited similar contact time and percentage of time attempting copulation as unwashed females, indicating that 9-methyl-pentacosane is a contact sex-pheromone component of A. planipennis. This is the first contact sex pheromone identified in the Buprestidae.

Abstract translation: 所公开的发明涉及翡翠灰烬（EAB），平菇（Agrilus planipennis Fairmaire）（Coleoptra：B-prestidae）的检测，特别是涉及使用接触性的方法。 来自男性和女性翡翠灰螟的新陈代谢分析（新鲜出现与性成熟（> 10天龄））显示女性特异性化合物9-甲基 - 二十五烷（9-Me-C25），仅存在于 性成熟女性 该物质通过2-癸酮与（正十六烷基） - 三苯基溴化鏻的Wittig反应合成，然后进行催化还原，得到外消旋的9-Me C25，其通过GC / MS（保留时间和EI质谱）与天然化合物相符 ）。 在具有冷冻杀死性成熟的平豌豆女性的野外生物测定中，野性雄性花费显着更多的时间接触并尝试与未洗涤的雌性交配，而不是在已经在正己烷中洗涤以除去角质碳氢化合物的雌性。 已经重新应用9-Me-C25的己烷洗涤的雌性引起类似的接触时间和尝试交配作为未洗涤的雌性的时间百分比，表明9-甲基 - 二十五烷是A.planipennis的接触性信息素组分。 这是Buprestidae中首次接触性信息素。

公开(公告)号：US20120238791A1

公开(公告)日：2012-09-20

申请号：US13466813

申请日：2012-05-08

Applicant: Ramin Abhari ,  H. Lynn Tomlinson ,  Vladimir Gruver

Inventor： Ramin Abhari ,  H. Lynn Tomlinson ,  Vladimir Gruver

IPC: C10G1/08

CPC classification number: C07C1/2078 ,  C07C1/22 ,  C07C9/14 ,  C07C9/15 ,  C07C9/22 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2523/888 ,  C07C2525/00 ,  C07C2525/02 ,  C07C2527/18 ,  C09K5/063 ,  C10L1/04

Abstract: Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.

Abstract translation: 本文公开了主要包括偶数碳数链烷烃的石蜡组合物及其制备方法。 在一个实施方案中，该方法包括将天然存在的脂肪酸/甘油酯与氢气在含有约10至约400微米当量粒径的双金属催化剂的浆液气泡塔反应器中接触。 均匀的碳数组合物特别可用作相变材料。

公开(公告)号：US20120209036A1

公开(公告)日：2012-08-16

申请号：US12769757

申请日：2010-04-29

Applicant: Benjamin G. Harvey ,  Roxanne L. Quintana

Inventor： Benjamin G. Harvey ,  Roxanne L. Quintana

IPC: C10L1/16 ,  C07C2/00

CPC classification number: C10L1/04 ,  C07C2/16 ,  C07C2/34 ,  C07C5/03 ,  C07C2527/054 ,  C07C2531/14 ,  C07C2531/38 ,  C10G69/126 ,  C07C11/02 ,  C07C9/14 ,  C07C9/22

Abstract: A process for making diesel and turbine fuels including, providing an effective amount of branched olefins, adding active heterogeneous acid catalyst(s) to said branched olefins to produce a solvent-free mixture, heating said solvent-free mixture greater than about 100° C. for a desired amount of time depending on various conditions, to produce C16 dimers/catalyst mixture, removing said catalysts from said dimers/catalyst mixture, and adding hydrogenation catalyst(s) to said dimers under hydrogen atmosphere to produce a mixture of stable fuels.

