Abstract:
A method for pre-doping a lithium ion capacitor, including: compressing a lithium ion capacitor of the formula: C/S/A/S/C/S/A/S/C, where: /A/ is an anode coated on both sides with an anode carbon layer, and each anode carbon layer is further coated with lithium composite powder (LCP) layer; C/ is a cathode coated on one side with a layer of an cathode carbon mixture; and S is a separator; and a non-aqueous electrolyte; and conditioning the resulting compressed lithium ion capacitor, for example, at a rate of from C/20 to 4C, and the conditioning redistributes the impregnated lithium as lithium ions in the anode carbon structure. Also disclosed is an carbon coated anode having lithium composite powder (LCP) layer compressed on the carbon coated anode.
Abstract:
An electrode in an energy storage device, including: an activated carbon, including: a surface area of from 1000 to 1700 m2/g; a pore volume from 0.3 to 0.6 cc/g; a chemically bonded oxygen content of 0.01 to 1.5 wt %; and a pH of from 7.5 to 10. Also disclosed is a method of making the activated carbon, the electrode, and the energy storage device.
Abstract:
An electrode in an energy storage device, including: an activated carbon, including: a surface area of from 1000 to 1700 m2/g; a pore volume from 0.3 to 0.6 cc/g; a chemically bonded oxygen content of 0.01 to 1.5 wt %; and a pH of from 7.5 to 10. Also disclosed is a method of making the activated carbon, the electrode, and the energy storage device.
Abstract:
An anode in a lithium ion capacitor, including: a carbon composition comprising: a coconut shell sourced carbon in from 85 to 95 wt %; a conductive carbon in from 1 to 10 wt %; and a binder in from 3 to 8 wt %; and an electrically conductive substrate, wherein the coconut shell sourced carbon has a disorder (D) peak to graphitic (G) peak intensity ratio by Raman analysis of from 1.40 to 1.85; and by elemental analysis a hydrogen content of from 0.01 to 0.25 wt %; a nitrogen content of from 0.01 to 0.55 wt %; and an oxygen content of from 0.01 to 2 wt %. Also disclosed are methods of making and using the carbon composition.
Abstract:
An energy storage device such as an electric double layer capacitor has positive and negative electrodes, each including a blend of respective first and second activated carbon materials having distinct pore size distributions. The blend (mixture) of first and second activated carbon materials may be equal in each electrode.
Abstract:
A method of making activated carbon including: compressing a mixture of an alkali metal hydroxide, a carbon source, and a solid thermosetting polymer precursor into a pellet; and a first heating of the compressed mixture, as defined herein; and optionally crushing, washing, or both, the resulting first heated mixture, as defined herein; and optionally a second heating, as defined herein.
Abstract:
A lithium ion capacitor, including: an anode including: a conductive support; a first mixture coated on the conductive support including: a carbon sourced from coconut shell flour; a conductive carbon black; and a PVDF binder in amounts as defined herein, and where the PVDF binder has a weight average molecular weight of from 300,000 to 400,000; and a second mixture coated on the first mixture, the second mixture comprising micron-sized lithium metal particles having an encapsulating shell comprised of LiPF6, mineral oil, and a thermoplastic binder. Also disclosed is a method of making and using the lithium ion capacitor.
Abstract:
A non-activated, majority non-graphitic amorphous carbon material may be produced by supplying a carbonized precursor material, heating the carbonized precursor material in a first heating step at a temperature and for a duration sufficient to produce a heat-treated carbon material that has a specific surface area less than about 500 m2/g and is less than about 20% graphitic by mass, purifying the heat-treated carbon material, and heating the purified heat-treated carbon material in a second heating step at a temperature and for a duration to produce a non-activated, majority non-graphitic amorphous carbon material that has a specific surface area less than about 500 m2/g and is less than about 20% graphitic by mass.
Abstract:
A method of forming an electrolyte solution involves combining ammonium tetrafluoroborate and a quaternary ammonium halide in a liquid solvent to form a quaternary ammonium tetrafluoroborate and an ammonium halide. The ammonium halide precipitate is removed from the solvent to form an electrolyte solution. The reactants can be added step-wise to the solvent, and the method can include using a stoichiometric excess of the ammonium tetrafluoroborate to form a substantially halide ion-free electrolyte solution.
Abstract:
A sorbent structure that includes a continuous body in the form of a flow-through substrate comprised of at least one cell defined by at least one porous wall. The continuous body comprises a sorbent material carbon substantially dispersed within the body. Further, the temperature of the sorbent structure can be controlled by conduction of an electrical current through the body.