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    Process for producing fluoropropenes
    56.
    发明授权
    Process for producing fluoropropenes 有权
    制备氟丙烯的方法

    公开(公告)号：US08034984B2

    公开(公告)日：2011-10-11

    申请号：US12887739

    申请日：2010-09-22

    申请人： Daniel C. Merkel ,  Rajiv R. Singh ,  Hsueh S. Tung

    发明人： Daniel C. Merkel ,  Rajiv R. Singh ,  Hsueh S. Tung

    IPC分类号： C07C17/00

    CPC分类号： C07C21/18 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C19/08

    摘要： Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.

    摘要翻译： 用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法，其中氟丙烯具有式CF 3C≡≡CXNHP，其中X和Y独立地是氢或选自氟，氯，溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数，条件是（N + P）= 2。

    COMPOSITIONS CONTAINING SULFUR HEXAFLUORIDE AND USES THEREOF
    59.
    发明申请
    COMPOSITIONS CONTAINING SULFUR HEXAFLUORIDE AND USES THEREOF 有权
    含有硫化氢的组合物及其用途

    公开(公告)号：US20100171062A1

    公开(公告)日：2010-07-08

    申请号：US12728371

    申请日：2010-03-22

    申请人： Matthew H. Luly ,  Rajiv R. Singh ,  Robert G. Richard

    发明人： Matthew H. Luly ,  Rajiv R. Singh ,  Robert G. Richard

    IPC分类号： H02H99/00 ,  H01B3/16 ,  H05K5/06 ,  A62D1/00

    CPC分类号： H01B3/16 ,  A62C99/0018 ,  H01H2033/566

    摘要： A method for suppressing an electric arc or corona discharge includes providing a device capable of storing, transmitting, or generating an electrical current or field; and enveloping at least a portion of said device with a dielectric gas consisting essentially of: sulfur hexafluoride; a second component selected from the group consisting of nitrous oxide; carbon dioxide; trifluoromethane (R32); trifluoroiodomethane; octafluoropropane (R218); 1,1,1,2,2-pentafluoroethane (R125); propane (R290); 1,1,1,2-tetrafluoropropene (HFO-1234yf); 1,2,3,3-tetrafluoro-2-propene (HFO-1234yc); 1,1,3,3-tetrafluoro-2-propene (HFO-1234zc); 1,1,1,3-tetrafluoro-2-propene (HFO-1234ze); 1,1,2,3-tetrafluoro-2-propene (HFO-1234ye); 1,1,1,2,3-pentafluoropropene (HFO-1225ye); 1,1,2,3,3-pentafluoropropene (HFO-1225yc); 1,1,1,3,3-pentafluoropropene (HFO-1225zc); (Z)1,1,1,3-tetrafluoropropene (HFO-1234zeZ); (Z)1,1,2,3-tetrafluoro-2-propene (HFO-1234yeZ); (E)1,1,1,3-tetrafluoropropene (HFO-1234zeE); (E)1,1,2,3-tetrafluoro-2-propene (HFO-1234yeE); (Z)1,1,1,2,3-pentafluoropropene (HFO-1225yeZ); (E)1,1,1,2,3-pentafluoropropene (HFO-1225yeE) and combinations of two or more of these; and optionally, an additive selected from the group consisting of stabilizers, metal passivators, corrosion inhibitors, and lubricants.

    摘要翻译： 抑制电弧或电晕放电的方法包括提供能够存储，传输或产生电流或场的装置; 以及用基本上由六氟化硫组成的介电气体包封所述装置的至少一部分; 选自由一氧化二氮组成的组的第二组分; 二氧化碳; 三氟甲烷（R32）; 三氟碘甲烷 八氟丙烷（R218）; 1,1,1,2,2-五氟乙烷（R125）; 丙烷（R290）; 1,1,1,2-四氟丙烯（HFO-1234yf）; 1,2,3,5-四氟-2-丙烯（HFO-1234yc）; 1,1,3,3-四氟-2-丙烯（HFO-1234zc）; 1,1,1,3-四氟-2-丙烯（HFO-1234ze）; 1,1,2,3-四氟-2-丙烯（HFO-1234ye）; 1,1,1,2,3-五氟丙烯（HFO-1225ye）; 1,1,2,3,3-五氟丙烯（HFO-1225yc）; 1,1,1,3,3-五氟丙烯（HFO-1225zc）; （Z）1,1,1,3-四氟丙烯（HFO-1234zeZ）; （Z）1,1,2,3-四氟-2-丙烯（HFO-1234yeZ）; （E）1,1,1,3-四氟丙烯（HFO-1234zeE）; （E）1,1,2,3-四氟-2-丙烯（HFO-1234yeE）; （Z）1,1,1,2,3-五氟丙烯（HFO-1225yeZ）; （E）1,1,1,2,3-五氟丙烯（HFO-1225yeE）及其两种或多种的组合; 和任选的选自稳定剂，金属钝化剂，腐蚀抑制剂和润滑剂的添加剂。

    Chloro- And Bromo-Fluoro Olefin Compounds Useful As Organic Rankine Cycle Working Fluids
    60.
    发明申请
    Chloro- And Bromo-Fluoro Olefin Compounds Useful As Organic Rankine Cycle Working Fluids 有权
    氯和氟氟烯烃化合物可用作有机兰金循环工作液

    公开(公告)号：US20100139274A1

    公开(公告)日：2010-06-10

    申请号：US12630647

    申请日：2009-12-03

    申请人： Gary Zyhowski ,  Ryan Hulse ,  Haridasan K. Nair ,  David Nalewajek ,  Rajiv R. Singh

    发明人： Gary Zyhowski ,  Ryan Hulse ,  Haridasan K. Nair ,  David Nalewajek ,  Rajiv R. Singh

    IPC分类号： F01K25/08 ,  F01K23/02 ,  F01K23/08 ,  C07C21/18

    CPC分类号： C09K5/048 ,  C07B2200/09 ,  C07C21/18 ,  C09K5/045 ,  C09K2205/126 ,  F01K25/06 ,  F01K25/08

    摘要： Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.

    摘要翻译： 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。 本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。