公开(公告)号：US10358506B2

公开(公告)日：2019-07-23

申请号：US15723225

申请日：2017-10-03

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Randall S. Muninger ,  Qing Yang ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/6192 ,  C08F4/64 ,  C08F10/02 ,  C08F4/659

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190° C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102° C., and a low temperature peak from 18 to 36° C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.

公开(公告)号：US09718907B2

公开(公告)日：2017-08-01

申请号：US15194622

申请日：2016-06-28

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Youlu Yu ,  Qing Yang ,  Richard M. Buck

IPC: C08F4/00 ,  C08F210/00 ,  C08F10/00 ,  C08F10/14 ,  C08F110/02 ,  C08F210/02 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/02 ,  C08F4/65912 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.

公开(公告)号：US20170145123A1

公开(公告)日：2017-05-25

申请号：US15428183

申请日：2017-02-09

Applicant: Chevron Phillips Chemical Company LP

Inventor： Ashish M. Sukhadia ,  Max P. McDaniel ,  Errun Ding ,  Guylaine St. Jean ,  Qing Yang ,  Daniel G. Hert ,  Chung Ching Tso

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08F2410/02 ,  C08F2420/01 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/26

Abstract: Disclosed herein are ethylene-based polymers produced using dual metallocene catalyst systems. These polymers have low densities, high molecular weights, and broad molecular weight distributions, as well as having the majority of the long chain branches in the lower molecular weight component of the polymer, and the majority of the short chain branches in the higher molecular weight component of the polymer. Films produced from these polymers have improved impact and puncture resistance.

公开(公告)号：US20160304644A1

公开(公告)日：2016-10-20

申请号：US15193195

申请日：2016-06-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish M. Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09273159B2

公开(公告)日：2016-03-01

申请号：US14493384

申请日：2014-09-23

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/642 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/76 ,  C08F4/659 ,  C08F10/02 ,  C08F10/00 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。

公开(公告)号：US20150175726A1

公开(公告)日：2015-06-25

申请号：US14639582

申请日：2015-03-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/16 ,  C08J5/18

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

Abstract translation: 本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。 这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。

公开(公告)号：US08829125B2

公开(公告)日：2014-09-09

申请号：US13927165

申请日：2013-06-26

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Albert P. Masino ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/00 ,  C08F4/06 ,  C08F4/12 ,  C08F2/00 ,  C08F210/00 ,  C08F210/16 ,  C08F10/00 ,  C08F110/02

CPC classification number: C08F210/16 ,  C08F10/00 ,  C08F110/02 ,  C08F2400/02 ,  C08F2/00 ,  C08F2/42 ,  C08F2500/04 ,  C08F2500/12

Abstract: Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.

Abstract translation: 公开了使用协同量的氢和有机锌化合物控制聚合反应的方法。 所得聚合物具有较低的分子量和较高的熔体流动指数。

公开(公告)号：US20140088274A1

公开(公告)日：2014-03-27

申请号：US13625898

申请日：2012-09-25

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP

Inventor： Errun Ding ,  Qing Yang ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/76 ,  C08F2/00

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。

公开(公告)号：US20130289226A1

公开(公告)日：2013-10-31

申请号：US13927165

申请日：2013-06-26

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Albert P. Masino ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F10/00 ,  C08F110/02 ,  C08F2400/02 ,  C08F2/00 ,  C08F2/42 ,  C08F2500/04 ,  C08F2500/12

Abstract: Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.

公开(公告)号：US08450436B2

公开(公告)日：2013-05-28

申请号：US13681443

申请日：2012-11-20

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Rex E. Murray ,  Qing Yang ,  Steve J. Secora ,  Kumudini C. Jayaratne ,  William B. Beaulieu ,  Errun Ding ,  Gary L. Glass ,  Alan L. Solenberger ,  Ted H. Cymbaluk

IPC: C08F4/642 ,  C08F4/643 ,  C08F4/6592 ,  B01J31/22

CPC classification number: C08F4/642 ,  C08F4/12 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

Abstract: The present invention provides dual catalyst systems and polymerization processes employing these dual catalyst systems. The disclosed polymerization processes can produce olefin polymers at higher production rates, and these olefin polymers may have a higher molecular weight and/or a lower melt index.