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    Polyimide resin composition
    2.
    发明授权
    Polyimide resin composition 失效
    聚酰亚胺树脂组合物

    公开(公告)号：US5494996A

    公开(公告)日：1996-02-27

    申请号：US277568

    申请日：1994-07-20

    申请人： Shoji Tamai ,  Yuichi Okawa ,  Wataru Yamashita ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Keizaburo Yamaguchi ,  Tadashi Asanuma ,  Akihiro Yamaguchi ,  Mitsunori Matsuo

    发明人： Shoji Tamai ,  Yuichi Okawa ,  Wataru Yamashita ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Keizaburo Yamaguchi ,  Tadashi Asanuma ,  Akihiro Yamaguchi ,  Mitsunori Matsuo

    IPC分类号： C08L71/10 ,  C08G73/10 ,  C08L71/08 ,  C08L79/04 ,  C08L79/08

    CPC分类号： C08L79/08 ,  C08L79/04

    摘要： A polyimide resin composition substantially comprising 1 99.9.about.50 parts by weight of polyimide having recurring structural units of the formula ##STR1## and 2 0.1.about.50 parts by weight of a polyimide which improved melt flowability and is prepared by using 1,3-bis(3-aminophenoxy)benzene or 6,6'-bis(3-aminophenoxy)-3,3,3',3'-tetramethyl-1,1'-spirobiindane as essential diamine component, or polyether pyridine having recurring structural units of the formula: ##STR2## is disclosed. Further, a polyimide based resin composition comprising the polyimide resin composition or a polyimide copolymer obtained by using the above diamines and a fibrous reinforcement is disclosed. These compositions have remarkably good processability, excellent heat stability and repeated fatigue characteristics.

    摘要翻译： 一种聚酰亚胺树脂组合物，其基本上包含+ E，crc / 1 / 99.9差异50重量份具有式（1）的重复结构单元的聚酰亚胺和+ E，crc / 2 / 0.1差异50重量份的 通过使用1,3-双（3-氨基苯氧基）苯或6,6'-双（3-氨基苯氧基）-3,3,3'，3'-四甲基-1,1' - 螺环丁烷作为必需二胺组分，或具有下式重复结构单元的聚醚吡啶：。 此外，公开了一种聚酰亚胺系树脂组合物，其包含使用上述二胺和纤维增强剂而得到的聚酰亚胺树脂组合物或聚酰亚胺共聚物。 这些组合物具有非常好的加工性能，优异的热稳定性和重复的疲劳特性。

    Readily soluble, amorphous polyimide, and preparation process of same
    3.
    发明授权
    Readily soluble, amorphous polyimide, and preparation process of same 失效
    易溶，无定形聚酰亚胺及其制备方法相同

    公开(公告)号：US5480965A

    公开(公告)日：1996-01-02

    申请号：US280551

    申请日：1994-07-26

    申请人： Wataru Yamashita ,  Yuichi Okawa ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Yuko Ishihara ,  Mitsunori Matsuo ,  Keizaburo Yamaguchi ,  Akihiro Yamaguchi ,  Shoji Tamai

    发明人： Wataru Yamashita ,  Yuichi Okawa ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Yuko Ishihara ,  Mitsunori Matsuo ,  Keizaburo Yamaguchi ,  Akihiro Yamaguchi ,  Shoji Tamai

    IPC分类号： C07C201/12 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C08G73/10 ,  C08G73/12 ,  C08J5/18 ,  C08L79/08 ,  C08G69/26 ,  C08L77/00

    CPC分类号： C08G73/10 ,  C08G73/1007 ,  C08G73/1014 ,  C08G73/1017 ,  C08G73/1067 ,  Y10T428/31504 ,  Y10T428/31721

    摘要： This invention relates to a novel thermoplastic and amorphous polyimide which is readily soluble in organic solvent, a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the thermoplastic polyimide and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition, a polyimide-based composite obtained by molding the above soluble and thermoplastic polyimide in combination with a fibrous reinforcement, and a fibrous reinforcement having a surface modified with the above polyimide.The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein m and n are individually an integer of 0 or 1, and R is ##STR2## The polyimide of the invention is essentially amorphous, excellent in melt flow stability in the decreased temperature as compared with conventionally known polyimide and has greatly improved processability.The polyimide of the invention obtained by using a novel aromatic diamino compound as a monomer can control various properties such as melt flow ability and solubility in solvents by side chains and not by principal chain of polyimide. Thus, excellent melt flow property and solubility in solvents can be obtained while maintaining high heat resistance and adhesive property which are derived from benzophenone structure of the diamino compound of the the invention.

