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公开(公告)号:US4287366A
公开(公告)日:1981-09-01
申请号:US128712
申请日:1980-03-10
IPC分类号: C07C315/02 , C07C317/22 , C07C147/10
CPC分类号: C07C315/02
摘要: A process for preparing bisphenol sulfone derivatives represented by the general formula (I) ##STR1## where R stands for hydrogen, a halogen, an alkyl radical, a cycloalkyl radical, an aryl radical, an aralkyl radical, hydroxyl group, an alkoxy radical, allyloxy group, carboxyl group, or a carboalkoxy radical, m is an integer of from 1 to 3, and when m is 2 or more, R may be identical to or different from each other, and adjacent Rs may be combined to form a ring, by oxidizing with hydrogen peroxide a compound represented by the general formula (II) ##STR2## where R and m have the same meanings as defined for the formula (I), and n is zero or 1, in the presence of an alkali in an amount more than the equimolar amount thereof relative to said compound in water and/or an organic solvent which do not form any organic peracids under reaction conditions.
摘要翻译: 一种制备由通式(I)表示的双酚砜衍生物的方法,其中R代表氢,卤素,烷基,环烷基,芳基,芳烷基,羟基, 烷氧基,烯丙氧基,羧基或烷氧羰基,m为1〜3的整数,当m为2以上时,R可以相同也可以不同,相邻的Rs可以组合成 形成环,通过用过氧化氢氧化由通式(II)表示的化合物(II)其中R和m具有与式(I)所定义相同的含义,并且n为0或1,在 在水和/或在反应条件下不形成任何有机过酸的有机溶剂中,相对于所述化合物,碱的存在量超过等摩尔量。
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公开(公告)号:US5798422A
公开(公告)日:1998-08-25
申请号:US511809
申请日:1995-08-07
IPC分类号: B41M5/155 , C07C65/105 , C07C65/24 , C08G61/02 , C08L63/00 , G03F7/023 , C08F6/00 , C08F6/02
CPC分类号: G03F7/0236 , B41M5/155 , C07C65/105 , C07C65/24 , C08G61/02 , C08L63/00 , G03F7/0233
摘要: Disclosed are an aromatic hydroxycarboxylic acid resin represented by the following formula (1): ##STR1## wherein each A group is the same or different and individually represents a substituted or unsubstituted phenylene or naphthylene group, R.sup.1 represents a hydrogen atom or a C.sub.1-4 alkyl group, R.sup.2 represents a hydrogen atom or a C.sub.1-10 alkyl, C.sub.1-10 alkoxyl, nitro or hydroxyl group, l stands for an integer of 0-100, m stands for an integer of 0-20 and n stands for an integer of 0-3 with the proviso that m stands for an integer other than 0 when all of the A group represent an unsubstituted or substituted a group, a preparation process thereof and use of the same.
摘要翻译: 公开了由下式(1)表示的芳族羟基羧酸树脂:其中每个A基团相同或不同,并且各自表示取代或未取代的亚苯基或亚萘基 R 1表示氢原子或C 1-4烷基,R 2表示氢原子或C 1-10烷基,C 1-10烷氧基,硝基或羟基,l表示0〜100的整数,m表示 0〜20的整数,n表示0-3的整数,条件是当A组全部为未取代或取代的基团时,m表示0以外的整数,其制备方法及其用途 。
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公开(公告)号:US5484880A
公开(公告)日:1996-01-16
申请号:US354806
申请日:1994-12-13
申请人: Wataru Yamashita , Yuichi Okawa , Shoji Tamai , Mitsunori Matsuo , Tsutomu Ishida , Keizaburo Yamaguchi , Akihiro Yamaguchi
发明人: Wataru Yamashita , Yuichi Okawa , Shoji Tamai , Mitsunori Matsuo , Tsutomu Ishida , Keizaburo Yamaguchi , Akihiro Yamaguchi
IPC分类号: C07C225/22 , C07B61/00 , C07C221/00 , C08G73/10 , C08L79/08 , C08G77/10 , C08G69/26
CPC分类号: C08G73/1071 , C08G73/1014 , C08G73/105 , C08G73/1064 , C08L79/08
摘要: The present invention relates to an amorphous polyimide or a polyimide copolymer having a requisite structural unit consisting of one or more recurring structural units represented by the formula (1): ##STR1## wherein X is a direct bond, oxygen atom or sulfur atom, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are individually a hydrogen atom or methyl, and Ar is a tetravalent radical having 6 to 27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed polyaromatic radical having aromatic radicals connected to each other with a direct bond or a bridge member.Polyimide and the polyimide copolymer of the invention has excellent heat resistance, is outstanding in melt-flow stability, has greatly improved processability, and can be applied to structural materials, and electric- electronic appliances.
摘要翻译: 本发明涉及具有必要结构单元的无定形聚酰亚胺或聚酰亚胺共聚物,所述结构单元由一个或多个由式(1)表示的重复结构单元:原子或硫原子组成,并且R 1,R 2,R 3和R 4分别为 氢原子或甲基,Ar是具有6至27个碳原子的四价基团,并且选自具有芳族基团的单芳族基团,缩合多芳族基团和具有直接键或桥键的彼此连接的非缩合多芳族基团 会员。 本发明的聚酰亚胺和聚酰亚胺共聚物具有优异的耐热性,熔体流动稳定性优异,加工性能大大提高,可应用于结构材料和电子电器。
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公开(公告)号:US5354839A
公开(公告)日:1994-10-11
申请号:US40608
申请日:1993-03-31
申请人: Wataru Yamashita , Yoshihiro Sakata , Toshiyuki Kataoka , Yuichi Okawa , Hideaki Oikawa , Tadashi Asanuma , Mitsunori Matsuo , Tsutomu Ishida , Keizaburo Yamaguchi , Akihiro Yamaguchi
发明人: Wataru Yamashita , Yoshihiro Sakata , Toshiyuki Kataoka , Yuichi Okawa , Hideaki Oikawa , Tadashi Asanuma , Mitsunori Matsuo , Tsutomu Ishida , Keizaburo Yamaguchi , Akihiro Yamaguchi
IPC分类号: C07C217/90 , C08G73/10 , H05K1/00 , H05K1/03 , C08G69/26
CPC分类号: C08G73/105 , C07C217/90 , C08G73/10 , C08G73/1014 , C08G73/1017 , H05K1/0346 , H05K3/4676
摘要: A polyimide comprising a requisite structural unit having one or more recurring structural units of the formula: ##STR1## such as the structural units of the formula ##STR2## The polyimide can have an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance, and also provides an aromatic diamine which is useful as a raw material monomer of the polyimide or a raw material of other various engineering plastics.