Abstract translation: 一种制备柴油和涡轮燃料的方法，包括提供有效量的支链烯烃，向所述支链烯烃中加入活性多相酸催化剂以产生无溶剂的混合物，加热大于约100℃的无溶剂混合物 根据各种条件的期望的时间量，生产C16二聚体/催化剂混合物，从所述二聚体/催化剂混合物中除去所述催化剂，并在氢气氛下向所述二聚体中加入氢化催化剂以产生稳定燃料的混合物 。

公开(公告)号：US08168838B2

公开(公告)日：2012-05-01

申请号：US12689709

申请日：2010-01-19

Applicant: William J Heilman ,  Yajnanarayana Halmuthur Jois ,  Abraham Robert De Kraker ,  Wei Song

Inventor： William J Heilman ,  Yajnanarayana Halmuthur Jois ,  Abraham Robert De Kraker ,  Wei Song

IPC: C10M105/04 ,  C07C9/22

CPC classification number: C07C9/22 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/301 ,  C10G2300/302 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/06 ,  C10N2230/08 ,  C10N2230/10 ,  C10N2230/74 ,  C10N2240/10 ,  C10N2260/02

Abstract: A process for the preparation of a synthetic predominantly single carbon number hydrocarbon fluid comprises the steps of: contacting an alpha olefin having a carbon number of 4 to 30 with a single site catalyst under conditions effective to produce reactive hydrocarbon oligomers that contain reactive double bonds and comprising predominantly dimers, trimers, and tetramers wherein at least 10 weight percent of such reactive hydrocarbon oligomers at least one of trimers and tetramers; separating at least one of said trimers and tetramers in said reactive hydrocarbon oligomers; dimerizing said separated one of said trimers tetramers by contacting said separated one of said trimers or tetramers with a dimerization catalyst thereby producing an unsaturated synthetic hydrocarbon fluid; and contacting said unsaturated synthetic hydrocarbon fluid with hydrogen in the presence of a hydrogenation catalyst thereby producing a synthetic hydrocarbon fluid having predominantly single carbon number.

Abstract translation: 用于制备主要为单一碳原子数合成烃合成流体的方法包括以下步骤：在有效产生含有反应性双键的活性烃低聚物的条件下，将碳数为4〜30的α-烯烃与单中心催化剂接触， 主要包含二聚体，三聚体和四聚体，其中至少10重量％的这种活性烃低聚物至少一种三聚体和四聚体; 在所述反应性烃低聚物中分离所述三聚体和四聚体中的至少一种; 通过使所述三聚体或四聚体中的所述分离的一个与二聚催化剂接触来使所述三聚体四聚体中的所述分离的一个二聚，由此产生不饱和的合成烃流体; 并在氢化催化剂存在下使所述不饱和合成烃流体与氢气接触，从而产生主要具有单一碳数的合成烃流体。

公开(公告)号：US20110160505A1

公开(公告)日：2011-06-30

申请号：US12701236

申请日：2010-02-05

Applicant: Michael J. McCall

Inventor： Michael J. McCall

IPC: C07C1/00

CPC classification number: C07C9/16 ,  C07C9/22 ,  C10G3/42 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/4006 ,  C10G2300/4081 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

Abstract: A process has been developed for producing diesel fuel from crude tall oil. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

Abstract translation: 已经开发了一种从粗妥尔油生产柴油的方法。 该方法包括通过氢化和脱氧处理可再生原料以提供柴油沸程燃料烃产物。 如果需要，烃产物可被异构化以改善冷流动性能。 一部分烃产物被再循环到处理区以提高反应混合物的氢溶解度。

公开(公告)号：US20110056656A1

公开(公告)日：2011-03-10

申请号：US12863643

申请日：2009-01-15

Applicant: Holger Ziehe ,  Achim Weitze ,  Thoralf Gross

Inventor： Holger Ziehe ,  Achim Weitze ,  Thoralf Gross

IPC: F28D15/00

CPC classification number: C07C1/24 ,  C07C5/03 ,  C07C9/22 ,  C07C29/80 ,  C07C41/09 ,  C07C43/04 ,  C07C2523/755 ,  C09K5/063

Abstract: The invention relates to a method for producing latent heat storage material from linear alcohols by dehydrating to dialkyl ethers or to olefins, and hydrating to paraffins and dialkyl ether as a latent heat storage material.

