VAPOUR DEPOSITION OF ORGANIC UV ABSORBERS ONTO PLASTIC SUBSTRATES
    52.
    发明申请
    VAPOUR DEPOSITION OF ORGANIC UV ABSORBERS ONTO PLASTIC SUBSTRATES 审中-公开
    有机紫外线吸收剂蒸发沉积在塑料基材上

    公开(公告)号:US20150210651A1

    公开(公告)日:2015-07-30

    申请号:US14421907

    申请日:2013-08-19

    IPC分类号: C07D249/18 B05D7/02 B05D1/00

    摘要: Method for coating a plastics substrate with a functional layer, wherein (a) in a vacuum chamber, an organic UV absorber which comprises at least one chromophore and at least one reactive side chain is evaporated and (b) is brought into contact with at least one surface of the plastics substrate and excited with a plasma, or (c) is excited with a plasma and then brought into contact with at least one surface of the plastics substrate, whereby a functional layer comprising the UV absorber is formed on the surface of the plastics substrate, the plasma being ignited at a pressure of greater than 10−5 bar and less than 1.013 bar.

    摘要翻译: 用于涂覆具有功能层的塑料基材的方法,其中(a)在真空室中包含至少一个发色团和至少一个反应性侧链的有机UV吸收剂被蒸发,并且(b)至少与 塑料基板的一个表面并用等离子体激发,或(c)被等离子体激发,然后与塑料基板的至少一个表面接触,从而在其表面上形成包含紫外线吸收剂的功能层 塑料基材,等离子体在大于10-5巴和小于1.013巴的压力下点燃。

    METHOD FOR PRODUCING NITROBENZENE BY ADIABATIC NITRIDING
    55.
    发明申请
    METHOD FOR PRODUCING NITROBENZENE BY ADIABATIC NITRIDING 有权
    通过自制氮化生产硝基苯的方法

    公开(公告)号:US20150175522A1

    公开(公告)日:2015-06-25

    申请号:US14415788

    申请日:2013-07-23

    IPC分类号: C07C201/06

    摘要: The invention provides a continuous adiabatic process for the preparation of nitrobenzene by nitrating benzene with mixtures of sulfuric and nitric acids using a stoichiometric excess of benzene, wherein the content of organic compounds in the circulating sulfuric acid, at least during the start-up period of the production plant, is always kept below 1.0 mass percent, based on the total mass of circulating sulfuric acid. This is preferably achieved by a procedure in which, either after the end or before the beginning of a production cycle, the circulating sulfuric acid is circulated at elevated temperature so that the organics contained in the sulfuric acid, preferably comprising nitrobenzene and traces of benzene, dinitrobenzene and nitrophenols, are separated off in the evaporation apparatus for concentrating the sulfuric acid.

    摘要翻译: 本发明提供了一种连续的绝热方法,用于通过使用化学计量过量的苯将硫与硝酸的混合物硝化苯来制备硝基苯,其中循环硫酸中有机化合物的含量至少在启动期间 基于循环硫酸的总质量,生产厂总是保持在1.0质量%以下。 这优选通过以下程序来实现,其中,在生产周期结束或开始之前循环硫酸在升高的温度下循环,使得包含在硫酸中的有机物,优选包含硝基苯和痕量的苯, 二硝基苯和硝基苯酚在用于浓缩硫酸的蒸发装置中分离出来。

    METHOD FOR PRODUCING NITROBENZENE BY ADIABATIC NITRIDING
    56.
    发明申请
    METHOD FOR PRODUCING NITROBENZENE BY ADIABATIC NITRIDING 有权
    通过自制氮化生产硝基苯的方法

    公开(公告)号:US20150175521A1

    公开(公告)日:2015-06-25

    申请号:US14413277

    申请日:2013-07-23

    IPC分类号: C07C201/06

    摘要: The invention relates to an adiabatic process for producing nitrobenzene by nitrating benzene with sulphuric acid mixtures and nitric acid mixtures using a stoichiometric excess of benzene and reusing non-reacted benzene, the content of the aliphatic organic compounds in the feed benzene being limited, by the targeted evacuation of aliphatic organic compounds to at least one step in the process, to a content of less than 1.5 mass-%, in relation to the total amount of feed benzene.

