Stabilizer combination for the rotomolding process
    43.
    发明授权
    Stabilizer combination for the rotomolding process 有权
    稳定剂组合用于滚塑过程

    公开(公告)号:US06902695B2

    公开(公告)日:2005-06-07

    申请号:US10762601

    申请日:2004-01-22

    申请人: Urs Leo Stadler

    发明人: Urs Leo Stadler

    摘要: A process for the production of polyolefin hollow articles comprises charging the polyolefin with a stabilizer combination comprising (a) at least one compound from the group of the organic phosphites or phosphonites, (b) one or more compounds selected from the group consisting of i.) hydroxylamine derivatives and ii.) amine oxide derivatives and (c) at least one compound from the group of the hindered amine stabilizers, filling this mixture into a mold, heating this mold in an oven to above 280° C., such that the stabilized polyolefin fuses, rotating the mold around at least 2 axes, the plastic spreading to the walls, and cooling the mold while still rotating, opening it and taking the resultant hollow article out.

    摘要翻译: 制备聚烯烃中空制品的方法包括用稳定剂组合物填充聚烯烃,所述稳定剂组合包含(a)至少一种来自有机亚磷酸酯或亚膦酸酯的化合物,(b)一种或多种选自以下的化合物: )羟胺衍生物和ii。)氧化胺衍生物和(c)至少一种来自受阻胺稳定剂的化合物,将该混合物填充到模具中,将该模具在烘箱中加热至280℃以上,使得 稳定的聚烯烃保险丝,将模具绕至少2个轴线旋转,塑料扩展到墙壁,并在仍然旋转的同时冷却模具,将其打开并取出所得的空心制品。

    Granular polymer additives and their preparation
    44.
    发明申请
    Granular polymer additives and their preparation 失效
    颗粒状聚合物添加剂及其制备方法

    公开(公告)号:US20050009725A1

    公开(公告)日:2005-01-13

    申请号:US10911253

    申请日:2004-08-04

    申请人: John Semen

    发明人: John Semen

    摘要: A compacted particulate polymer additive composition in a dry granular form formed from a substantially uniform mixture of the following components: (a) at least one particulate sterically-hindered phenolic compound; and (b) one or more particulate polymer additives other than a sterically-hindered phenolic compound; wherein the particles of said composition are held together in compacted dry granular form exclusively or substantially exclusively by contact with dried surfaces of in situ desolvated particles from particles of one or more at least partially solvated components of (a), and optionally by contact with dried surfaces of in situ desolvated particles from particles of one or more at least partially solvated components of (b). Compositions of this type except that there is no component (b) are also described.

    摘要翻译: 由以下组分的基本均匀的混合物形成的干颗粒形式的压实颗粒状聚合物添加剂组合物:(a)至少一种空间位阻的微粒化合物; 和(b)一种或多种除空间位阻酚类化合物以外的颗粒聚合物添加剂; 其中所述组合物的颗粒通过与(a)的一种或多种至少部分溶剂化的组分的颗粒接触的原位脱溶剂颗粒的干燥表面,或通过与干燥的 来自(b)的一种或多种至少部分溶剂化成分的颗粒的原位脱溶剂颗粒的表面。 还描述了除了没有组分(b)之外的这种类型的组合物。

    Flame-resistant polycarbonate molding compositions
    46.
    发明申请
    Flame-resistant polycarbonate molding compositions 有权
    耐火聚碳酸酯模塑组合物

    公开(公告)号:US20040059031A1

    公开(公告)日:2004-03-25

    申请号:US10627015

    申请日:2003-07-25

    IPC分类号: C08K005/49

    摘要: A thermoplastic molding composition having good flame resistance, melt flowability, resistance to chemicals and creep is disclosed. The composition contains A) at least one member having weight average molecular weight (Mw) of 25,000 to 35,000 g/mol, selected from the group consisting of aromatic polycarbonate and polyestercarbonate B) ABS graft polymer produced by the mass polymerization process and characterized in (i) having a butadiene content of 8 to 15% in relation to the weight of the graft polymer, (ii) having an acrylic acid derivative content of 15 to 30% in relation to the total weight of the acrylic derivative and styrene monomer, and (iii) containing styrene monomer-acrylic acid derivative copolymer having a weight average molecular weight of 5null104 to 14null104 g/mol. The composition may further contain one or more of halogen-free phosphorus compounds, fluorinated polyolefin, a polymer containing acrylate monomer and an inorganic material in particulate form.