    摘要翻译： 本发明涉及易溶于有机溶剂的新型热塑性和无定形聚酰亚胺，用于聚酰亚胺的新型芳族二氨基化合物及其制备方法，包含热塑性聚酰亚胺和纤维增强剂的聚酰亚胺基树脂组合物， 用于制备树脂组合物的树脂组合物的注塑制品，通过将上述可溶性和热塑性聚酰亚胺与纤维增强剂组合成型而获得的聚酰亚胺类复合材料和具有用上述聚酰亚胺改性的表面的纤维增强剂。 聚酰亚胺包含必需的结构单元，其具有一个或多个下式的重复结构单元：其中m和n分别为0或1的整数，R为本发明的聚酰亚胺基本上为 与常规已知的聚酰亚胺相比，在降低的温度下的熔体流动稳定性优异并且具有极大的改进的加工性。 通过使用新颖的芳族二氨基化合物作为单体获得的本发明的聚酰亚胺可以通过侧链而不是聚酰亚胺的主链来控制各种性能如熔体流动性和在溶剂中的溶解度。 因此，在保持由本发明的二氨基化合物的二苯甲酮结构得到的高耐热性和粘合性的同时，可以获得优异的熔体流动性和溶剂中的溶解性。

    Polyimide composition
    4.
    发明授权
    Polyimide composition 失效
    聚酰亚胺组合物

    公开(公告)号：US5321096A

    公开(公告)日：1994-06-14

    申请号：US35043

    申请日：1993-03-22

    申请人： Yuichi Okawa ,  Nobuhito Koga ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Akihiro Yamaguchi

    发明人： Yuichi Okawa ,  Nobuhito Koga ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Akihiro Yamaguchi

    IPC分类号： C08G73/10 ,  C08L71/00 ,  C08L79/08 ,  C08L81/06 ,  C08F283/04 ,  C08G69/48

    CPC分类号： C08L71/00 ,  C08G73/101 ,  C08L79/08 ,  C08L81/06

    摘要： A thermoplastic resin composition comprise 99.9.about.50 parts by weight of one or more thermoplastic resin selected from the group consisting of aromatic polyimide, aromatic polyetherimide, aromatic polyamideimide, aromatic polyethersulfone and aromatic polyether ketone and 0.1.about.50 parts by weight of one or more liquid crystal type aromatic polyimide having recurring structural units represented by the formula (1): ##STR1## wherein R.sub.1 .about.R.sub.5 is a hydrogen atom, fluorine atom, trifluoromethyl, methyl, ethyl or cyano and may be the same or different, and R is a tetravalent radical having 6.about.27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected each other with a direct bond or a bridge member.The present invention can provide thermoplastic resin compositions which have remarkably good processability and excellent thermal stability in addition to essentially excellent properties of each resin.

    摘要翻译： 热塑性树脂组合物包含99.9重量份的一种或多种选自芳族聚酰亚胺，芳族聚醚酰亚胺，芳族聚酰胺酰亚胺，芳族聚醚砜和芳族聚醚酮的热塑性树脂和0.1重量份的一种或多种液体 具有由式（1）表示的重复结构单元的结晶型芳族聚酰亚胺：（1）n原子，氟原子，三氟甲基，甲基，乙基或氰基，可以相同或不同，R是具有 6个碳原子，并且选自由直链或桥构件相互连接的单芳族基团，缩合多芳族基团和非缩合芳族基团组成的组。 本发明可以提供具有非常好的加工性和优异的热稳定性的热塑性树脂组合物，除了每种树脂的基本上优异的性能。

    Heat-resistant adhesive and method of adhesion by using adhesive
    6.
    发明授权
    Heat-resistant adhesive and method of adhesion by using adhesive 失效
    耐热粘合剂和使用粘合剂粘合的方法

    公开(公告)号：US5300620A

    公开(公告)日：1994-04-05

    申请号：US79753

    申请日：1993-06-22

    申请人： Hideaki Okikawa ,  Shoji Tamai ,  Katsuaki Iiyama ,  Saburo Kawashima ,  Akihiro Yamaguchi ,  Tadashi Asanuma

    发明人： Hideaki Okikawa ,  Shoji Tamai ,  Katsuaki Iiyama ,  Saburo Kawashima ,  Akihiro Yamaguchi ,  Tadashi Asanuma