    摘要翻译: 本发明涉及通过使用化学计量过量的苯用硝酸混合物和硝酸混合物硝化苯并重新使用未反应的苯来生产硝基苯的绝热方法,所述进料苯中的脂肪族有机化合物的含量受到限制, 将脂肪族有机化合物定向排出至该步骤中的至少一个步骤,其含量相对于进料苯的总量小于1.5质量%。

    METHOD FOR STOPPING A REACTION DURING THE PRODUCTION OF AROMATIC AMINES FROM NITROAROMATICS
    58.
    发明申请
    METHOD FOR STOPPING A REACTION DURING THE PRODUCTION OF AROMATIC AMINES FROM NITROAROMATICS 有权
    在硝基菌生产芳族氨基酸期间停止反应的方法

    公开(公告)号:US20150087862A1

    公开(公告)日:2015-03-26

    申请号:US14394142

    申请日:2013-04-12

    IPC分类号: C07C209/36

    摘要: The present invention relates to A method for producing aromatic amines by the hydrogenation of aromatic nitro compounds. This method comprises: A) supplying aromatic nitro compounds and hydrogen to a reactor and contacting them with a hydrogenation catalyst; and B) stopping the supply of aromatic nitro compounds and hydrogen to the reactor. In addition, B) is carried out by: B1) stopping the supply of aromatic nitro compounds to the reactor such that any remaining aromatic nitro compounds present in the reactor and/or in parts of the installation that are fluidically connected to the reactor upstream react with the hydrogen that is still being supplied to the reactor, and B2) stopping the supply of hydrogen after a predetermined time interval and/or after the concentration of aromatic nitro compounds in the gas flow entering the reactor falls below a predetermined value.

    摘要翻译: 本发明涉及芳香族硝基化合物的氢化制造芳香胺的方法。 该方法包括:A)将芳香族硝基化合物和氢气供给反应器,并与氢化催化剂接触; 和B)停止向反应器供应芳族硝基化合物和氢气。 此外,B)通过以下方式进行:B1)停止向反应器供应芳族硝基化合物,使得存在于反应器中的任何剩余的芳族硝基化合物和/或流体连接到反应器上游的部分设备反应 其中仍然供应到反应器的氢气,以及B2)在预定时间间隔之后和/或在进入反应器的气流中的芳族硝基化合物的浓度之后停止氢气供应降低到预定值以下。

    EMULSION POLYMER CONTAINING COMPOUNDS WITH IMPROVED SURFACE AFTER STORAGE UNDER WARM AND HUMID STORAGE
    59.
    发明申请
    EMULSION POLYMER CONTAINING COMPOUNDS WITH IMPROVED SURFACE AFTER STORAGE UNDER WARM AND HUMID STORAGE 有权
    包含化合物的乳化聚合物在保存温度和湿度储存后储存改进后的表面

    公开(公告)号:US20150065623A1

    公开(公告)日:2015-03-05

    申请号:US14390601

    申请日:2013-03-20

    IPC分类号: C08L69/00 C08F257/02

    摘要: The invention relates to polymer compounds containing A) 0 to 98 parts by weight, based on the sum of A and B, of a thermoplastic polymer, or a mixture of a plurality of thermoplastic polymers differing from B, and B) 2 to I 00 parts by weight, based on the sum of A and B, of B I) at least one graft polymer produced by an emulsion polymerisation process, B2) optionally at least one graft polymer produced in a mass, suspension or solution polymerisation process, B3) optionally at least one rubber-free vinyl (co)polymer and (C) 0 to 30 parts by weight of at least one commercially available polymer additive, wherein the total of parts by weight A and B is 100.

    摘要翻译: 本发明涉及包含A)0至98重量份的聚合物化合物,基于A和B的总和,热塑性聚合物或多种不同于B的热塑性聚合物的混合物,以及B)2至I 00 基于BI的总和A和B的重量份)由乳液聚合方法制备的至少一种接枝聚合物,B2)任选地至少一种以质量,悬浮液或溶液聚合方法生产的接枝聚合物,B3)任选地 至少一种无橡胶的乙烯基(共)聚合物和(C)0至30重量份的至少一种市售聚合物添加剂,其中A和B的重量份数为100。