摘要翻译: 一种聚酰亚胺,其包含具有一个或多个下式的重复结构单元的必需结构单元:例如下式的结构单元:该聚酰亚胺可以具有极低的介电常数,为无色透明且加工性优异 和耐热性,并且还提供可用作聚酰亚胺的原料单体或其它各种工程塑料的原料的芳族二胺。
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公开(公告)号:US5260388A
公开(公告)日:1993-11-09
申请号:US894940
申请日:1992-06-08
申请人: Shoji Tamai , Wataru Yamashita , Yuichi Okawa , Yuko Ishihara , Keizaburo Yamaguchi , Akihiro Yamaguchi
发明人: Shoji Tamai , Wataru Yamashita , Yuichi Okawa , Yuko Ishihara , Keizaburo Yamaguchi , Akihiro Yamaguchi
IPC分类号: C07C225/22 , C08G73/10 , C08G73/14 , C08G8/02 , C08G69/26
CPC分类号: C07C225/22 , C08G73/1014 , C08G73/1017 , C08G73/1039 , C08G73/1067 , C08G73/14
摘要: A heat-resistant and thermoplastic polyimide which has low dielectric characteristics and recurring structural units of the following formula ##STR1## wherein R is a tetravalent radical having from 2 to 27 carbon atoms and selected from the group consisting of an aliphatic radical, alicyclic radical, monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected each other with a direct bond or a bridge member; aromatic diamines which are useful for the raw material monomers of the polyimide and have following formulas: ##STR2## and ##STR3## and a process for preparing the polyimide of the above formula by reacting these aromatic diamines with a tetracarboxylic dianhydride in the presence of an aromatic dicarboxylic anhydride or aromatic monoamine, and successively thermally or chemically imidizing the resultant polyamic acid.
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公开(公告)号:US4987261A
公开(公告)日:1991-01-22
申请号:US393797
申请日:1989-08-15
IPC分类号: C08K5/18 , C07C67/00 , C07C209/00 , C07C209/36 , C07C211/60 , C08K5/17
CPC分类号: C07C211/60 , C07C2102/08
摘要: The invention relates to diaminoindane derivatives represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.2 are each selected from the group consisting of a hydrogen atom and a lower alkyl group having from 1 to 4 carbon atoms, and a process for preparing same.
摘要翻译: 本发明涉及由下式表示的二氨基茚满衍生物及其制备方法:其中R 1和R 2各自选自氢原子和具有1至4个碳原子的低级烷基。
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公开(公告)号:US4407892A
公开(公告)日:1983-10-04
申请号:US400016
申请日:1982-07-20
CPC分类号: B41M5/3375 , B41M5/3336 , Y10S428/913 , Y10S428/914
摘要: Heat sensitive recording sheet having improved light resistance and water resistance. A developer contained therein is one or more specified metal salts of 2,2'-bisphenolsulfide, 2,2'-bisphenolsulfoxide and 2,2'-bisphenolsulfone compounds. The heat sensitive recording sheet can further contain a heat fusible material having a melting point of 50.degree. to 190.degree. C.
摘要翻译: 具有改善的耐光性和耐水性的热敏记录纸。 其中所含的显影剂是2,2'-双酚硫醚,2,2'-双酚亚砜和2,2'-双酚砜化合物的一种或多种特定的金属盐。 热敏记录片材还可以含有熔点为50〜190℃的热熔材料。
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公开(公告)号:US4312522A
公开(公告)日:1982-01-26
申请号:US177999
申请日:1980-08-14
CPC分类号: B41M5/3336 , Y10S428/913 , Y10S428/914
摘要: This invention discloses a heat sensitive recording sheet which contains, as a developer, at least one of the compounds represented by the general formula ##STR1## where R represents hydrogen, an alkyl radical of from 1 to 12 carbon atoms, a cycloalkyl radical of from 3 to 10 carbon atoms, an aralkyl radical of from 7 to 10 carbon atoms, and a phenyl radical, and may be identical to or different from each other, n is zero, or an integer of 1 or 2.The heat sensitive recording sheet of this invention has a sharper rise in developed color density and is advantageous for its handling and storage as well as gives a developed color image having an excellent fastness to light and water resistance in addition to very little decrease in density of the developed color image with time.
摘要翻译: 本发明公开了一种热敏记录片材,其包含作为显影剂的至少一种由通式“IMAGE”表示的化合物,其中R表示氢,1至12个碳原子的烷基, 3至10个碳原子,7至10个碳原子的芳烷基和苯基,并且可以彼此相同或不同,n为零或1或2的整数。热敏记录片材 本发明的显色浓度明显提高,并且其处理和储存有利,并且除了显影的彩色图像的密度几乎没有降低之外,还提供了具有优异的耐光和耐水牢度的显影彩色图像 时间。
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