摘要:
An oxidation catalyst for internal combustion engines which contains platinum on a finely divided support material and containing lead as a promoter. The catalytic activity of the oxidation catalyst can be increased greatly by promoting the catalyst with lead at a molar ratio of lead to platinum of 2:1. The light-off temperatures of the promoted catalyst are well below the corresponding temperatures for a conventional, lead-free catalyst.
摘要:
To adhere to legal exhaust-gas regulations, the exhaust gases of a lean-burn engine must be freed from soot particles and nitrogen oxides. It is proposed that the cylinders of the lean-burn engine be divided into two groups which discharge their exhaust gases into two associated exhaust lines which each comprise a soot filter and which are merged at an opening-in point into a common exhaust line. The common exhaust line comprises the catalytic converter for the removal of the nitrogen oxides. By regenerating the two soot filters at different times, the exhaust-gas temperature in the common exhaust line is limited to a mean temperature between the exhaust-gas temperature of normal operation and that of regeneration operation, and the catalytic converter for the removal of the nitrogen oxides is preserved.
摘要:
The present invention relates to an exhaust gas cleaning catalyst comprising on a honeycomb carrier a catalytic coating. Said honeycomb carrier has an upstream end and a downstream end and a plurality of flow channels are running from the upstream end to the downstream end. The catalytic coating comprises catalytically active precious metal components of which at least one component exhibits a concentration profile along the honeycomb carrier starting with a low concentration at the upstream end which increases along the flow channels up to a maximum value and then decreases again to the downstream end.
摘要:
Lean burn engines require an exhaust gas system comprising nitrogen oxide storage catalysts for removal of nitrogen oxides from their exhaust gases. When the lean burn engine is operated with a sulphur-containing exhaust gas, the storage catalysts have to be desulphurized from time to time. During the desulphurization, there is the risk of high pollutant emissions. These emissions can be reduced when the cylinders of the lean burn engine are combined in two groups which release their exhaust gas to two assigned exhaust legs, in each of which is arranged at least one nitrogen oxide storage catalyst. The two exhaust legs are combined beyond the storage catalysts to form a common exhaust leg which contains a catalyst which possesses a three-way function under stoichiometric conditions. The two nitrogen oxide storage catalysts are desulphurized offset in time with respect to one another. While rich exhaust gas at a high temperature flows through one storage catalyst for desulphurization, lean exhaust gas flows through the second storage catalyst, in such a way that the combined exhaust gas is of stoichiometric composition over the entire desulphurization period. Under the stoichiometric conditions, the catalyst with three-way function is capable of converting hydrocarbons, carbon monoxide and nitrogen oxides to harmless components.
摘要:
The invention relates to a process for coating ceramic honeycomb bodies with a coating suspension containing, in a carrier liquid, catalyst components as solids and/or in dissolved form. The honeycomb bodies have parallel flow channels running through them. The walls of the flow channels generally have an open pore structure. To coat the channel walls and in particular also the interior surfaces of the pores with the coating suspension, it is proposed that the flow channels be temporarily alternately closed and the coating suspension be forced through the open pore structure of the channel walls. The coating is subsequently dried and calcined. To close the flow channels, it is possible to use thermally or chemically decomposable or soluble compositions which are decomposed or dissolved either during calcination or by means of a subsequent chemical treatment. The coated honeycomb bodies are preferably used for the purification of exhaust gases from automobiles.
摘要:
The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.
摘要:
Coating a wall-flow filter with a catalytically active coating generally increases the exhaust-gas backpressure in the filter. The increase in the exhaust-gas backpressure is particularly pronounced if a slurry of fine-particle catalyst materials is used for the coating operation. The increase in the exhaust-gas backpressure can be restricted to a tolerable level if, prior to the coating operation, the slurry is so finely milled that virtually the entire mass of the catalyst materials is introduced into the pores of the filter and deposited on the inner surfaces of the pores. This is the case if the d90 diameter of the particles in the slurry is reduced to below 5 μm by milling.
摘要:
This invention relates to a method and a corresponding apparatus for coating open-pored bodies with at least one coating suspension. In particular, the coating suspension has solids and solutes in a liquid medium in a quantity in wet state which is to correspond to at least a required target quantity. The coating operation has a variation in the applied wet coating quantity from one body to the other. The method according to the invention is characterized by the steps of: coating the body with an actual quantity of the coating suspension, which is always larger than the required target quantity taking the variation of the coating operation into account, determining the difference between the actual quantity and the required target quantity, and reducing the difference between actual quantity and target quantity by removing still wet coating suspension.
摘要:
The invention relates to particle filters having an open pore structure for separating particles from fluids, which, for modification of their properties or for treatment of the fluid to be filtered, are provided with additional metal oxides or mixed metal oxides and optionally with further catalytically active components. In particular, the invention relates to particle filters treated with a catalytically active material, which is used for the treatment of the waste gases from combustion processes, in particular for the treatment of the exhaust gases of internal combustion engines. By impregnation of the filter bodies in a solution of a metal oxide sol or a mixed metal oxide sol, the preformed sol particles are deposited on the pore surfaces. Consequently, catalytic activations of the filter with good temperature stability in combination with a moderate increase in the exhaust gas back-pressure are possible.
摘要:
The present invention relates to an exhaust gas cleaning catalyst comprising on a honeycomb carrier a catalytic coating. Said honeycomb carrier has an upstream end and a downstream end and a plurality of flow channels are running from the upstream end to the downstream end. The catalytic coating comprises catalytically active precious metal components of which at least one component exhibits a concentration profile along the honeycomb carrier starting with a low concentration at the upstream end which increases along the flow channels up to a maximum value and then decreases again to the downstream end.