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公开(公告)号：US5294330A
公开(公告)日：1994-03-15
申请号：US929065
申请日：1992-08-12
申请人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Hye Kyung C. Timken
发明人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Hye Kyung C. Timken
CPC分类号： C10G47/16
摘要： There is provided a hydrocracking process with a catalyst comprising MCM-36.
摘要翻译： 提供了含有MCM-36的催化剂的加氢裂化方法。
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公开(公告)号：US5258566A
公开(公告)日：1993-11-02
申请号：US878277
申请日：1992-05-04
CPC分类号： C07C2/861 , C07C2/66 , C07C2/864 , C07C2521/04 , C07C2521/08 , C07C2529/70
摘要： Long chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a long chain alkylating agent in the presence of catalyst comprising a synthetic porous MCM-36 material.
摘要翻译： 长链烷基芳族化合物是通过在含有合成多孔MCM-36材料的催化剂存在下，用长链烷基化剂烷基化可烷基化芳族化合物来制备的。
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公开(公告)号：US5258565A
公开(公告)日：1993-11-02
申请号：US878111
申请日：1992-05-04
CPC分类号： C07C2/861 , C07C2/66 , C07C2/864 , C07C2521/04 , C07C2521/08 , C07C2529/70
摘要： Short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a short chain alkylating agent in the presence of catalyst comprising a synthetic porous MCM-36 material.
摘要翻译： 短链烷基芳族化合物通过在包含合成多孔MCM-36材料的催化剂存在下，用短链烷基化剂烷基化可烷基化芳族化合物来制备。
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54.发明授权Use of amphiphilic compounds to produce novel classes of crystalline oxide materials 失效使用两亲性化合物来生产新型的结晶氧化物材料
公开(公告)号：US5250282A
公开(公告)日：1993-10-05
申请号：US967962
申请日：1992-10-27
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/34
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/041 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a process for using amphiphilic compounds in preparing new classes of crystalline oxide materials. These oxide materials may have uniformly large pores, e.g., having a size of about 40 Angstoms in diameter. This process involves combining sources of oxides with micellar solutions of organic amphiphilic compounds, such as quaternary ammonium cationic surfactants. Aggregates of these micelles in the form of liquid crystals are believed to function as templates for the formation of the present highly porous, crystalline materials.
摘要翻译： 提供了一种在制备新类型的结晶氧化物材料中使用两亲性化合物的方法。 这些氧化物材料可以具有均匀的大孔，例如具有直径约40埃的尺寸。 该方法包括将氧化物源与有机两亲性化合物的胶束溶液结合，例如季铵阳离子表面活性剂。 认为这些胶体形式的胶束的聚集体用作形成本发明高度多孔的结晶材料的模板。
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公开(公告)号：US5238676A
公开(公告)日：1993-08-24
申请号：US735226
申请日：1991-07-24
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G11/05 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/223 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： This invention relates to a method for modifying a synthetic composition of ultra-large pore crystalline material, e.g., silicate, comprising an inorganic, porous, non-layered crystalline phase material exhibiting, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 18 Angstrom Units and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 6.7 kPa (50 torr) and 25.degree. C., by contacting with a treatment composition comprising an inorganic oxide of a trivalent element X, e.g., sodium aluminate, or precursor of said inorganic oxide, under sufficient conditions so that the trivalent element X is incorporated in the crystalline phase material. The composition is suited to use for catalytic conversion of organic compounds or as a sorbent.