    IPC分类号： C08G73/10 ,  C09J179/08 ,  H05K3/38 ,  C08G69/26 ,  C08L79/08

    CPC分类号： C08G73/1071 ,  C08G73/1014 ,  C08G73/1017 ,  C09J179/08 ,  H05K3/386 ,  Y10S525/928

    摘要： The heat resistant adhesive of the invention comprises polyamic acid and/or polyimide which are prepared by using 1,3-bis(3-aminophenoxy)benzene as an aromatic diamine component and 3,3',4,4'-biphenyltetracarboxylic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride and/or 3,3',4,4'-diphenylethertetracarboxylic dianhydride as tetracarboxylic acid dianhydrides, and further by blocking the polymer chain end with dicarboxylic anhydride or a monoamine compound; or comprises a polyimide solution containing the polyimide in a good solvent.The adhesive of the invention is a heat-resistant adhesive capable of adhering under mild temperature/mild pressure conditions. The adhesive of polyimide solution can provide desired adhesion by simple procedures such as applying to the adherend and heating under pressure and exhibits excellent adhesive strength. Consequently, the heat-resistant adhesive of the invention is very useful for the adhesion of structural and electronic materials and other industrial materials.

    摘要翻译： 本发明的耐热粘合剂包括通过使用1,3-双（3-氨基苯氧基）苯作为芳族二胺组分和3,3'，4,4'-联苯四羧酸二酐3，3'，4,4'-联苯四羧酸二酐制备的聚酰胺酸和/或聚酰亚胺 ，3'，4,4'-二苯甲酮四羧酸二酐和/或3,3'，4,4'-二苯基醚四羧酸二酐作为四羧酸二酐，并进一步通过用二羧酸酐或单胺化合物封闭聚合物链端; 或者包含在良溶剂中含有聚酰亚胺的聚酰亚胺溶液。 本发明的粘合剂是能够在温和/温和的条件下粘合的耐热粘合剂。 聚酰亚胺溶液的粘合剂可以通过简单的方法提供所需的粘附性，例如施加到被粘物上并在加压下加热并显示出优异的粘合强度。 因此，本发明的耐热粘合剂对于结构和电子材料和其它工业材料的粘合是非常有用的。

    Olefin polymerization catalyst system
    8.
    发明授权
    Olefin polymerization catalyst system 失效
    烯烃聚合催化剂体系

    公开(公告)号：US6063725A

    公开(公告)日：2000-05-16

    申请号：US743374

    申请日：1996-11-04

    申请人： Tadahiro Sunaga ,  Yukio Ishii ,  Tadashi Asanuma

    发明人： Tadahiro Sunaga ,  Yukio Ishii ,  Tadashi Asanuma

    IPC分类号： C08F4/02 ,  C08F4/602 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922

    摘要： An olefin polymerization catalyst system comprising an organic transition metal compound and a support, wherein an organic transition metal compound is soluble in an inert organic solvent and a support which is insoluble in the inert organic solvent, and the support comprises an organic high molecular weight compound which contains a specific carbonyl-containing group. The catalyst system can polymerize an olefin in a high activity, provides polymer with high stereoregularity, prevents adhesion or fouling of the polymer generated in the course of polymerization or an organic aluminum oxy compound on the inner wall of the reactor, leads to high bulk density of the polymer and very reduced level of fisheye and/or gel generation on the processed item, can maintain high productivity, can manufacture high quality product, and thus provides extremely high contribution in industry.

    摘要翻译： 一种包含有机过渡金属化合物和载体的烯烃聚合催化剂体系，其中有机过渡金属化合物可溶于惰性有机溶剂和不溶于惰性有机溶剂的载体，载体包含有机高分子量化合物 其含有特定的含羰基。 催化剂体系可以以高活性聚合烯烃，提供具有高立构规整性的聚合物，防止在聚合过程中产生的聚合物的粘附或结垢或反应器内壁上的有机铝氧化合物导致高堆积密度 的聚合物，并且处理物品上的鱼眼和/或凝胶生成水平非常降低，可以保持高生产率，可以制造高品质的产品，从而在工业中提供极高的贡献。

    Syndiotactic propylene copolymer, preparation of the same, and resin composition containing the same
    9.
    发明授权
    Syndiotactic propylene copolymer, preparation of the same, and resin composition containing the same 失效
    间同立构丙烯共聚物，其制备方法和含有它们的树脂组合物

