摘要:
Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译:描述了用于锂二次电池的尖晶石LiMn 2 O 4和层状LiCoO 2相的低温制备方法,这些相是可感兴趣的化合物。 这些相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。
摘要:
Method is described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 phase which is an intercalable compound of interest for use in lithium secondary batteries. This phase can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译:描述了用于锂二次电池的尖晶石LiMn 2 O 4相的低温制备方法,该尖晶石LiMn 2 O 4相是可用的化合物。 该相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。
摘要:
A Thin film electrode for a rechargeable (secondary) battery is prepared by electron beam deposition of LiMn.sub.2 O.sub.4, LiCoO.sub.2, or LiNiO.sub.2 on a smooth, amorphous substrate surface and in situ annealing of the deposited lithium composition at a temperature below about 500.degree. C. The amorphous nature of the substrate surface prevents epitaxial growth or ordered orientation of the minute composition crystallites thus formed. The finely granular structure of the resulting electrode thin film presents abundant surface area that enables a 4V battery to provide current densities in the range of 500 microamps/cm.sup.2. The low annealing temperature enables formation of the electrode structure and subsequent battery assembly directly upon semiconductor devices and integrated circuitry.
摘要翻译:通过在光滑的非晶基材表面上电子束沉积LiMn 2 O 4,LiCoO 2或LiNiO 2并在低于约500℃的温度对沉积的锂组合物进行原位退火,制备用于可再充电(二次)电池的薄膜电极。 衬底表面的无定形特性防止由此形成的微小组合物微晶的外延生长或有序取向。 所得电极薄膜的细颗粒结构具有丰富的表面积,使4V电池能够提供500微安/ cm2范围内的电流密度。 低退火温度能够直接在半导体器件和集成电路上形成电极结构和随后的电池组件。
摘要:
Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated with electrically conductive collector elements to form a unitary battery cell structure. Adhesion between the electrode and collector elements is enhanced by pretreatment of the collector elements in which a 0.25% to 3.0% solution of a polymeric material compatible with said matrix polymer is applied to a collector foil or grid and dried to form a coated film, and the resulting coated collector element is heated within the range of about 250.degree. to 450.degree. C. for about 5 to 60 seconds.
摘要:
A cathode slurry for use in a lithium battery, comprised of: about 60% to about 70% by weight manganese dioxide; about 5% to about 10% by weight carbon; and about 25% to about 35% by weight of an electrolyte, said electrolyte comprised of: about 10% to about 40% by weight ethylene carbonate, about 60% to about 90% by weight propylene carbonate, and about 0.5 to about 1.5 moles of triflate salt.
摘要:
A separator for a Li-ion polymer battery comprised of a plurality of separator layers that are laminated together. The plurality of separator layers including a first layer formed of a first separator material, and a second layer formed of a second separator material, wherein the second layer is compositionally and structurally different from the first layer.
摘要:
A Li-ion and/or Li-ion polymer battery, comprised of a plurality of battery cells, each battery cell comprised of at least one cathode section, an anode section and at least one separator layer disposed between the anode section and the at least one cathode section. A first, planar metal mesh layer is disposed within the anode section, the first metal mesh layer having a coplanar tab extending beyond the separator layer to define a negative lead. A second, planar metal mesh layer is disposed within the cathode section, the second metal mesh layer having a coplanar tab extending beyond the separator layer to form a positive lead. A plurality of reinforcing bands are wrapped around the peripheral edges of the battery cells securing the battery cells together.
摘要:
A cathode slurry for use in a lithium battery, comprised of: about 60% to about 70% by weight electrolytic manganese dioxide; about 5% to about 10% by weight carbon; and about 25% to about 35% by weight of an electrolyte, said electrolyte comprised of: about 10% to about 40% by weight ethylene carbonate, about 60% to about 90% by weight propylene carbonate, and about 0.5 to about 1.5 moles of triflate salt.
摘要:
A system for etching superconducting films of yttrium-barium-copper-oxide (YBa.sub.2 Cu.sub.3 O.sub.2) is disclosed. The etchant comprises ethylenediaminetetraacetic acid of varying concentrations in water or a water/glycerol mixture. The described etchant permits superconducting transition temperatures to remain unaffected within the experimental accuracy of 1.degree. C. Additionally, films do not require reoxygenation after etching, and the etchant is suitable for micropatterning using standard photolithography.
摘要:
An IC card comprising an electronic device and a battery within a plastic card for electrically energizing the electronic device. The battery is comprised of a monolithic electrochemical cell having a lithium-containing cathode, a carbon anode, and a porous polymer separator infused with electrolyte solution. The cell has a thickness of less than 0.7 mm. A package containing the cell formed of a sheet of flexible laminate material having at least one metal foil layer and a layer of an adhesive-like polymeric material. The battery has an overall thickness of less than 0.8 mm.