摘要:
The invention concerns an electrochemical cell with emission controlled by electrodeposition under the action of a control voltage. The cell comprises the following flexible elements, superimposed and respectively in intimate contact: a first electrode (11) intended to be connected to a first potential of the control voltage, a first porous layer (12), formed of a mixture of PVDF-HFP, PEO and an activated carbon powder, a porous separator (13), formed of a mixture of PVDF-HFP and PEO, a second electrode (14) formed of a grid and connected to a second potential of the control voltage, a second porous layer (15), formed of a mixture of PVDF-HFP, PEO and carbon powder, an aqueous electrolytic solution containing a copper salt being contained in the first flexible layer (12), in the separator (13) and in the second flexible layer (15).
摘要:
The invention concerns an electrochemical cell in thin films and aqueous electrolyte, with an emissivity that varies as a function of an applied control voltage. It is formed of the following flexible elements, superimposed and respectively in intimate contact:a first current collector (11) in electrically conducting material and intended to be connected to a first potential of the control voltage,a porous counter electrode (12) formed of a mixture of PVDF-HFP, PEO and a powder of a compound comprising complementary ions of an insertion material,a porous separator (13) formed of a mixture of PVDF-HFP and PEO,a second current collector (14) in electrically conducting material, intended to be connected to a second potential of the control voltage and capable of being traversed by ions,a porous electronic conduction layer (15) formed of a mixture of PVDF-HFP, PEO and a powder of an electrically conducting material,a porous active layer (16) formed of a mixture of PVDF-HFP, PEO and a powder of an insertion material.
摘要:
The invention concerns an electrochemical lithium cell battery (10; 12; 14) comprising at least one positive electrode (5, 6), at least one liquid electrolyte including at least one lithium salt, and at least one negative electrode (1, 2) Said cell battery (10; 12; 14) is characterized in that it comprises at least one layer (3, 13) of a gelled separator (SG) comprising at least one polymer (PG), capable of being gelled by the liquid electrolyte, which is at least partly gelled by the liquid electrolyte, in contact with the negative electrode (1, 2), and in that it comprises at least a layer (4) of a plasticized separator (SP), including at least one polymer (PP) capable of being plasticized by the liquid electrolyte, at least partly in contact with the separator layer (SG). The invention is particularly applicable to hybrid and/or electric vehicles or portable appliances.
摘要:
Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymeric matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要:
A method for preparing an amorphous ternary lithiated vanadium metal oxide of the formula Li.sub.x M.sub.y V.sub.z O.sub.(x+5z+ny)/2, where M is a metal, 0
摘要:
The extent of self-discharge of rechargeable Li-ion secondary batteries is significantly reduced by treatment of LiMn.sub.2 O.sub.4 intercalation compound electrode material with a chelating agent, such as acetylacetone. This treatment decreases the incidence of non-coordinated Mn-ion sites which can lead to battery electrolyte decomposition and resulting loss of battery capacity. The treatment, which also includes annealing at about 400.degree. C. to 800.degree. C., further prevents such decomposition by varying the surface area and topography of the potentially catalytic electrode material.
摘要:
The present invention is a method of fabricating a rechargeable battery structure by extracting plasticizer from plastic battery preforms to render them insensitive to water while maintaining the homogeneous characteristics of the plastic materials to allow subsequent activation of the batteries through the introduction of an electrolyte solution. These battery preforms need not be maintained under anhydrous conditions and can be activated immediately preceding use thereof.
摘要:
Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated to form a unitary battery cell structure. The structure may be stored indefinitely, since it is essentially devoid of electrolyte solution which typically comprises a moisture-sensitive lithium salt. Prior to the battery's being put into service, the plasticizer of the polymeric composition is removed by leaching with a selective solvent and is replaced with a lithium salt electrolyte solution by simple imbibition. The battery thus activated may then be charged and recharged in the usual manner.
摘要:
Lithium intercalation compounds suitable for use in high capacity secondary battery electrodes are prepared by reacting together at a temperature in the range of about 800.degree. to 900.degree. C. lithium and manganese compounds in a stoichiometric ratio resulting in a Li.sub.x Mn.sub.2 O.sub.4 compound wherein x is within the range of about 1.00 to 1.20. The resulting compound is annealed at a temperature in excess of about 800.degree. C. and cooled to at least about 500.degree. C. at the rate less than about 10.degree. C. per hour before being finally cooled to ambient working temperature. Intercalation electrodes comprising these lithiated compounds are used in secondary batteries to yield stable, extended capacities in excess of 110 AHr/Kg.
摘要:
Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译:描述了用于锂二次电池的尖晶石LiMn 2 O 4和层状LiCoO 2相的低温制备方法,这些相是可感兴趣的化合物。 这些相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。