    公开(公告)号：US5534595A

    公开(公告)日：1996-07-09

    申请号：US468316

    申请日：1995-06-06

    申请人： Tadashi Asanuma ,  Hiroshi Matsuzawa ,  Tateyo Sasaki ,  Kaoru Kawanishi

    发明人： Tadashi Asanuma ,  Hiroshi Matsuzawa ,  Tateyo Sasaki ,  Kaoru Kawanishi

    IPC分类号： C08F8/00 ,  C08F4/642 ,  C08F210/06

    CPC分类号： C08F8/00

    摘要： Disclosed is a syndiotactic propylene copolymer containing 0.01 to 40 mol % of olefin units containing --OH group in the side chain. Of absorption peaks attributed to the methyl groups of the propylene units on an absorption spectrum by .sup.13 C-NMR of the copolymer, the intensity of an absorption peak observed at about 20.2 ppm is 0.3 or more of the intensity of absorption peaks of all the methyl groups attributed to the propylene units. The copolymer is produced by copolymerizing propylene and an alkenylsilane or alkenylborane compound in the presence of a catalyst system comprising an asymmetric ligands-having transition metal compound and an aluminoxane, followed by heat-treating the resulting propylene-alkenylsilane copolymer in the presence of a trialkylamine oxide and KF.HF or oxidizing and decomposing the resulting propylene-alkenylborane compound copolymer. Also disclosed is a resin composition comprising the copolymer and other polyolefin(s).

    摘要翻译： 公开了含侧链中含有-OH基的烯烃单元为0.01〜40摩尔％的间同立构丙烯共聚物。 归因于丙烯单元的甲基的吸收峰在共聚物的13 C-NMR吸收光谱上，在约20.2ppm处观察到的吸收峰的强度为所有甲基的吸收峰的强度的0.3以上 归因于丙烯单元。 共聚物通过在包含不对称配体的过渡金属化合物和铝氧烷的催化剂体系的存在下共聚丙烯和烯基硅烷或烯基硼烷化合物，然后在三烷基胺存在下热处理所得的丙烯 - 链烯基硅烷共聚物 氧化物和KF.HF，或氧化和分解得到的丙烯 - 烯基硼烷化合物共聚物。 还公开了包含共聚物和其它聚烯烃的树脂组合物。

    Polypropylene fiber and a preparation process thereof
    10.
    发明授权
    Polypropylene fiber and a preparation process thereof 失效
    聚丙烯纤维及其制备方法

    公开(公告)号：US5478646A

    公开(公告)日：1995-12-26

    申请号：US15056

    申请日：1993-02-08

    申请人： Tadashi Asanuma ,  Tetsunosuke Shiomura ,  Shigeru Kimura ,  Nobutaka Uchikawa ,  Yoichi Kawai ,  Keigo Suehiro ,  Satoshi Fukushima

    发明人： Tadashi Asanuma ,  Tetsunosuke Shiomura ,  Shigeru Kimura ,  Nobutaka Uchikawa ,  Yoichi Kawai ,  Keigo Suehiro ,  Satoshi Fukushima

    IPC分类号： D01F6/06 ,  D02G3/00

    CPC分类号： D01F6/06 ,  Y10T428/2913 ,  Y10T428/2929 ,  Y10T428/2931

    摘要： A fiber excellent in strength and having an average size of 10,000-0.1 denier can be obtained by extruding a raw material composed mainly of a polypropylene having a syndiotactic pentad fraction of 0.7 or more and optionally stretching the resulting extruded material.By using as the raw material a composition consisting of two kinds of polypropylenes each having an intrinsic viscosity .eta..sub.1 or .eta..sub.2, the log(.eta..sub.2 /.eta..sub.1) being more than 0.05 or less than -0.05, and a syndiotactic pentad fraction of 0.7 or more at a weight ratio of 95:5-5:95 or a composition consisting of at least 50 parts by weight of a syndiotactic polypropylene having the intrinsic viscosity .eta..sub.1 and a syndiotactic pentad fraction of 0.7 or above and at most 50 parts by weight of an isotactic polypropylene having the intrinsic viscosity .eta..sub.2, the extrudability is improved and the fiber stretching conditions are broadened.

    摘要翻译： 通过将主要由间同立构五单元组分为0.7以上的聚丙烯组成的原料挤出并任选地拉伸所得的挤出材料，可以获得强度优异且平均粒径为10,000-0.1旦尼尔的纤维。 通过使用由两种各自具有特性粘度eta 1或eta 2的聚丙烯组成的组合物，log（eta 2 / eta 1）大于0.05或小于-0.05，并且间同立构五单元组分数 0.7重量％以上，重量比为95:5.5:95的组合物或由至少50重量份的特性粘度η1和间同立构五单元组分数为0.7以上至多50份的间同立构聚丙烯组成的组合物 的特性粘度等于2的全同立构聚丙烯，可挤出性提高，纤维拉伸条件变宽。