摘要翻译： 本发明涉及一种用于改性超大孔结晶材料（例如硅酸盐）的合成组合物的方法，该方法包括无机，多孔，非层状结晶相材料，其在煅烧后表现出具有至少一种 在d =间距大于18埃的单位峰，并且在6.7kPa（50托）和25℃下，每100克所述材料的苯吸附能力大于15克苯，通过与含有 三价元素X的无机氧化物，例如铝酸钠或所述无机氧化物的前体，在足够的条件下使得三价元素X掺入结晶相材料中。 该组合物适用于有机化合物或吸附剂的催化转化。
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公开(公告)号：US5174888A
公开(公告)日：1992-12-29
申请号：US783473
申请日：1991-10-28
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C01B37/00 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： A process is provided for effecting catalytic conversion of an organic compound-containing feedstock to conversion product which comprises contacting said feedstock under catalytic conversion conditions with a catalyst comprising an active form of an inorganic, non-pillared crystalline phase exhibiting, after calcination, an X-ray diffraction pattern with at least one peak at a position greater than about 18 Angstrom Units d-spacing with a relative intensity of 100, and a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams crystal at 50 torr and 25.degree. C.
摘要翻译： 提供了一种用于将含有机化合物的原料催化转化成转化产物的方法，其包括在催化转化条件下使所述原料与包含活性形式的无机非柱状结晶相的催化剂接触，所述催化剂在煅烧后显示出X 在大于约18埃的位置处具有至少一个峰的阵列衍射图，相对强度为100的d-间距，以及在50托和25度下每100克晶体的苯吸附能力大于约15克苯 C。
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58.发明授权Sulfated layered titanium oxide catalysts in process for preparing long chain alkyl aromatic compounds 失效硫酸盐层状氧化钛催化剂在制备长链烷基芳族化合物的过程中
公开(公告)号：US5105042A
公开(公告)日：1992-04-14
申请号：US617455
申请日：1990-11-21
IPC分类号： B01J21/06 , B01J27/053 , B01J29/04 , C07C2/66 , C07C15/02
CPC分类号： B01J29/049 , B01J21/06 , B01J21/063 , B01J27/053 , C07C2/66 , C07C2521/06 , C07C2521/08
摘要： There is provided a sulfated layered titanium oxide catalyst. Relatively long chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively long chain alkylating agent under alkylation reaction conditions in the presence of this sulfated layered material as alkylation catalyst. The layered material contains titanium oxide in the layers and oxide pillars separating the layers. The alkylation activity of the catalyst is increased by including sulfate ions in the layered material. This increased alkylation activity may be obtained by contacting the layered material with an aqueous solution of a sulfate compound such as sulfuric acid.
摘要翻译： 提供硫酸化层状氧化钛催化剂。 在烷基化反应条件下，在烷基化催化剂存在下，通过使烷基化芳族化合物与较长链烷基化剂在烷基化反应条件下进行烷基化来制备相对长链烷基芳族化合物。 层状材料在层中含有氧化钛和分离层的氧化物柱。 催化剂的烷基化活性通过在层状材料中包含硫酸根离子而增加。 这种增加的烷基化活性可以通过使层状材料与硫酸化合物如硫酸的水溶液接触而获得。
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公开(公告)号：US5102643A
公开(公告)日：1992-04-07
申请号：US470008
申请日：1990-01-25
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/10 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/10 , B01D53/8628 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/16 , B01J20/223 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , Y10S423/30
摘要： This invention relates to a new synthetic composition of ultra-large pore crystalline material, a method for its preparation and use thereof as sorbent and in catalytic conversion of organic compounds. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams anhydrous crystal at 50 torr and 25.degree. C.
摘要翻译： 本发明涉及一种新的超大孔结晶材料的合成组合物，其制备方法和用作吸附剂以及有机化合物的催化转化。 新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克无水晶体。
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公开(公告)号：US5098684A
公开(公告)日：1992-03-24
申请号：US625245
申请日：1990-12-10
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/10 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/10 , B01D53/8628 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/16 , B01J20/223 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , Y10S423/30
摘要： This invention relates to a new synthetic composition of ultra-large pore crystalline material and use thereof as sorbent and in catalytic conversion of organic and inorganic compounds. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units.
摘要翻译： 本发明涉及一种超大孔结晶材料的新型合成组合物及其作为吸附剂的用途以及有机和无机化合物的催化转化。 新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。
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