摘要:
To adhere to legal exhaust-gas regulations, the exhaust gases of a lean-burn engine must be freed from soot particles and nitrogen oxides. It is proposed that the cylinders of the lean-burn engine be divided into two groups which discharge their exhaust gases into two associated exhaust lines which each comprise a soot filter and which are merged at an opening-in point into a common exhaust line. The common exhaust line comprises the catalytic converter for the removal of the nitrogen oxides. By regenerating the two soot filters at different times, the exhaust-gas temperature in the common exhaust line is limited to a mean temperature between the exhaust-gas temperature of normal operation and that of regeneration operation, and the catalytic converter for the removal of the nitrogen oxides is preserved.
摘要:
To adhere to legal exhaust-gas regulations, the exhaust gases of a lean-burn engine must be freed from soot particles and nitrogen oxides. It is proposed that the cylinders of the lean-burn engine be divided into two groups which discharge their exhaust gases into two associated exhaust lines which each comprise a soot filter and which are merged at an opening-in point into a common exhaust line. The common exhaust line comprises the catalytic converter for the removal of the nitrogen oxides. By regenerating the two soot filters at different times, the exhaust-gas temperature in the common exhaust line is limited to a mean temperature between the exhaust-gas temperature of normal operation and that of regeneration operation, and the catalytic converter for the removal of the nitrogen oxides is preserved.
摘要:
Nitrogen oxide storage catalysts are used to remove nitrogen oxides from the exhaust gas of internal combustion engines operated predominantly under lean burn conditions. When these catalysts are used in diesel vehicles, the increased sulfur content in the fuel during operation results in poisoning of the catalyst, which is reversible at high temperatures under reduced exhaust gas conditions. In the case of conventional nitrogen oxide storage catalysts, temperatures of more than 600° C. have to be obtained for desulfurization. This is not always possible in diesel vehicles with a nitrogen oxide storage catalyst in the underbody area.The invention presents a process whose application allows the desulfurization temperature of conventional nitrogen oxide storage catalysts which comprise a platinum component and at least one nitrogen oxide storage material to be lowered. The basicity of the chemical environment of the platinum is lowered, while the nitrogen oxide storage material can remain unchanged as such. In addition, an improved nitrogen oxide storage catalyst with reduced desulfurization temperature which results from the application of the process is presented. Such catalysts are suitable particularly for nitrogen oxide aftertreatment of the exhaust gases of diesel engines.
摘要:
Nitrogen oxide storage catalysts are used to remove the nitrogen oxides present in the lean exhaust gas of lean-burn engines. As a result of the stress due to high temperatures in vehicle operation, they are subject to thermal aging processes which affect both the nitrogen oxide storage components and the noble metals present as catalytically active components. The present invention provides a process with which the catalytic activity of a nitrogen oxide storage catalyst which comprises, in addition to platinum as a catalytically active component, basic compounds of strontium and/or barium on a support material comprising cerium oxide, said catalytic activity being lost owing to the thermal aging process, can be at least partly restored. The two-stage process is based on the fact that strontium and/or barium compounds formed during the thermal aging with the support material, which also comprise platinum, are recycled to the catalytically active forms by controlled treatment with specific gas mixtures.
摘要:
Lean burn engines require an exhaust gas system comprising nitrogen oxide storage catalysts for removal of nitrogen oxides from their exhaust gases. When the lean burn engine is operated with a sulphur-containing exhaust gas, the storage catalysts have to be desulphurized from time to time. During the desulphurization, there is the risk of high pollutant emissions. These emissions can be reduced when the cylinders of the lean burn engine are combined in two groups which release their exhaust gas to two assigned exhaust legs, in each of which is arranged at least one nitrogen oxide storage catalyst. The two exhaust legs are combined beyond the storage catalysts to form a common exhaust leg which contains a catalyst which possesses a three-way function under stoichiometric conditions. The two nitrogen oxide storage catalysts are desulphurized offset in time with respect to one another. While rich exhaust gas at a high temperature flows through one storage catalyst for desulphurization, lean exhaust gas flows through the second storage catalyst, in such a way that the combined exhaust gas is of stoichiometric composition over the entire desulphurization period. Under the stoichiometric conditions, the catalyst with three-way function is capable of converting hydrocarbons, carbon monoxide and nitrogen oxides to harmless components.