    摘要翻译: 公开了具有良好的阻燃性,熔体流动性,耐化学性和蠕变性的热塑性模塑组合物。 该组合物包含A)至少一种重均分子量(Mw)为25,000-35,000g / mol,选自芳族聚碳酸酯和聚酯碳酸酯B)通过本体聚合方法制备的ABS接枝聚合物,其特征在于( i)相对于接枝聚合物的重量,丁二烯含量为8〜15%,(ii)相对于丙烯酸衍生物和苯乙烯单体的总重量,丙烯酸衍生物含量为15〜30%,和 (iii)含有重均分子量为5.10 4至1​​4.10 4 g / mol的苯乙烯单体 - 丙烯酸衍生物共聚物。 组合物还可以含有一种或多种无卤素磷化合物,氟化聚烯烃,含有丙烯酸酯单体的聚合物和颗粒形式的无机材料。

    Acid-methylol compound reaction products for flame resistance
    47.
    发明申请
    Acid-methylol compound reaction products for flame resistance 审中-公开
    酸 - 羟甲基化合物反应产物用于阻燃

    公开(公告)号:US20040039085A1

    公开(公告)日:2004-02-26

    申请号:US10275239

    申请日:2002-10-29

    摘要: This invention relates to novel flame retardants (FR) resulting from the reaction of (a) or (b) with (c) where (a) is a compound containing at least one amine group and with at least one sixteenth of the amine molecules having at least one methylol bond, (b) is a phenol with at least one sixteenth of the phenol molecules having at least one methylol bond, and (c) is a mineral acid, organic acid, and organo-phosphorous acid, or a mixture thereof and optionally adding a polyhydric compound and/or optionally adding formaldehyde to the acid. These compositions are for use in general flame retardant applications such as coatings, adhesives, and articles made of polymeric materials. The FR mechanism by which these compounds generally perform as an FR agent is intumescence but the field of this invention is not restricted to that mechanism. Some of the compounds have substantial intumescence and others have very little intumescence but still are flame retardants.

    摘要翻译: 本发明涉及由(a)或(b)与(c)的反应得到的新的阻燃剂(FR),其中(a)是含有至少一个胺基的化合物,并且至少十六分之一的胺分子具有 至少一种羟甲基键,(b)是具有至少十六分之一的具有至少一个羟甲基键的酚分子的苯酚,(c)是无机酸,有机酸和有机亚磷酸,或其混合物 并任选地加入多羟基化合物和/或任选地向酸中加入甲醛。 这些组合物用于通常的阻燃应用,例如涂料,粘合剂和由聚合材料制成的制品。 这些化合物通常作为FR剂进行的FR机理是膨胀,但是本发明的领域不限于该机理。 一些化合物具有显着的膨胀,而其它化合物具有很少的膨胀性,但仍然是阻燃剂。

    Non-inflammable, anti-electrostatic polycarbonate molding materials
    50.
    发明申请
    Non-inflammable, anti-electrostatic polycarbonate molding materials 有权
    不易燃,防静电聚碳酸酯成型材料

    公开(公告)号:US20030171472A1

    公开(公告)日:2003-09-11

    申请号:US10296687

    申请日:2002-11-26

    IPC分类号: C08L001/00

    摘要: The present invention relates to anti-electrostatic polycarbonate compositions which are provided with chlorine- and bromine-free flame resistance and are distinguished by good mechanical and thermal properties and problem-free processability in the injection moulding process, i.e. by a good melt flowability and a low tendency towards juicing. The present invention also relates to the use of the polycarbonate moulding compositions according to the invention for the production of shaped articles and mouldings of all types, and the shaped articles and mouldings themselves.

    摘要翻译: 本发明涉及具有无氯和无溴阻燃性的抗静电聚碳酸酯组合物,其特征在于在注射成型工艺中具有良好的机械和热性能以及无问题的可加工性,即通过良好的熔体流动性和 低榨汁倾向。 本发明还涉及根据本发明的聚碳酸酯模塑组合物用于生产各种成型制品和模制品以及成型制品和模制品本身的用途。