Abstract translation: 本发明涉及一种通过脱水至二烷基醚或烯烃从线性醇生产潜热蓄热材料的方法，并将其与作为潜热蓄热材料的石蜡和二烷基醚进行水合。

公开(公告)号：US20100317910A1

公开(公告)日：2010-12-16

申请号：US12813244

申请日：2010-06-10

Applicant: Martijn J. M. Mies ,  Mark H. Harte ,  Edgar Evert Steenwinkel ,  Emanuel Hermanus van Broekhoven

Inventor： Martijn J. M. Mies ,  Mark H. Harte ,  Edgar Evert Steenwinkel ,  Emanuel Hermanus van Broekhoven

IPC: B01J29/068 ,  B01J29/06 ,  C07C5/27

CPC classification number: B01J29/85 ,  B01J29/005 ,  B01J37/10 ,  B01J2229/18 ,  C01B39/54 ,  C07C5/2775 ,  C07C2529/85 ,  C10G45/64 ,  C07C9/22

Abstract: Novel silicoaluminophosphate molecular sieve compositions comprising SAPO-11 and SAPO-41 with at least about 5 wt % of in situ-produced amorphous portion. Such compositions can be uncalcined or calcined and novel processes for their preparation are described. These compositions, when loaded or impregnated with a catalytically active species such as a Group VIII noble metal are novel, and are excellent hydroisomerization catalysts.

Abstract translation: 新型硅铝磷酸盐分子筛组合物，其包含SAPO-11和SAPO-41，其具有至少约5重量％的原位产生的无定形部分。 这些组合物可以是未煅烧的或煅烧的，并且描述了它们制备的新方法。 当用催化活性物质如VIII族贵金属负载或浸渍时，这些组合物是新颖的，并且是优异的加氢异构化催化剂。

公开(公告)号：US07259284B2

公开(公告)日：2007-08-21

申请号：US10900221

申请日：2004-07-27

Applicant: Kenneth D. Hope ,  Donald W. Twomey ,  Michael S. Driver ,  Donald A. Stern ,  J. Barry Collins ,  Thomas V. Harris

Inventor： Kenneth D. Hope ,  Donald W. Twomey ,  Michael S. Driver ,  Donald A. Stern ,  J. Barry Collins ,  Thomas V. Harris

IPC: C07C2/04

CPC classification number: C08F10/00 ,  C07C2/22 ,  C07C2/26 ,  C07C2/30 ,  C07C9/22 ,  C07C11/02 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/14 ,  C08F110/14 ,  C08F4/14 ,  C08F2/00 ,  C08F4/12 ,  C08F2500/02 ,  C08F2500/17

Abstract: A process for preparing very high viscosity polyalphaolefins using an acidic ionic liquid oligomerization catalyst in the absence of an organic diluent and the products formed thereby. A method of continuously manufacturing a high viscosity polyalphaolefin product by introducing a monomer and an ionic liquid catalyst together into a reaction zone while simultaneously withdrawing from the reaction zone a reaction zone effluent that contains the high viscosity polyalphaolefin. The reaction zone is operated under reaction conditions suitable for producing the high viscosity polyalphaolefin product. The preferred high viscosity polyalphaolefin has a kinematic viscosity exceeding 8 cSt and is the reaction product of the trimerization, oligomerization, or polymerization of an alpha olefin or a mixture of one or more product thereof. The high viscosity polyalphaolefins are useful as lubricants or lubricant additives.

Abstract translation: 在不存在有机稀释剂的情况下使用酸性离子液体低聚催化剂制备非常高粘度的聚α-烯烃的方法以及由此形成的产物。 通过将单体和离子液体催化剂一起引入反应区而同时从反应区抽出包含高粘度聚α烯烃的反应区流出物，连续制造高粘度聚α-烯烃产物的方法。 反应区在适于生产高粘度聚α-烯烃产物的反应条件下运行。 优选的高粘度聚α-烯烃具有超过8cSt的运动粘度，并且是α烯烃或其一种或多种产物的混合物的三聚，低聚或聚合的反应产物。 高粘度聚α-烯烃可用作润滑剂或润滑剂添加剂。