摘要:
An emission control system for the cleaning of the exhaust gases of a lean burn engine with two or more cylinders comprises a first exhaust leg for the exhaust gases of a first group of cylinders and a second exhaust leg for the exhaust gases of a second group of cylinders. A nitrogen oxide storage catalyst is arranged in each exhaust leg. The two exhaust legs are combined downstream of the storage catalysts at a confluence to form a common exhaust leg. The common exhaust leg contains an SCR catalyst. The first and second groups of cylinders are each supplied alternately in periodic intervals with lean and rich air/fuel mixtures. Lean or rich exhaust gases are thus obtained in the combustion in the cylinders and released into the corresponding exhaust legs. Lean and rich exhaust gases are adjusted with respect to one another so as to result in a lean exhaust gas after the combination of the exhaust gases in the common exhaust leg. The regeneration of the storage catalysts may result in the formation of ammonia, which is stored by the SCR catalyst and reacted with nitrogen oxides which pass through the storage catalysts in an unwanted manner during the storage phases.
摘要:
Nitrogen oxide storage catalysts are used to remove the nitrogen oxides present in the lean exhaust gas of lean-burn engines. Storage catalysts are thermally aged by high temperatures. Ageing is due to sintering of the catalytically active noble metal components of the catalyst and to formation of compounds of the storage components with the support materials. According to the invention, the formation of compounds of the storage materials can be largely reversed by treatment of the storage material with a gas mixture containing carbon dioxide, optionally water vapor and optionally nitrogen oxides at temperatures in the range from 200° C. to 950° C., preferably from 300° C. to 700° C. The reactivation can be carried out under emission-neutral conditions directly in the vehicle during driving operation by setting of suitable exhaust gas conditions and regulating the air/fuel ratio.
摘要:
The present invention relates to a method for the treatment of an exhaust gas comprising NOx, wherein the method comprises the step of subjecting the exhaust gas to an exhaust gas treatment system comprising, in order of the exhaust stream: (a) a first NOx storage catalytic converter (2, 2′); (b) a catalytic converter (3) for selective catalytic reduction (SCR) downstream of the first NOx storage catalytic converter; and (C) a catalytic converter (4) having oxygen storage capacity downstream of the SCR catalytic converter; wherein the exhaust gas treatment system is operated in alternating rich and lean phases, wherein the rich phase is terminated when the amount of reducing components leaving the first NOx storage catalytic converter is at least 0.05 times the N amount of reducing components consumed by the first NOx storage catalytic converter during the time interval beginning when the air/fuel ratio upstream of the first NOx storage catalytic converter turns from lean to rich conditions and ending when the air/fuel ratio downstream of the first NOx storage catalytic converter turns from lean to rich conditions. Optionally there can be provided a close coupled three-way or diesel oxidation or NOx storage catalytic converter (1, 1′).
摘要:
The present invention relates to an exhaust-gas aftertreatment system which comprises a preferably catalytically active particle filter (wall-flow filter) which is followed in turn by a throughflow monolith (flow-through monolith) which is preferably provided with a catalytically active function. Both components have the same storage functions for gaseous substances present in the exhaust gas of internal combustion engines. The system is suitable in particular for the simultaneous removal of particles and pollutants from the exhaust gas of both predominantly lean-operated internal combustion engines and also of internal combustion engines operated predominantly with a stoichiometric air/fuel mixture. Likewise described is a process for the production and the use of such a system for exhaust-gas aftertreatment.
摘要:
The present invention relates to an exhaust-gas aftertreatment system which comprises a preferably catalytically active particle filter (wall-flow filter) which is followed in turn by a throughflow monolith (flow-through monolith) which is preferably provided with a catalytically active function. Both components have the same storage functions for gaseous substances present in the exhaust gas of internal combustion engines. The system is suitable in particular for the simultaneous removal of particles and pollutants from the exhaust gas of both predominantly lean-operated internal combustion engines and also of internal combustion engines operated predominantly with a stoichiometric air/fuel mixture. Likewise described is a process for the production and the use of such a system for exhaust-gas aftertreatment.